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Effects of medium and nickel salt source in the synthesis and catalytic performance of nano-sized nickel in the Suzuki-Miyaura cross-coupling reaction

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Abstract

In this contribution, the influence of the origin of the nickel salts and the applied temperature were investigated on the preparation of Ni nanoparticles by the reduction of hydrazine. The nanoparticles obtained were characterized by X-ray diffractometry, dynamic light scattering as well as transmission and scanning electron microscopies. Several nickel salts proved to be applicable; however, only the bromide and iodide nickel halides could be transformed into metallic nickel form under room temperature. Their catalytic activities were also tested in the cross-coupling reaction between iodobenzene and phenylboronic acid, and it was found that most catalysts performed superbly. An experimentally supported explanation for the varying catalytic activities of Ni nanoparticles derived from various halide salts is offered. Furthermore, an unusual crystal rearrangement was observed during the catalytic tests.

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Acknowledgement

This work was supported by the GINOP-2.3.2-15-2016-00013 grant. The financial help is highly appreciated.

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Authors and Affiliations

  1. Department of Organic Chemistry, University of Szeged, Dóm tér 8, Szeged, 6720, Hungary

    Adél Anna Ádám, Márton Szabados, Katalin Musza & István Pálinkó

  2. Material and Solution Structure Research Group, Institute of Chemistry, University of Szeged, Aradi Vértanúk tere 1, Szeged, 6720, Hungary

    Adél Anna Ádám, Márton Szabados, Katalin Musza, Pál Sipos & István Pálinkó

  3. Department of Applied and Environmental Chemistry, University of Szeged, Rerrich B. tér 1, Szeged, 6720, Hungary

    Péter Bélteky, Zoltán Kónya & Ákos Kukovecz

  4. MTA-SZTE Reaction Kinetics and Surface Chemistry Research Group, Rerrich B. tér 1, Szeged, 6720, Hungary

    Zoltán Kónya

  5. Department of Inorganic and Analytical Chemistry, University of Szeged, Dóm tér 7, Szeged, 6720, Hungary

    Pál Sipos

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  1. Adél Anna Ádám
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Ádám, A.A., Szabados, M., Musza, K. et al. Effects of medium and nickel salt source in the synthesis and catalytic performance of nano-sized nickel in the Suzuki-Miyaura cross-coupling reaction. Reac Kinet Mech Cat 126, 841–855 (2019). https://doi.org/10.1007/s11144-018-01526-0

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  • DOI: https://doi.org/10.1007/s11144-018-01526-0

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