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Abraham Model Expressions for Describing Water-to-Diethylene Glycol and Gas-to-Diethylene Glycol Solute Transfer Processes at 298.15 K

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Abstract

A gas chromatographic headspace analysis method was used to experimentally determine gas-to-liquid partition coefficients and infinite dilution activity dilution for 14 different aliphatic and cyclic hydrocarbons (alkanes, cycloalkanes, alkenes, alkynes), eight different aromatic compounds (benzene, alkylbenzenes, halobenzenes), five different chloroalkanes (dichloromethane, trichloromethane, 1-chlorobutane, 1,2-dichloropropane, isopropylbromide), tetrahydrofuran, butyl acetate, and acetonitrile dissolved in diethylene glycol at 298.15 K. Solubilities were also measured at 298.15 K for 31 crystalline nonelectrolyte organic solutes including several polycyclic aromatic hydrocarbons and substituted benzoic acid derivatives. The experimental results of the headspace chromatographic and spectroscopic solubility measurements were converted to gas-to-diethylene glycol and water-to-diethylene glycol partition coefficients, and molar solubility ratios using standard thermodynamic relationships. Expressions were derived for solute transfer into diethylene glycol from the calculated partition coefficients and solubility ratios. Mathematical correlations based on the Abraham model describe the observed partition coefficient and solubility data to within 0.14 log10 units (or less).

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Acknowledgements

The work of Igor Sedov and Timur Magsumov was performed according to the Russian Government Program of Competitive Growth of Kazan Federal University. Elizabeth Higgins thanks the University of North Texas’s Texas Academy of Math and Science (TAMS) program for a summer research award.

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Authors and Affiliations

  1. Department of Chemistry, Kazan Federal University, Kremlevskaya 18, Kazan, Russia, 420008

    Igor A. Sedov & Timur I. Magsumov

  2. Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, Denton, TX, 76203, USA

    Erin Hart, Elizabeth Higgins, Damini Grover, Heidi Zettl, Minaz Zad & William E. Acree Jr.

  3. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ, UK

    Michael H. Abraham

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  1. Igor A. Sedov
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  2. Timur I. Magsumov
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  8. William E. Acree Jr.
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  9. Michael H. Abraham
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Correspondence to William E. Acree Jr..

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Sedov, I.A., Magsumov, T.I., Hart, E. et al. Abraham Model Expressions for Describing Water-to-Diethylene Glycol and Gas-to-Diethylene Glycol Solute Transfer Processes at 298.15 K. J Solution Chem 46, 331–351 (2017). https://doi.org/10.1007/s10953-017-0579-x

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  • DOI: https://doi.org/10.1007/s10953-017-0579-x

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