Skip to main content

Advertisement

SpringerLink
Log in

Production of Products of Various Shapes From Si3N4-Based Refractory Compounds by Spark Plasma Sintering

  • Theory and Technology of Sintering, Thermal and Thermochemical Treatment
  • Published:
Powder Metallurgy and Metal Ceramics Aims and scope

The possibility of manufacturing ball-, cylinder-, and hollow cylinder-shaped products based on Si3N4 and TiN nanocomposites by spark plasma sintering (SPS) is demonstrated. The features of the product properties associated with different conductivity of composites. The mechanical properties of ball- and hollow cylinder-shaped materials measured: HV ~ 11.5 GPa, KIc ~ 4.1 MPa · m1/2 (for Si3N4); and HV ~ 12.7 GPa, KIc ~ 4.8 MPa · m1/2 (for Si3N4–TiN).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Li Xikun, Liu Jing, and Qin Like, “Composition, characteristics and development of advanced ceramic cutting tools,” J. Rare Earths, 25, 287 (2007).

  2. O. B. Zgalat-Lozinskii, A. V. Ragulya, and M. Herrmann, “Nanostructured composites based on highmelting nitrides,” Silicates Industries, 69, No. 7–8, 147–153 (2004).

    Google Scholar 

  3. R. A. Andriyevskii and A. M. Glezer, “Size effects in nanocrystalline materials. II. Mechanical and physical properties,” Fiz. Metal. Metalloved., 89, No. 1, 91–112 (2000).

    Google Scholar 

  4. I. Schulz, M. Herrmann, I. Endler, et al., “Nano Si3N4 composites with improved tribological properties,” Lubr. Sci., 21, 69–81 (2009).

    Article  Google Scholar 

  5. M. H. Bocanegra-Bernal and B. Matovic, “Mechanical properties of silicon nitride – based ceramic and its use in structural applications at high temperatures,” Mat. Sci. Eng. A, 527, 1314–1338 (2010).

    Article  Google Scholar 

  6. B. Zou, C. Z. Huang, H. L. Liu, and M. Chen, “Preparation and characterization of Si3N4/TiN nanocomposites ceramic tool materials,” J. Mat. Proc. Techn., 209, 4595–4600 (2009).

    Article  Google Scholar 

  7. N. Ahmad and H. Sueyosli, “Properties of Si3N4–TiN composites fabricated by spark plasma sintering using a mixture of Si3N4 and Ti powders,” Ceram. Int., 36, 491–496 (2010).

    Article  Google Scholar 

  8. L. Ceja-Cardenas, J. Lemus-Ruiz, D. Jaramillo-Vigueras, and S. D. de la Torre, “Spark plasma sintering of Si3N4 ceramics with Al2O3 and Y2O3 as additives and its morphology transformation,” J. All. Comp., 501, 345–351 (2010).

    Article  Google Scholar 

  9. Z. Guo, G. Blugan, and R. Kirchner, “Microstructure and electrical properties of Si3N4–TiN composites sintered by hot pressing and spark plasma sintering,” Ceram. Int., 33, 1223–1229 (2007).

    Article  Google Scholar 

  10. V. V. Izmailov and M. V. Novoselova, “Study on the electrical conductivity of a liquid-metal composite powder material,” Vest. TvGU, Ser. Fiz., No. 8, 83–92 (2010).

  11. T. Ya. Kosolapova, Properties, Production, and Application of Refractory Compounds [in Russian], Metallurgiya, Moscow (1986), p. 928.

    Google Scholar 

  12. R. A. Andriyevskii and I. I. Spivak, Silicon Nitride and Si 3 N 4 -Based Materials [in Russian], Metallurgiya, Moscow (1984), p. 136.

    Google Scholar 

  13. P. T. Oreshkin, Electrical Conductivity of Refractories and Relaxation Effects on the Barrier Layers [in Russian], Metallurgiya, Moscow (1965), p. 152.

    Google Scholar 

  14. A. V. Karpov, Yu. G. Morozov, V. A. Bunin, and I. P. Borovinskaya, “Effect of yttrium oxide on the electrical conductivity of nitride SHS-ceramics,” Neorgan. Mater., 38, No. 6, 762–766 (2002).

    Google Scholar 

  15. P. B. Kotel’nikov, S. N. Bashlykov, Z. G. Galiakbarov, and A. I. Kashtanov, Super-Refractory Elements and Compounds: Handboolk [in Russian], Metallurgiya, Moscow (1969), p. 376.

    Google Scholar 

  16. V. G. Kolesnichenko, V. P. Popov, O. B. Zgalat-Lozinskii, et al., “Field assisted sintering of nanocrystalline titanium nitride powder,” Powder Metall. Met. Ceram., 50, No. 3–4, 157–166 (2011).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frantsevich Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, Kiev, Ukraine

    M. V. Zamula, A. V. Derevyanko, V. G. Kolesnichenko, O. B. Zgalat-Lozinskii & A. V. Ragulya

Authors
  1. M. V. Zamula
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Derevyanko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. G. Kolesnichenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. B. Zgalat-Lozinskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Ragulya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. V. Zamula.

Additional information

Translated from Poroshkovaya Metallurgiya, Vol. 54, Nos. 1–2 (501), pp. 12–21, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zamula, M.V., Derevyanko, A.V., Kolesnichenko, V.G. et al. Production of Products of Various Shapes From Si3N4-Based Refractory Compounds by Spark Plasma Sintering. Powder Metall Met Ceram 54, 8–15 (2015). https://doi.org/10.1007/s11106-015-9673-z

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11106-015-9673-z

Keywords

Search

Navigation