Abstract
The adsorption of copper (Cu(II)) from aqueous solutions by activated Luffa cylindrica biochar fibres has been investigated by means of batch equilibrium experiments and FTIR spectroscopy. The effect of various physicochemical parameters, such as pH, initial metal concentration, ionic strength, mass of the adsorbent, contact time and temperature, has been evaluated by means of batch type adsorption experiments. FTIR spectroscopy, as well as acid-base titrations, was used for the characterization of the material and the surface species formed. According to the experimental results even at pH 3, the relative sorption is above 85% and the adsorption capacity of the activated biochar fibres for Cu(II) is q max = 248 g kg−1. Moreover, the interaction between the surface carboxylic moieties and Cu(II) results in the formation of very stable inner-sphere complexes (∆G o = −11.2 kJ mol−1 at pH 3 and −22.4 kJ mol−1 at pH 5.5).
Similar content being viewed by others
References
Atkins, P., & De Paula, J. (2010). Physical chemistry. Oxford: Oxford University Press.
Baes, C. F., & Mesmer, R. E. (1976). The hydrolysis of cations. New York: John Wiley & Sons.
Bouhamed, F., Elouear, Z., Bouzid, J., & Ouddane, B. (2016). Multi-component adsorption of copper, nickel and zinc from aqueous solutions onto activated carbon prepared from date stones. Environmental Science and Pollution Research, 23, 15801–15806.
Chen, X., Chen, G., Chen, L., Chen, Y., Lehmann, J., McBride, M. B., & Hay, A. G. (2011). Adsorption of copper and zinc by biochars produced from pyrolysis of hardwood and corn straw in aqueous solution. Bioresource Technology, 102(19), 8877–8884.
Hadjittofi, L., Prodromou, M., & Pashalidis, I. (2014). Activated biochar derived from cactus fibres-preparation, characterization and application on Cu(II) removal from aqueous solutions. Bioresource Technology, 159, 460–464.
Hamdaoui, O. (2017). Adsorption of Cu(II) from aqueous phase by cedar bark. Journal of Dispersion Science and Technology, 38(8), 1087–1091.
Hossain, M. A., Haongo, H., Guo, W. S., & Nguyen, T. V. (2012). Removal of copper from water by adsorption onto banana peel as bioadsorbent. International Journal of GEOMATE, 2(2), 227–234.
Kim, B.-S., Lee, H. W., Park, S. H., Baek, K., Jeon, J.-K., Cho, H. J., Jung, S.-C., Kim, S. C., & Park, Y.-K. (2016). Removal of Cu2+ by biochars derived from green macroalgae. Environmental Science and Pollution Research, 23, 985–994.
Liatsou, I., Michail, G., Demetriou, M., & Pashalidis, I. (2016). Uranium binding by biochar fibres derived from Luffa cylindrica afrer controlled surface oxidation. Journal of Radioanalytical and Nuclear Chemistry. doi:10.1007/s10967-016-5063-3.
Mazali, I. O., & Alves, O. L. (2005). Morphosynthesis: high fidelity inorganic replica of the fibrous network of loofa sponge (Luffa cylindrica). Anais da Academia Brasileira de Ciências, 77(1), 25–31.
Meng, J., Feng, X., Dai, Z., Liu, X., Wu, J., & Xu, J. (2014). Adsorption characteristics of Cu(II) from aqueous solution onto biochar derived from swine manure. Environmental Science and Pollution Research, 21(11), 7035–7046.
Mishra, S., Dwivedi, J., Kumar, A., & Sankararamakrishnan, N. (2015). Studies on salophen anchored micro/meso porous activated carbon fibres for the removal and recovery of uranium. RSC Advances, 5(42), 33023–33036.
Mohan, D., Pittman Jr., C. U., & Steele, P. H. (2006). Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on raft lignin-a biosorbent. Journal of Colloid and Interface Science, 297, 489–504.
Osinska, M. (2016). Removal of lead(II), copper(II), cobalt(II) and nickel(II) ions from aqueous solutions using carbon gels. Journal of sol-gel Science and Technology. doi:10.1007/s10971-016-4256-0.
Prodromou, M., & Pashalidis, I. (2013a). Copper (II) removal from aqueous solutions by adsorption on non-treated and chemically modified cactus fibres. Water Science & Technology, 68(11), 2497–2504.
Prodromou, M., & Pashalidis, I. (2013b). Uranium adsorption by non-treated and chemically modified cactus fibres in aqueous solutions. Journal of Radioanalytical and Nuclear Chemistry, 298(3), 1587–1595.
Sulaymon, A. H., Mohammed, T. J., & Al-Najar, J. (2012). Equilibrium and kinetics studies of adsorption of heavy metals onto activated carbon. Canadian Journal on Chemical Engineering & Technology, 3(4), 86–92.
Trakal, L., Roman, S. R., Sillerova, H., Faturykova, D., & Komarek, M. (2014). Copper removal from aqueous solution using biochar: effect of chemical activation. Arabian Journal of Chemistry, 7, 43–52.
Wu, Z.-C., Wang, Z.-Z., Liu, J., Yin, J.-H., & Kuang, S.-P. (2015). A new porous magnetic chitosan modified by melamine for fast and efficient adsorption of Cu(II) ions. International Journal of Biological Macromolecules, 81, 838–846.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Liatsou, I., Constantinou, P. & Pashalidis, I. Copper Binding by Activated Biochar Fibres Derived from Luffa cylindrica . Water Air Soil Pollut 228, 255 (2017). https://doi.org/10.1007/s11270-017-3411-8
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-017-3411-8