Abstract
The present study deals with the preparation of oxidized biochar fibres derived from Luffa cylindrica sponges and the subsequent adsorption of Th(IV). The adsorption experiments were performed by batch-type experiments and include the effect of various physiochemical parameters, as well as characterization of the solid phases by means of spectroscopic (FTIR) and XRD measurements. The experimental data are best described by the pseudo-second order kinetic model (R2 = 0.998) and the adsorbent was found to have a relatively high adsorption capacity (qmax = 70 mg g−1) even at pH 3, attributed to the formation of inner-sphere complexes.
Similar content being viewed by others
References
Khalil HPSA, Bhat AH, Yusra AFI (2012) Green composites from sustainable cellulose nanofibrils: a review. Carbohyd Polym 87:963–979
Chedeville O, Debacq M, Porte C (2009) Removal of phenolic compounds present in olive mill wastewaters by ozonation. Desalination 249:865–869
Amin NAS, Akhtar J, Rai HK (2010) Screening of combined zeolite-ozone system for phenol and COD removal. Chem Eng J 158:520–527
El-Ashtoukhy E-SZ, El-Taweel YA, Abdelwahab O, Nassef EM (2013) Treatment of petrochemical wastewater containing phenolic compounds by electrocoagulation using a fixed bed electrochemical reactor. Int J Electrochem Sci 8:1534–1550
Abdelwahab O, Amin NK, El-Ashtoukhy E-S (2009) Electrochemical removal of phenol from oil refinery wastewater. J Hazard Mater 163:711–716
Burghoff B, de Haan AB (2009) Liquid-liquid equilibrium study of phenol extraction with Cyanex 923. Sep Sci Technol 44:1753–1771
Yu P, Chang Z, Ma Y, Wang S, Cao H, Hua C, Liu H (2009) Separation of p-Nitrophenol and o-Nitrophenol with three-liquid-phase extraction system. Sep Purif Technol 70:199–206
Bodalo A, Gomez E, Hidalgo AM, Gomez M, Murcia MD, Lopez I (2009) Nanofiltration membranes to reduce phenol concentration in wastewater. Desalination 245:680–686
Liu Q-S, Zheng T, Wang P, Jiang J-P, Li N (2010) Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers. Chem Eng J 157:348–356
Tarley CRT, Arruda MAZ (2003) Natural adsorbents: potential and applications of natural sponge (Luffa cylindrica) in lead removal in wastewater laboratory. Rev Anal 4:26–31
Tran HH, Roddick FA, O’Donnell FA (1999) Comparison of chromatography and desiccant silica gels for the adsorption of metal ions—I. Adsorption and kinetics. Water Res 33:2992–3000
Dabrowski A (2001) Adsorption, from theory to practice. Adv Colloid Interface 93:135–224
Liatsou I, Constantinou P, Pashalidis I (2017) Copper binding by activated biochar fibres derived from Luffa Cylindrica. Water Air Soil Pollut. https://doi.org/10.1007/s11270-017-3411-8
Liatsou I, Michail G, Demetriou M, Pashalidis I (2017) Uranium binding by biochar fibres derived from Luffa cylindrica after controlled surface oxidation. J Radioanal Nucl Chem 311:871–875
Hadjittofi L, Prodromou M, Pashalidis I (2014) Activated biochar derived from cactus fibres—preparation, characterization and application on Cu(II) removal from aqueous solutions. Bioresour Technol 159:460–464
Somayajulu BLK, Goldberg ED (1966) Thorium and uranium isotopes in seawater and sediments. Earth Planet Sci Lett 1:102–106
Fanghänel Th, Neck V (2002) Aquatic chemistry and solubility phenomena of actinide oxides/hydroxides. Pure Appl Chem 74:1895–1907
IAEA (2002) Thorium fuel utilization: options and trends. In: Proceedings of three IAEA meetings held in Vienna in 1997, 1998 and 1999. IAEA-TECDOC-1319
Metaxas M, Kasselouri-Rigopoulou V, Galiatsatou P, Konstantopoulou C, Oikonomou D (2003) Thorium removal by different adsorbents. J Hazard Mater B97:71–82
Anirudhan TS, Rejeena SR (2011) Thorium(IV) removal and recovery from aqueous solutions using tannin-modified poly(glycidylmethacrylate)-grafted zirconium oxide densified cellulose. Ind Eng Chem Res 50:13288–13298
Anirudhan TS, Sreekumari SS, Jalajamony S (2013) An investigation into the adsorption of thorium(IV) from aqueous solutions by a carboxylate-functionalised graft copolymer derived from titanium dioxide-densified cellulose. J Environ Radioact 116:141–147
Salem NA, Yakoot SME (2016) Adsorption kinetic and mechanism studies of thorium on nitric acid oxidized activated carbon. Desalin Water Treat 57(58):28313–28322
Chen Y, Wei Y, He L, Tang F (2016) Separation of thorium and uranium in nitric acid solution using silica based anion exchange resin. J Chromatogr A 1466:37–41
Wang Y, Huang C, Li F, Dong Y, Sun X (2017) Process for the separation of thorium and rare earth elements from radioactive waste residues using Cyanex® 572 as a new extractant. Hydrometallurgy 169:158–164
Liatsou I, Pashalidis I, Oezaslan M, Dosche C (2017) Surface characterization of oxidized biochar fibers derived from Luffa cylindrica and lanthanide binding. J Environ Chem Eng 5:4069–4074
Langmuir D, Herman JS (1980) The mobility of thorium in natural waters at low temperatures. Geochim Cosmochim Acta 44:1753–1766
Worthen AJ, Lapitsky Τ (2011) Stabilization of bioderived surfactant/polyelectrolyte complexes through surfactant conjugation to the biopolymer. Colloid Polym Sci 289:1589–1596
Kutahyali C, Eral M (2010) Sorption studies of uranium and thorium on activated carbon prepared from olive stones: kinetic and thermodynamic aspects. J Nucl Mater 396:251–256
Bhalara PD, Punetha D, Balasubramanian K (2015) Kinetic and isotherm analysis for selective thorium(IV) retrieval from aqueous environment using eco-friendly cellulose composite. Int J Environ Sci Technol 12:3095–3106
Riazi M, Keshtkar AR, Moosavian MA (2014) Batch and continuous fixed-bed column biosorption of thorium(IV) from aqueous solutions: equilibrium and dynamic modeling. J Radioanal Nucl Chem 301:493–503
Zhou L, Wang Y, Zou H, Liang X, Zeng K, Liu Z, Adesina AA (2016) Biosorption characteristics of uranium(VI) and thorium(IV) ions from aqueous solution using CaCl2-modified Giant Kelp biomass. J Radioanal Nucl Chem 307:635–644
Li Y, Wang C, Guo Z, Liu C, Wu W (2014) Sorption of thorium(IV) from aqueous solutions by graphene oxide. J Radioanal Nucl Chem 299:1683–1691
Hadjittofi L, Pashalidis I (2016) Thorium removal from acidic aqueous solutions by activated biochar derived from cactus fibers. Desalin Water Treat 57:27864–27868
Pan N, Deng J, Guan D, Jin Y, Xia C (2013) Adsorption characteristics of Th(IV) ions on reduced graphene oxide from aqueous solutions. Appl Surf Sci 287:478–483
Agarwal AK, Kadu MS, Pandhurnekar CP, Muthreja IL (2015) Kinetics study on the adsorption of Ni2+ ions onto flyash. J Chem Technol Metall 60:601–605
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Liatsou, I., Christodoulou, E. & Pashalidis, I. Thorium adsorption by oxidized biochar fibres derived from Luffa cylindrica sponges. J Radioanal Nucl Chem 317, 1065–1070 (2018). https://doi.org/10.1007/s10967-018-5959-1
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-018-5959-1