Abstract
Removal of microamounts of 60Co and 137Cs from different aqueous solutions, included NPP trap waters and simulated NPP bottom residues, by coprecipitation with various solid phases was studied. It was showed that coprecipitation of 60Co and 137Cs with the solid phase of K+, Fe3+, and Ni2+ ferrocyanides formed by adding K4[Fe(CN)6], Fe(NO3)3, and Ni(NO3)2 ensures almost 100% removal of both radionuclides from simulated NPP trap waters and more than 99% from simulated NPP bottom residue containing simultaneously up to 400 g l−1 NaNO3 and 3.4 × 10−5 mol l−1 EDTA.
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References
Nikiforov AS, Kulichenko VV, Zhikharev MI (1985) Obezvrezhivanie zhidkikh radioaktivnykh otkhodov (liquid radioactive waste management). Energoatomizdat, Moscow
Onufrienko SV (2002) Treatment of liquid radioactive waste in a new generation of nuclear power plant designs with VVER, Candidate (Tech.) Dissertation, Sankt-Peterburg: Sankt-Peterburg Research and Development Inst. “Atomenergoproekt”
Muratov OE, Stepanov IK, Tsareva SM (2012) Metody pererabotki zhidkikh radioaktivnykh otkhodov (analiticheskii obzor) [Methods for processing liquid radioactive waste (analytical review)]. Ecol Ind Prod (Russia) 3:30–43
Milyutin VV (2008) Physicochemical methods for removing radionuclides from low- and intermediate-level liquid radioactive wastes, Doctoral (Chem.) Dissertation, Moscow: Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Application of Membrane Technologies for Liquid Radioactive Waste Processing (2004) IAEA technical reports series, Vienna: IAEA, N 431
Ryabchikov BE (2008) Ochistka zhidkikh radioaktivnykh otkhodov (Treatment of Liquid Radioactive Wastes). DeLi, Moscow, pp 75–134
El-Dessouky MI, El-Sourougy MR, Aly HF (1990) Investigations on the treatment of low- and medium-level radioactive liquid waste. Isotopenpraxis Isot Environ Health Stud 26:608–611
Lokshin EP, Ivanenko VI, Korneikov RI (2011) Izvlechenie kationov kobalta(II) iz rastvorov, soderzhashchikh etilendiamintetraatsetat- i oksalat-iony (extraction of cobalt (II) cations from solutions containing ethylenediaminetetraacetate and oxalate ions). At Energiya (Russia) 110:285–288
Kulyukhin SA, Gorbacheva MP, Mizina LV, Rumer IA, Konovalova NA, Krasavina EP (2011) Soosazhdenie 60Co s kompleksami nitratov d-elementov s trietilendiaminom iz vodnykh rastvorov (coprecipitation of 60Co with d-element nitrate complexes with triethylenediamine from aqueous solutions). Radiokhimiya (Russia) 53:340–342
Hiraoka M (1982) Crown compounds. Their characteristics and applications, Elsevier, Amsterdam (Translated under the title: Kraun-soedineniya. Svoistva i primenenie (1986) Moscow: Mir.)
Su ACL, Weiher JF (1968) Cobaltous complexes of cyclic polyethers. Inorg Chem 7:176–177
De Vos D, Van Daalen J, Knegt AC, Van Heyningen ThC, Otto LP, Vonk MW, Wijsman AJM, Driessen WL (1975) Complexes of some divalent metals with 18-crown-6. Inorg Nucl Chem 37:1319–1320
Egorov YuV (1975) Statika sorbtsii mikrokomponentov oksigidratami (statics of sorption of microcomponents with oxyhydrates). Atomizdat, Moscow
Seifer GB, YuYa Kharitonov, Tananaev IV (1971) Khimiya ferrotsianidov (chemistry of ferrocyanides). Nauka, Moscow
Wilkinson G, Gillard RD, McCleverty JA (1987) Comprehensive coordination chemistry, vol 7. Pergamon, Oxford, pp 635–900
Kulyukhin SA, Krasavina EP, Gorbacheva MP, Rumer IA, Konovalova NA, Mizina LV, Tanashchuk NV (2007) Sorbtsiya mikrokolichestv 85Sr, 137Cs i 152Eu na smeshannykh geksatsianoferratakh kaliya i uranila iz rastvorov (sorption of the microquantities 85Sr, 137Cs and 152Eu on mixed hexacyanoferrates of potassium and uranyl from solutions). Radiokhimiya (Russia) 49:68–73
Kulyukhin SA, Krasavina EP, Mizina LV, Rumer IA, Tanashchuk NV, Konovalova NA, Murachev AS, Sergeev VV (2005) Izuchenie povedeniya mikrokolichestv 22Na, 85Sr, 137Cs i 152Eu v protsessakh sorbtsii i soosazhdeniya na smeshannom ferrotsianide kaliya i neodima iz rastvorov (studying the behavior of trace 22Na, 85Sr, 137Cs and 152Eu in sorption processes and coprecipitation with a mixed potassium and neodymium ferrocyanide from solutions). Radiokhimiya (Russia) 47:528–533
Kulyukhin SA, Gorbacheva MP, Krasavina EP, Rumer IA (2009) Sokristallizatsiya mikrokolichestv 137Cs, 90Sr i 90Y s tverdoi fazoi smeshannogo ferrotsianida kaliya i neodima iz vodnykh rastvorov (Cocrystallization microquantities 137Cs, 90Sr and 90Y with the solid phase of the mixed potassium and neodymium ferrocyanide from aqueous solutions). Radiokhimiya (Russia) 51:36–39
Mekhail FM, Ibrahim GS, Aly HF (1991) Effect of pH on retention of 134Cs and 60Co from MAW by potassium hexacyanocobaltate(III). Isotopenpraxis Isot Environ Health Stud 27:130–133
Milyutin VV, Gelis VM, Klindukhov VG, Obruchikov AV (2004) Soosazdenie mikrokolichestv Cs s ferrotsianidami razlichnykh metallov (coprecipitation of microamounts of Cs with ferrocyanides of various metals). Radiokhimiya (Russia) 46:444–445
Kulyukhin SA, Konovalova NA, Rumer IA (2010) Soosazdenie 137Cs i 85,90Sr radionuklidov iz vodnykh rastvorov c tverdoi fazoi CsBPh4 i [M(18-kraun-6)]BPh4 (M = Na+, Cs+) (coprecipitation of 137Cs and 85,90Sr radionuclides from aqueous solutions with the solid phases of CsBPh4 and [M(18-crown-6)]BPh4 (M = Na+, Cs+)). Radiokhimiyia (Russia) 52:43–48
Egorov NB, Indik DV, Fiterer IP (2005) Sorption of noble metals by metallosulphides. Materialy 11 Mezdunarodnoi Nauchnoi i Practicheskoi Konferentsii Studentov, Postgraduetov i Molodykh Uchenykh “Sovremennay Technika i Technologii” (Proc. 11th International Scientific and Practical Conference of Students, Postgraduates and Young Scientists; “Modem Techniques and Technologies”. Tomsk. Russian Federation, pp 171–172. https://doi.org/10.1109/spcmtt.2005.4493244
Volkov LV, Kalashnikova MI, Shneerson YaM, Chetvertakov VV (2007) Sposob osazhdeniya nikelya, kobalta i medi selektivno ot zinka iz sulfatnykh rastvorov v vide sulfidov (the method of depositing nickel, cobalt and copper selectively from zinc from sulfate solutions in the form of sulfides). RF Patent 2328537
Orlov SL, Baskov DB (2005) Sposob osazhdeniya sulfidnogo kontsentrata nikelya i kobalta iz sernokislykh rastvorov (method for precipitating the sulphide concentrate of nickel and cobalt from sulfuric acid solutions). RF Patent 2281978
Ovchinnikov YuA, Ivanov VG, Shkrob AM (1974) Membranno-aktivnye kompleksony (Membrane-Active Complexones). Nauka, Moscow
Kulyukhin SA, Konovalova NA, Rumer IA, Gorbacheva MP, Mizina LV (2010) Izvlechenie 131I i 137Cs iz modelnogo rastvora trapnykh vod AES (extraction of 131I and 137Cs from the model trap solution of NPPs). Radiokhimiyia (Russia) 52:435–441
Mikheev SV (2010) Sorption and precipitation processes for removing cesium radionuclides from highly saline solutions, Candidate (Chem.) Dissertation, Moscow: Frumkin Inst. of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Pshinko GN (2008) Effect of complexing agents on processes of sorption purification of waters containing cobalt. Khimiua i Tekhnol Vody (Ukr) 30:358–364
Gordon J (2004) Where courage is present. Nucl. Eng. Int. 3:8–9
Jansons EJ, Ievins AF (1959) Tetrafenilboraty i ikh primenenie v analiticheskoi khimii (tetraphenylborates and their application in analytical chemistry). Uspekhi Khimii (Russia) 28:980–989
Lidin RA, Andreeva LL, Molochko VA (2006) Konstanty neorganicheskikh veshchestv (Constants of Inorganic Substances). Drofa, Moscow
Plyasunova NV, Zhang Yu, Muhammed M (1998) Critical evaluation of thermodynamics of complex formation of metal ions in aqueous solutions. V. hydrolysis and hydroxo-complexes of Co2+ at 298.15 K. Hydrometallurgy 48:153–169
Rastvorimost’ sul’fidov (Solubility of Sulfides) (2017) http://www.chemicals-el.ru/chemicals-2844-1.html. Accessed 02 Nov 2017
Spravochnik khimika (Chemist’s Handbook) (1964). Khimiya, Moscow 3:162
Zhilov VI, Kotov VYu, Tsirlin AA (2003) Geksatsianometallaty kaliya-natriya K2Na[M(CN)6] (M = Fe, Co) (Potassium-sodium hexachiocyanometallates K2Na[M(CN)6] (M = Fe, Co)). Zhurnal Neorg Khimii (Russia) 48:2027–2028
Zaitsev BA, Kulakov SI, and Malinina EI (1983) A study of the possibility of sorption decontamination of NPP wastes containing boric acid from cesium and cobalt radionuclides on inorganic Sorvents, Report no. 80 066 906, Moscow: Institute of Physical Chemistry, Russian Academy of Sciences, and All-Union Research Institute for Operation of Nuclear Power Plants
Kulyukhin SA, Konovalova NA, Gorbacheva MP, Mizina LV, Rumer IA (2013) Soosazhdenie 60Co s tverdymi fazami kompleksnykh soedinenii razlichnogo sostava iz vodnykh rastvorov (coprecipitation of 60Co with solid phases of complex compounds of various compositions from aqueous solutions). Radiokhimiya (Russia) 55:131–135
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Kulyukhin, S.A., Kulemin, V.V., Krasavina, E.P. et al. Recovery of 60Co and 137Cs with various solid phases from aqueous solutions of different chemical composition. J Radioanal Nucl Chem 316, 869–884 (2018). https://doi.org/10.1007/s10967-018-5714-7
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DOI: https://doi.org/10.1007/s10967-018-5714-7