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Polyhedral Oligomeric Silsesquioxane and Polyorganosilicon Hybrid Materials and Their Usage in the Removal of Methylene Blue Dye

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Abstract

Polyhedral oligomeric silsesquioxane and organosilicon polymers, which are important classes of inorganic–organic hybrid materials, have emerged as effective adsorbents for the removal of contaminants from the wastewater. In this study, two hybrid materials polyhedral oligomeric silsesquioxane (1-(3-(polyhedraloligomericsilsesquioxane)propoxy)ethane-1,2-diol, POSS-diol) and organosilicon polymer (PGPTS) as adsorbents have been synthesized from 3-glycidyloxypropyltrimethoxysilane (GPTS) monomers by using basic catalyst tetrapropylammonium hydroxide (Pr4NOH(aq)) and acidic catalyst chlorotinbis[trimethylsilyl)]amide (SnCl(HMDS)), respectively. These hybrid materials POSS-diol and PGPTS were characterized by a few instrumental techniques such as NMR, FTIR, GPC, XRD, BET and then used in the removal of methylene blue (MB) dye from aqueous solutions. These hybrid silicon materials showed an exceptionally high degree of adsorption for MB dye compared to GPTS hydrolyzed with HCl(aq) (POSS-epoxide) and inorganic–organic hybrid materials of Al, Ti, and Zr. The reason for this high adsorption capacity of MB has been tried to be determined mechanically and discussed.

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References

  1. G.Ö. Kayan, A. Kayan, J. Polym. Environ. 29, 3477 (2021)

    Article  CAS  Google Scholar 

  2. H.S. Jamwal, S. Kumari, G.S. Chauhan, N.S. Reddy, J.H. Ahn, J. Environ. Chem. Eng. 5, 103 (2017)

    Article  CAS  Google Scholar 

  3. M. Oz, D.E. Lorke, M. Hasan, G.A. Petroianu, Med. Res. Rev. 31, 93 (2011)

    Article  PubMed  PubMed Central  CAS  Google Scholar 

  4. E. Alver, A.Ü. Metin, F. Brouers, Int. J. Biol. Macromol. 154, 104 (2020)

    Article  PubMed  CAS  Google Scholar 

  5. A. Kausar, R. Shahzad, J. Iqbal, N. Muhammad, S.M. Ibrahim, M. Iqbal, Int. J. Biol. Macromol. 149, 1059 (2020)

    Article  PubMed  CAS  Google Scholar 

  6. S. Varjani, P. Rakholiya, H.Y. Ng, S. You, J.A. Teixeira, Bioresour. Technol. 314, 123728 (2020)

    Article  PubMed  CAS  Google Scholar 

  7. M.R. Gadekar, M.M. Ahammed, Appl. Water Sci. 10, 160 (2020)

    Article  CAS  Google Scholar 

  8. P. Cañizares, F. Martínez, C. Jiménez, J. Lobato, M.A. Rodrigo, Ind. Eng. Chem. Res. 45, 8749 (2006)

    Article  CAS  Google Scholar 

  9. E. Oyarce, B. Butter, P. Santander, J. Sánchez, J. Environ. Chem. Eng. 9, 106297 (2021)

    Article  CAS  Google Scholar 

  10. G. Fadillah, T.A. Saleh, S. Wahyuningsih, E.N.K. Putri, S. Febrianastuti, Chem. Eng. J. 378, 122140 (2019)

    Article  CAS  Google Scholar 

  11. G.Ö. Kayan, A. Kayan, J. Inorg. Organomet. Polym. Mater. 31, 3613 (2021)

    Article  CAS  Google Scholar 

  12. Z. Sun, K. Qu, J. Li, S. Yang, B. Yuan, Z. Huang, Z. Guo, Adv. Compos. Hybrid Mater. 4, 1413 (2021)

    Article  CAS  Google Scholar 

  13. S. Sun, B. Sun, Y. Wang, M.F. Antwi-Afari, H.Y. Mi, Z. Guo, C. Liu, C. Shen, Sep. Purif. Technol. 278, 119621 (2022)

    Article  CAS  Google Scholar 

  14. M. Rafique, A.J. Shaikh, R. Rasheed, M.B. Tahir, S.S.A. Gillani, A. Usman, M. Imran, A. Zakir, Z.U. Khan, F. Rabbani, J. Inorg. Organomet. Polym. Mater. 28, 2455 (2018)

    Article  CAS  Google Scholar 

  15. J. Zheng, L. Sun, C. Jiao, Q. Shao, J. Lin, D. Pan, N. Naik, Z. Guo, Colloids Surf. A 623, 126629 (2021)

    Article  CAS  Google Scholar 

  16. X. Liu, J. Tian, Y. Li, N. Sun, S. Mi, Y. Xie, Z. Chen, J. Hazard. Mater. 373, 397 (2019)

    Article  PubMed  CAS  Google Scholar 

  17. T. Fazal, A. Razzaq, F. Javed, A. Hafeez, N. Rashid, U.S. Amjad, F. Rehman, J. Hazard. Mater. 390, 121623 (2020)

    Article  PubMed  CAS  Google Scholar 

  18. F.J. Tuli, A. Hossain, A.F. Kibria, A.R.M. Tareq, S.M. Mamun, A.A. Ullah, Environ. Nanotechnol. Monit. Manag. 14, 100354 (2020)

    Google Scholar 

  19. N. Somsesta, V. Sricharoenchaikul, D. Aht-Ong, Mater. Chem. Phys. 240, 122221 (2020)

    Article  CAS  Google Scholar 

  20. P.M.K. Reddy, P. Verma, C. Subrahmanyam, J. Taiwan Inst. Chem. Eng. 58, 500 (2016)

    Article  CAS  Google Scholar 

  21. S. Swamiappan, S. Ganesan, V. Sekar, S. Devaraj, A. Subramanian, V.K. Ponnusamy, P. Kathirvel, Int. J. Appl. Ceram. Technol. 18, 902 (2021)

    Article  CAS  Google Scholar 

  22. W. Chen, Y. Guo, X. Mi, Y. Yu, G. Li, Desalin. Water Treat. 188, 257 (2020)

    Article  CAS  Google Scholar 

  23. A. Ahmad, N. Khan, B.S. Giri, P. Chowdhary, P. Chaturvedi, Bioresour. Technol. 306, 123202 (2020)

    Article  PubMed  CAS  Google Scholar 

  24. A.H. Jawad, A.S. Abdulhameed, Surf. Interfaces 18, 100422 (2020)

    Article  CAS  Google Scholar 

  25. T.C.N. Tan, T.K. Sen, Sep. Sci. Technol. 55, 1036 (2020)

    Article  CAS  Google Scholar 

  26. S.K. Bozbas, U. Ay, A. Kayan, Desalin. Water Treat. 51, 7208 (2013)

    Article  CAS  Google Scholar 

  27. A. Kayan, M.O. Arican, Y. Boz, U. Ay, S.K. Bozbas, J. Environ. Chem. Eng. 2, 935 (2014)

    Article  CAS  Google Scholar 

  28. A. Kayan, Ind. Eng. Chem. Res. 51, 13339 (2012)

    Article  CAS  Google Scholar 

  29. A. Kayan, Adv. Compos. Hybrid Mater. 2, 34 (2019)

    Article  CAS  Google Scholar 

  30. I.V. Melnyk, V.V. Tomina, N.V. Stolyarchuk, G.A. Seisenbaeva, V.G. Kessler, J. Mol. Liq. 336, 116301 (2021)

    Article  CAS  Google Scholar 

  31. S. Hossain, M. Shahruzzaman, S.F. Kabir, M.S. Rahman, S. Sultana, A.K. Mallik, P. Haque, M. Takafuji, M.M. Rahman, J. Sci.: Adv. Mater. Devices 6, 254 (2021)

    CAS  Google Scholar 

  32. J.J. Chruściel, E. Leśniak, Prog. Polym. Sci. 41, 67 (2015)

    Article  CAS  Google Scholar 

  33. M. Pálmai, L.N. Nagy, J. Mihály, Z. Varga, G. Tárkányi, R. Mizsei, I.C. Szigyártó, T. Kiss, T. Kremmer, A. Bóta, J. Colloid Interface Sci. 390, 34 (2013)

    Article  PubMed  CAS  Google Scholar 

  34. S. Altmann, J. Pfeiffer, Monatsh. Chem. 134, 1081 (2003)

    Article  CAS  Google Scholar 

  35. L. Alvarez-Rodriguez, J.A. Cabeza, P. Garcia-Alvarez, D. Polo, Organometallics 32, 3557 (2013)

    Article  CAS  Google Scholar 

  36. A. Kayan, Des. Monomers Polym. 18, 545 (2015)

    Article  CAS  Google Scholar 

  37. K. Piana, U. Schubert, Chem. Mater. 6, 1504 (1994)

    Article  CAS  Google Scholar 

  38. Y. Bai, Q. Yang, M. Li, Y. Yu, J. Clean. Prod. 314, 127932 (2021)

    Article  CAS  Google Scholar 

  39. Q. Liu, D. Wang, Z. Li, Z. Li, X. Peng, C. Liu, Y. Zhang, P. Zheng, Materials 13, 2145 (2020)

    Article  PubMed Central  CAS  Google Scholar 

  40. F. Altan, Master Thesis, Kocaeli University, 1–87 (2018)

  41. A. Kayan, J. Appl. Polym. Sci. 123, 3527 (2012)

    Article  CAS  Google Scholar 

  42. A. Kayan, J. Appl. Polym. Sci. 136, 47074 (2019)

    Google Scholar 

  43. A. Kayan, O. Mert, J. Inorg. Organomet. Polym. Mater. 24, 1055 (2014)

    Article  CAS  Google Scholar 

  44. E. Cerrahoğlu, A. Kayan, D. Bingöl, J. Inorg. Organomet. Polym. Mater. 27, 427 (2017)

    Article  CAS  Google Scholar 

  45. A. Kayan, J. Inorg. Organomet. Polym. Mater. 25, 1345 (2015)

    Article  CAS  Google Scholar 

  46. A. Kayan, J. Inorg. Organomet. Polym. Mater. 26, 640 (2016)

    Article  CAS  Google Scholar 

  47. I.A. Salem, T.A. Fayed, M.N. El-Nahass, M. Dawood, J. Pharm. Appl. Chem. 4, 30 (2018)

    Article  Google Scholar 

  48. D. Teng, Y. Xu, T. Zhao, X. Zhang, Y. Li, Y. Zeng, J. Hazard. Mater. 425, 128004 (2022)

    Article  PubMed  CAS  Google Scholar 

  49. H. Li, D. Shen, H. Lu, F. Wu, X. Chen, R. Pleixats, J. Pan, Sep. Pur. Technol. 277, 119453 (2021)

    Article  CAS  Google Scholar 

  50. S.K. Bozbas, M. Karabulut, Int. J. Environ. Anal. Chem. (2021). https://doi.org/10.1080/03067319.2021.1873312

    Article  Google Scholar 

  51. J. Zhao, W. Li, L. Fan, Q. Quan, J. Wang, C. Xiao, J. Colloid Interface Sci. 534, 480 (2019)

    Article  PubMed  CAS  Google Scholar 

  52. E.C. Peres, J.C. Slaviero, A.M. Cunha, A. Hosseini-Bandegharaei, G.L. Dotto, J. Environ. Chem. Eng. 6, 649 (2018)

    Article  CAS  Google Scholar 

  53. F.D.C. de Paula, L. Effting, G.G.C. Arízaga, R.M. Giona, A.L. Tessaro, F.M. Bezerra, A. Bail, Environ. Technol. (2021). https://doi.org/10.1080/09593330.2021.1871662

    Article  PubMed  Google Scholar 

  54. K.J.L. Dos Santos, G.E.D.S. Dos Santos, Í.M.G.L. de Sá, A.H. Ide, J.L. da SilvaDuarte, S.H.V. de Carvalho, J.I. Soletti, L. Meili, Bioresour. Technol. 293, 122093 (2019)

    Article  PubMed  CAS  Google Scholar 

  55. L. Meili, P.V. Lins, C.L.P.S. Zanta, J.I. Soletti, L.M.O. Ribeiro, C.B. Dornelas, T.L. Silva, M.G.A. Vieira, Appl. Clay Sci. 168, 11 (2019)

    Article  CAS  Google Scholar 

  56. K.M. Khalil, W.A. Elhamdy, K.M. Mohammed, A.S. Abd-El-Aziz, Mater. Chem. Phys. 282, 125881 (2022)

    Article  CAS  Google Scholar 

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Acknowledgements

Financial support from the research foundation of Kocaeli University (project No: 2021/2719) is gratefully acknowledged.

Funding

This study was supported by Kocaeli Üniversitesi [Grant No. 2719/2021].

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Authors and Affiliations

  1. Metallurgical & Materials Engineering Department, Faculty of Chemical and Metallurgical Engineering, Istanbul Technical University, Maslak, 34469, Istanbul, Turkey

    Gizem Özge Kayan

  2. Department of Chemistry, Kocaeli University, 41380, Kocaeli, Turkey

    Asgar Kayan

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Kayan, G.Ö., Kayan, A. Polyhedral Oligomeric Silsesquioxane and Polyorganosilicon Hybrid Materials and Their Usage in the Removal of Methylene Blue Dye. J Inorg Organomet Polym 32, 2781–2792 (2022). https://doi.org/10.1007/s10904-022-02288-y

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