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Silica-coated magnetic NiFe2O4 nanoparticles-supported H3PW12O40; synthesis, preparation, and application as an efficient, magnetic, green catalyst for one-pot synthesis of tetrahydrobenzo[b]pyran and pyrano[2,3-c]pyrazole derivatives

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Abstract

A powerful, magnetic, supported, acid catalyst, NiFe2O4@SiO2–H3PW12O40, was prepared by chemical support of Keggin (H3PW12O40) heteropolyacid (HPA) on silica-coated NiFe2O4 magnetic nanoparticles. XRD, TEM, SEM, VSM, and FTIR confirmed that the keggin HPA is well dispersed on the surface of silica-coated NiFe2O4 magnetic nanoparticles. The magnetically recoverable catalyst could be easily recycled at least six times without significant loss of catalytic activity. After full characterization, its catalytic activity was investigated in the synthesis of tetrahydrobenzo[b]pyran and pyrano[2,3-c]pyrazole derivatives.

Graphical Abstract

(1) Novel silica-coated magnetic NiFe2O4 nanoparticles-supported H3PW12O40 was fabricated and characterized. (2) Recyclability of the catalyst. (3) Avoiding use of corrosive acid catalysts. (4) Green chemistry.

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Acknowledgments

The author thanks the Research Council of Hakim Sabzevari University for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Behrooz Maleki, Negar Nasiri & Samaneh Sedigh Ashrafi

  2. Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad, Iran

    Hossein Eshghi & Amir Khojastehnezhad

  3. Department of Chemistry, Sabzevar Branch, Islamic Azad University, Sabzevar, Iran

    Mohammad Barghamadi

  4. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Omid Pourshiani

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  1. Behrooz Maleki
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Correspondence to Behrooz Maleki.

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Maleki, B., Eshghi, H., Barghamadi, M. et al. Silica-coated magnetic NiFe2O4 nanoparticles-supported H3PW12O40; synthesis, preparation, and application as an efficient, magnetic, green catalyst for one-pot synthesis of tetrahydrobenzo[b]pyran and pyrano[2,3-c]pyrazole derivatives. Res Chem Intermed 42, 3071–3093 (2016). https://doi.org/10.1007/s11164-015-2198-8

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