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High Temperature Oxidation Behavior of 9–12 % Cr Ferritic/Martensitic Steels in a Simulated Dry Oxyfuel Environment

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Abstract

The materials in oxyfuel power plant will be subjected to CO2− and SO2−rich gases on the fireside. The oxidation behaviour of two 9–12 % Cr steels T92 and VM12 was studied under dry oxyfuel environment in the temperature range of 580–650 °C for up to 1,000 h. The oxide structure and morphology were analyzed using various experimental techniques. A complex temperature dependence of oxidation rate is observed for both T92 and VM12 whereby the oxidation rate decreased with increasing temperature. This is attributed to increased Cr-enrichment in the inner scale with increasing temperature. T92 and VM12 alloys are also susceptible to carburization in an oxyfuel environment.

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Acknowledgments

K. Chandra would like to acknowledge Adolf Martens Foundation for his post-doctoral fellowship program under which this research was carried out. F. Rizzo thanks the support from CAPES, CNPq and FAPERJ. The authors also wish to thank Mr. Gobel Artur for his contribution in conducting the corrosion experiments.

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Authors and Affiliations

  1. Federal Institute for Materials Research and Testing, Division 5.1, Unter den Eichen 87, 12205, Berlin, Germany

    K. Chandra, A. Kranzmann, R. Saliwan Neumann, G. Oder & F. Rizzo

  2. Department of Materials Engineering, Pontificia Universidade Católica, Rio de Janeiro, Brazil

    F. Rizzo

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  1. K. Chandra
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  2. A. Kranzmann
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  3. R. Saliwan Neumann
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  4. G. Oder
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  5. F. Rizzo
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Correspondence to K. Chandra.

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Chandra, K., Kranzmann, A., Saliwan Neumann, R. et al. High Temperature Oxidation Behavior of 9–12 % Cr Ferritic/Martensitic Steels in a Simulated Dry Oxyfuel Environment. Oxid Met 83, 291–316 (2015). https://doi.org/10.1007/s11085-014-9521-4

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  • DOI: https://doi.org/10.1007/s11085-014-9521-4

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