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Fabrication and advanced optical and electronic characteristics of PVA/SiC/CeO2 hybrid nanostructures for augmented nanoelectronics and optics fields

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Abstract

The current research aims to create of novel nanostructured films from silicon sarbide(SiC)/cerium oxide (CeO2) doped polyvinyl alcohol (PVA) as a promising nanocomposites materials to utilize in numerous quantum electronics and optical nanodevices. The fabricated nanostructures have great properties compared of other nanomaterials comprised few cost, excellent optical characteristics, flexible and lightweight. The structure, optical, and electronic features of PVA/SiC/CeO2 nanostructures were investigated. The structure properties included optimization, FTIR and optical microscope (OM). The optical characteristics were tested at wavelength ranged (200–800) nm. The optical characteristics results indicated that the absorbance of PVA rises about 76.9% at (λ = 240 nm, UV-spectra) while rises of 87% at (λ = 540 nm, VIS-spectra) when the SiC/CeO2 NPs content reached of (5.7 wt%).%. The energy gap decreased when the SiC/CeO2NPs content reached of 5.7wt% where it reduced from 4.5 to 2.7 eV, this performance make them appropriate for may optoelectronics nanodevices like transistors, photovoltaic cell, electronic gates, lasers, diodes and other applications. The optical parameters of PVA; with an increase in the SiC/CeO2 NPs content, the optical conductivity(σop), real (ε1) and imaginary (ε2) dielectric constants, absorption coefficient (α), refractive index (n), extinction coefficient (k), and other properties improved. Finally, the obtained results demonstrated that the PVA/SiC/CeO2 nanostructures are promising nanomaterials to employ in many quantum electronics and optical nanodevices.

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References

  • Abduljalil, H., Hashim, A., Jewad, A.: The effect of addition titanium dioxide on electrical properties of poly-methyl methacrylate. Eur. J. Sci. Res. 63(2), 231–235 (2011)

    Google Scholar 

  • Ahmed, H., Hashim, A.: Design and characteristics of novel PVA/PEG/Y2O3 structure for optoelectronics devices. J. Mol. Model. 26, 210 (2020). https://doi.org/10.1007/s00894-020-04479-1

    Article  CAS  PubMed  Google Scholar 

  • Ahmed, H., Hashim, A.: Structure, optical, electronic and chemical characteristics of novel (PVA-CoO) structure doped with silicon carbide. SILICON 13, 4331–4344 (2021a). https://doi.org/10.1007/s12633-020-00723-8

    Article  CAS  Google Scholar 

  • Ahmed, H., Hashim, A.: Lightweight, flexible and high energies absorption property of PbO2 doped polymer blend for various renewable approaches. Trans. Electr. Electron. Mater. 22, 335–345 (2021b). https://doi.org/10.1007/s42341-020-00244-6

    Article  Google Scholar 

  • Ahmed, H., Hashim, A.: Design and exploring the structure, optical and electronic characteristics of silicon doped PS/MoS2 structures for electronics Nanodevices. Opt. Quant. Electron. 54, 403 (2022a). https://doi.org/10.1007/s11082-022-03784-8

    Article  CAS  Google Scholar 

  • Ahmed, H., Hashim, A.: Design and tailoring the optical and electronic characteristics of silicon doped PS/SnS2 new composites for nano-semiconductors devices. SILICON 14, 6637–6643 (2022b). https://doi.org/10.1007/s12633-021-01449-x

    Article  CAS  Google Scholar 

  • Ahmed, H., Hashim, A.: Tuning the spectroscopic and electronic characteristics of ZnS/SiC nanostructures doped organic material for optical and nanoelectronics fields. SILICON 15, 2339–2348 (2023a). https://doi.org/10.1007/s12633-022-02173-w

    Article  CAS  Google Scholar 

  • Ahmed, H., Hashim, A.: Design and tailoring the structural and spectroscopic characteristics of Sb2S3 nanostructures doped PMMA for flexible nanoelectronics and optical fields. Opt. Quant. Electron. 55, 280 (2023b). https://doi.org/10.1007/s11082-022-04528-4

    Article  CAS  Google Scholar 

  • Ahmed, G., Hashim, A.: Synthesis and tailoring morphological and optical characteristics of PMMA/PEG/Si3N4 hybrid nanomaterials for optics and quantum nanoelectronics applications. SILICON (2023c). https://doi.org/10.1007/s12633-023-02572-7

    Article  Google Scholar 

  • Al-Aaraji, N.A.H., Hashim, A., Hadi, A., et al.: Effect of silicon carbide nanoparticles addition on structural and dielectric characteristics of PVA/CuO nanostructures for electronics devices. SILICON 14, 4699–4705 (2022a). https://doi.org/10.1007/s12633-021-01265-3

    Article  CAS  Google Scholar 

  • Al-Aaraji, N.A.H., Hashim, A., Hadi, A., et al.: Synthesis and enhanced optical characteristics of silicon carbide/copper oxide nanostructures doped transparent polymer for optics and photonics nanodevices. SILICON 14, 10037–10044 (2022b). https://doi.org/10.1007/s12633-022-01730-7

    Article  CAS  Google Scholar 

  • Alamdari, S., Ara, M.H.M., Tafreshi, M.J.: Synthesize and optical response of ZnO/CdWO4: Ce nanocomposite with high sensitivity detection of ionizing radiations. Opt. Laser Technol. 151, 107990 (2022). https://doi.org/10.1016/j.optlastec.2022.107990

    Article  CAS  Google Scholar 

  • Alamdari, S., Mirzaee, O., Tafreshi, M.J., Riedel, R.: Immobilization of ZnO: Ga nanocrystals in a polystyrene/cellulose matrix: a novel hybrid nanocomposite photocatalyst for future photo energy application. Compos. B Eng. 265, 110934 (2023). https://doi.org/10.1016/j.compositesb.2023.110934

    Article  CAS  Google Scholar 

  • Andriesh, A.M., Iovu, M., Shutov, S.: Chalcogenidenoncrystalline semiconductors in optoelectronics. J. Optoelectron. Adv. Mater. 4(3), 631–647 (2002)

    CAS  Google Scholar 

  • Divya, R., Meena, M., Mahadevan, C.K., Padma, C.M.: Investigation on CuO dispersed PVA polymer films. J. Eng. Res. Appl. 4(5), 1–7 (2014)

    Google Scholar 

  • Elmarzugi, N.A., et al.: Spectroscopic characterization of PEGDNA biocomplexes by FTIR. J. Appl. Pharm. Sci. 4(8), 6–10 (2014).

    Google Scholar 

  • Fadil, O.B., Hashim, A.: Fabrication and tailored optical characteristics of CeO2/SiO2 nanostructures doped PMMA for electronics and optics fields. SILICON 14, 9845–9852 (2022). https://doi.org/10.1007/s12633-022-01728-1

    Article  CAS  Google Scholar 

  • Florea, I., Feral-Martin, C., Majimel, J., Ihiawakrim, D., Hirlimann, C., Ersen, O.: Three-dimensional tomographic analyses of CeO2 nanoparticles. Cryst. Growth Des. 13(3), 1110–1121 (2013)

    Article  CAS  Google Scholar 

  • Hadi, A., Hashim, A.: development of a new humidity sensor based on (carboxymethyl cellulose–starch) blend with copper oxide nanoparticles. Ukr. J. Phys. 62, 1044–1049 (2017). https://doi.org/10.15407/ujpe62.12.1044

    Article  Google Scholar 

  • Hashim, A.: Enhanced morphological, optical and electronic characteristics of WC NPs doped PVP/PEO for flexible and lightweight optoelectronics applications. Opt. Quant. Electron. 53, 478 (2021). https://doi.org/10.1007/s11082-021-03100-w

    Article  CAS  Google Scholar 

  • Hashim, A., et al.: Controlling the morphological, optical and dielectric characteristics of PS/SiC/CeO2 nanostructures for nanoelectronics and optics fields. J. Inorg. Organomet. Polym. 33, 1–9 (2023a). https://doi.org/10.1007/s10904-022-02485-9

    Article  CAS  Google Scholar 

  • Hashim, A., et al.: Facile fabrication and developing the structural, optical and electrical properties of SiC/Y2O3 nanostructures doped PMMA for optics and potential nanodevices. SILICON 15, 1283–1290 (2023b). https://doi.org/10.1007/s12633-022-02104-9

    Article  CAS  Google Scholar 

  • Hdidar, M., Chouikhi, S., Fattoum, A., Arous, M., Kallel, A.: Infuence of TiO2 rutile doping on the thermal and dielectric properties of nanocomposite flms based PVA. J. Alloys Compd. 750, 375–383 (2018)

    Article  CAS  Google Scholar 

  • Hehre, W.J., Radom, L., Schleyer, P.R., Pople, J.A.: Ab Initio Molecular Orbital Theory. Wiley, New York (1986)

    Google Scholar 

  • Hugosson, H.W.: A theoretical treatise on the Electronic Structure of designer Hard Materials. Diss. ActaUniversitatisUpsaliensis (2001).

  • Hussien, H.A.J., Hashim, A.: Synthesis and exploring the structural, electrical and optical characteristics of PVA/TiN/SiO2 hybrid nanosystem for photonics and electronics nanodevices. J. Inorg. Organomet. Polym. 33, 2331–2345 (2023). https://doi.org/10.1007/s10904-023-02688-8

    Article  CAS  Google Scholar 

  • Hussien, H.A.J., Kadhim, R.G., Hashim, A.: Investigating the low cost photodegradation performance against organic pollutants using CeO2/MnO2/ polymer blend nanostructures. Opt. Quant. Electron. 54, 704 (2022). https://doi.org/10.1007/s11082-022-04094-9

    Article  CAS  Google Scholar 

  • Indolia, A.P., Gaur, M.S.: Optical properties of solution grown PVDF ZnO nanocomposite thin flms. J. Polym. Res. 20(1), 43 (2013a)

    Article  Google Scholar 

  • Indolia, A., Gaur, M.: Optical properties of solution grown PVDF–ZnOnanocomposite thin films. J. Polym. Res. 20, 43–50 (2013b)

    Article  Google Scholar 

  • Jang, J.H., Han, J.I.: Cylindrical relative humidity sensor based on poly-vinyl alcohol (PVA) for wearable computing devices with enhanced sensitivity. Sens. Actuators A 261, 268–273 (2017)

    Article  CAS  Google Scholar 

  • Jasim, F.A., Hashim, A., Hadi, A.G., Lafta, F., Salman, S.R., Ahmed, H.: Preparation of (pomegranate peel-polystyrene) composites and study their optical properties. Res. J. Appl. Sci. 8(9), 439–441 (2013)

    Google Scholar 

  • Kadhim, A.F., Hashim, A.: Fabrication and augmented structural optical properties of PS/SiO2/SrTiO3 hybrid nanostructures for optical and photonics applications. Opt. Quant. Electron. 55, 432 (2023). https://doi.org/10.1007/s11082-023-04699-8

    Article  CAS  Google Scholar 

  • Kadhim, M.H., Hasan, A.S., Akraa, M.A., Layla, A.Y.: Preparation and optimization of heterojunction donor(DLC)—acceptor(SI) as a solar cell by DFT and PLD. J. Ovonic Res. 17(3), 273–281 (2021). https://doi.org/10.15251/JOR.2021.173.273

    Article  CAS  Google Scholar 

  • Lalithambika, K.C., Shanthakumari, K., Sriram, S.: Optical properties of CdO thin films deposited by chemical bath method. Int. J. Chemtech Res. 6(5), 3071–3077 (2014)

    Google Scholar 

  • Li, Z., et al.: Preparation and characterization of aluminum-doped silicon carbide by combustion synthesis. J. Am. Ceram. Soc. 91(8), 2607–2610 (2008)

    Article  CAS  Google Scholar 

  • Mansuripur, M.: Classical Optics and its Applications. Cambridge Press, Cambridge (2002)

    Google Scholar 

  • Meteab, M.H., Hashim, A., Rabee, B.H.: Controlling the structural and dielectric characteristics of PS-PC/Co2O3–SiC hybrid nanocomposites for nanoelectronics applications. SILICON 15, 251–261 (2023a). https://doi.org/10.1007/s12633-022-02020-y

    Article  CAS  Google Scholar 

  • Meteab, M.H., Hashim, A., Rabee, B.H.: Synthesis and characteristics of SiC/MnO2/PS/PC quaternarynanostructures for advanced nanodielectrics fields. SILICON 15, 1609–1620 (2023b). https://doi.org/10.1007/s12633-022-02114-7

    Article  CAS  Google Scholar 

  • Mohapatra, S., Mishra, D.K., Mishra, G., Roy, G.S., Behera, D., Mantry, S., Singh, S.K.: A study on sintered TiO2 and TiO2/SiC composites synthesized through chemical reaction based solution method. J. Compos. Mater. 47(24), 3081–3089 (2013)

    Article  ADS  CAS  Google Scholar 

  • Obaid, W.O., Hashim, A.: Synthesis and augmented optical properties of PC/SiC/TaC hybrid nanostructures for potential and photonics fields. SILICON 14, 11199–11207 (2022). https://doi.org/10.1007/s12633-022-01854-w

    Article  CAS  Google Scholar 

  • Oftadeh, M., Naseh, S., Hamadanian, M.: Electronic properties and dipole polarizability of thiophene and thiophenol derivatives via Author’s personal copy Transactions on Electrical and Electronic Materials 1 3 density functional theory. Comput. Theoret. Chem. 966(1–3), 20–25 (2011)

    Article  CAS  Google Scholar 

  • Panahi-Kalamuei, M., Alizadeh, S., Mousavi-Kamazani, M., Salavati-Niasari, M.: Synthesis and characterization of CeO2 nanoparticles via hydrothermal route. J. Ind. Eng. Chem. 21, 1301–1305 (2015)

    Article  CAS  Google Scholar 

  • Phukan, P., Saikia, D.: Optical and structural investigation of CdSe quantum dots dispersed in PVA matrix and photovoltaic applications. Int. J. Photoenergy (2013). https://doi.org/10.1155/2013/728280

    Article  Google Scholar 

  • Ragab, H., Rajeh, A.: Structural, thermal, optical and conductive properties of PAM/PVA polymer composite doped with Ag nanoparticles for electrochemical application. Mater. Electron. 31, 16780–16792 (2020)

    Article  CAS  Google Scholar 

  • Rahman, M.T., Hoque, M.A., Rahman, G.T., Gafur, M.A., Khan, R.A., Hossain, M.K.: Study on the mechanical, electrical and opticalproperties of metal-oxide nanoparticles dispersed unsaturated polyester resin nanocomposites. Results Phys. 13, 102264 (2019). https://doi.org/10.1016/j.rinp.2019.102264

    Article  Google Scholar 

  • Rathod, S.G., Bhajantri, R.F., Ravindrachary, V., Sheela, T., Pujari, P.K., Naik, J., Poojary, B.: Pressure sensitive dielectric properties of TiO2 doped PVA/CN–Li nanocomposite. J. Polym. Res. 22(2), 6 (2015)

    Article  Google Scholar 

  • Sabbah, S., Hasan, M., Yehiaa, B., Satar, Z.: The effect of metal powder on the optical properties of polyvinyl acetate. J. Adv. Res. Appl. Sci. 3(1), 1–6 (2016). https://doi.org/10.53555/nnas.v3i1.666

    Article  Google Scholar 

  • Suresh, S.: Investigation of the optical and dielectric properties of the urea L-malic acid NLO single crystal. Am. Chem. Sci. J. 3(3), 325–337 (2013)

    Article  Google Scholar 

  • Tintu, R., Saurav, K., Sulakshna, K., Nampoori, V.P.N., Radhakrishnan, P., Thomas, S.: Ge28Se60Sb12/PVA composite films for photonic applications. J. Non-Oxide Glasses 2(4), 167–174 (2010)

    Google Scholar 

  • Venkatarayappa, M., Kilarkaje, S., Prasad, A., Hundekal, D.: Refractive index and dispersive energy of NiSO4 doped poly (ethylene oxide) films. J. Mater. Sci. Eng A 1(71), 964 (2011)

    Google Scholar 

  • Yu, M., Jayanthi, C.S., Wu, S.Y.: Bonding nature, structural optimization, and energetics studies of SiC graphitic-like layer structures and single/double walled nanotubes. http://arxiv.org/abs/901.356:07 (2009)

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Authors and Affiliations

  1. College of Education for Pure Sciences, Department of Physics, University of Babylon, Babylon, Iraq

    Huda Bukheet Hassan & Ahmed Hashim

  2. College of Materials Engineering, Department of Polymer and Petrochemical Industries, University of Babylon, Babylon, Iraq

    Ali S. Hasan

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  1. Huda Bukheet Hassan
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  2. Ali S. Hasan
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HBH, AH, ASH wrote the main manuscript text, prepared figures and reviewed the manuscript.

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Correspondence to Ahmed Hashim.

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Hassan, H.B., Hasan, A.S. & Hashim, A. Fabrication and advanced optical and electronic characteristics of PVA/SiC/CeO2 hybrid nanostructures for augmented nanoelectronics and optics fields. Opt Quant Electron 56, 309 (2024). https://doi.org/10.1007/s11082-023-05940-0

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