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Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones

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Abstract

N,N′-Bis(2-hydroxyiminoalkyl)-α,α′-dinitrones are of interest for the synthesis of 1,1′-dihydroxy-2,2′-biimidazoles. Thermal decomposition of two these dinitrones was studied in helium atmosphere. Thermal decomposition of the studied dinitrones at temperature interval 20–500 °C consists of several steps, the first step accompanying with significant exothermic effect (700–1000 J g−1). The first step has been shown to be a two-stage process, and decomposition products have been determined using chromatography–mass spectrometry. Thermogravimetric curves were used for the kinetic studies. Kinetic parameters of decomposition are estimated within the approaches of non-isothermal kinetics (“model-free” kinetics and nonlinear regression methods), with the computer program Netzsch Thermokinetics 2.

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Acknowledgements

This work was partially supported by the Russian Foundation for Basic Research (Grant 14–03–00291).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave 3, Novosibirsk-90, Russia, 630090

    V. A. Logvinenko

  2. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, Ac. Lavrentyev Ave 7, Novosibirsk-90, Russia, 630090

    V. P. Fadeeva, B. A. Selivanov, V. D. Tikhova, A. A. Nefedov & A. Ya. Tikhonov

  3. Novosibirsk State University, Pirogova St 2, Novosibirsk-90, Russia, 630090

    V. A. Logvinenko & V. P. Fadeeva

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  1. V. A. Logvinenko
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  2. V. P. Fadeeva
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  3. B. A. Selivanov
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  4. V. D. Tikhova
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  5. A. A. Nefedov
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  6. A. Ya. Tikhonov
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Correspondence to V. A. Logvinenko.

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Logvinenko, V.A., Fadeeva, V.P., Selivanov, B.A. et al. Thermal decomposition of several N,N′-bis(2-hydroxyiminoalkyl)-α,α′-dinitrones. J Therm Anal Calorim 140, 685–693 (2020). https://doi.org/10.1007/s10973-019-08868-4

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