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Adsorption of Dyes from Aqueous Solutions onto Multi-functional PPy/CS Exfoliated Nanohybrid for Fashionable Layered Polymer Nanocomposites

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Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition) (EMCEI 2019)

Part of the book series: Environmental Science and Engineering ((ENVSCIENCE))

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Abstract

Wastewater treatment has become immensely challenging. Adsorption process has an obvious drawback since it does not lead to dyes degradation in the end. A novel Polypyrrole/Chitosan/exfoliated Grapheneoxide/Montmorillonite (PPy@CS/MMT/GO) nanohybrid was synthesized using in situ polymerization of pyrrole on a high surface area CS/MMT/GO nanocomposite to give multi-functional adsorbent with high ability for removal of neutral, anionic, and cationic dyes. The PPy@CS/MMT/GO surface morphology was characterized by various instrumental techniques such as SEM, TEM, and XRD. The removal efficiency for Biebrich scarlet (99%), Eosin Y (97%), neutral red (95%), Safranin O (66%), and Titan yellow (85%) was estimated. The adsorption trend was rapid in the case of Biebrich scarlet, Eosin Y, and neutral red, consequently. The R2 values for second-order model indicated the high reliability for the developed regression models in explaining experimental data of adsorption of Saf-O and Tit-Y onto PPy@CS/MMT/GO. Langmiur and Freundlich adsorption models were used to describe the equilibrium isotherm for Tit-Y and Saf-O. Thermodynamic studies demonstrated that the adsorption of Saf-O and Tit-Y onto PPy@CS/MMT/GO was feasible endothermic and spontaneous. The reutilization of the nanohybrid which adsorbed the dyes was examined.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Tanta University, 31527, Tanta, Egypt

    Nehal A. Salahuddin, Hosny A. EL-Daly, Rehab G. El Sharkawy & Beshoy T. Nasr

Authors
  1. Nehal A. Salahuddin
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  2. Hosny A. EL-Daly
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  3. Rehab G. El Sharkawy
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  4. Beshoy T. Nasr
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Corresponding author

Correspondence to Nehal A. Salahuddin .

Editor information

Editors and Affiliations

  1. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Mohamed Ksibi

  2. Appliquées et Technologies, Institut Supérieur des Sciences, Gabès, Tunisia

    Achraf Ghorbal

  3. University of Calabria, Rende, Cosenza, Italy

    Sudip Chakraborty

  4. School of Engineering (ISEP), Polytechnic of Porto, Porto, Portugal

    Helder I. Chaminé

  5. Università degli Studi di Roma, Roma, Roma, Italy

    Maurizio Barbieri

  6. University of Naples, Naples, Italy

    Giulia Guerriero

  7. High Institute of Biotechnology, University of Sfax, Sfax, Tunisia

    Olfa Hentati

  8. Faculty of Engineering, Water and Water Structure Engineering Department, Zagazig University, Zagazig, Egypt

    Abdelazim Negm

  9. University of Geneva, Genève, Geneve, Switzerland

    Anthony Lehmann

  10. ECT Oekotoxikologie GmbH, Flörsheim am Main, Hessen, Germany

    Jörg Römbke

  11. Centre for Environmental+Marine Studies, University of Aveiro, Aveiro, Portugal

    Armando Costa Duarte

  12. Department of Geography, Justus-Liebig-University Giessen, Gießen, Hessen, Germany

    Elena Xoplaki

  13. Springer Nature, Heidelberg, Baden-Württemberg, Germany

    Nabil Khélifi

  14. Gembloux Agro-Bio Tech, University of Liège, Gembloux, Belgium

    Gilles Colinet

  15. University of Aveiro, Aveiro, Portugal

    João Miguel Dias

  16. Faculty of Medicine of Sfax, University of Sfax, Sfax, Tunisia

    Imed Gargouri

  17. Institut de Physique du Globe de Paris, Université de Paris, Paris, France

    Eric D. Van Hullebusch

  18. FOTOAIR-CIEMAT, Madrid, Madrid, Spain

    Benigno Sánchez Cabrero

  19. Department of Civil Engineering, University of Salerno, Fisciano, Italy

    Settimio Ferlisi

  20. College of Engineering, Swansea University, Swansea, UK

    Chedly Tizaoui

  21. Sfax National School of Engineering, University of Sfax, Sfax, Tunisia

    Amjad Kallel

  22. Swiss Federal Institute of Technology, Lausanne, Switzerland

    Sami Rtimi

  23. Department of Mining Engineering, Suleyman Demirel University, Isparta, Turkey

    Sandeep Panda

  24. Université Clermont Auvergne, Polytech, Aubière, France

    Philippe Michaud

  25. Institute of Chemical Technology, University of Stuttgart, Stuttgart, Baden-Württemberg, Germany

    Jaya Narayana Sahu

  26. High School of Science and Technology, University of Sousse, Sousse, Tunisia

    Mongi Seffen

  27. SEED DICIV, University of Salerno, Fisciano, Italy

    Vincenzo Naddeo

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Salahuddin, N.A., EL-Daly, H.A., El Sharkawy, R.G., Nasr, B.T. (2021). Adsorption of Dyes from Aqueous Solutions onto Multi-functional PPy/CS Exfoliated Nanohybrid for Fashionable Layered Polymer Nanocomposites. In: Ksibi, M., et al. Recent Advances in Environmental Science from the Euro-Mediterranean and Surrounding Regions (2nd Edition). EMCEI 2019. Environmental Science and Engineering(). Springer, Cham. https://doi.org/10.1007/978-3-030-51210-1_76

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