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The Application of Encapsulated Trinuclear Cobalt Cluster Complex in Y Zeolite in the One-Pot Multi-Component Synthesis of Spiro Indoline Derivatives

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Abstract

A trinuclear cobalt cluster complex was prepared into the nanocages of dealuminated Y zeolite ([Co3(O)(CH3COO)6(py)3]-DAZY) and characterized by XRD, FT-IR, EDS, FE-SEM, AAS and BET-BJH analyses. The elemental content of Cobalt in [Co3(O)(CH3COO)6(py)3]-DAZY was estimated to be about 5.5 mg/g support on the basis of atomic absorption spectroscopy. The catalytic activity of [Co3(O)(CH3COO)6(py)3]-DAZY was evaluated in the synthesis of tri series of spiro indoline derivatives in a library synthesis via the condensation of isatins, malononitrile or ethylcyano acetate, and active methylene compounds (4-hydroxycoumarine, dimedone and pyrazoline-5-one). Corresponding products were obtained in good to excellent yields. Short reaction time, high yield of product, structural diversity of products, absence of organic solvents and the use of water as a green solvent, non-toxicity, stability and reusability of the catalyst are noteworthy advantages of the current work.

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Acknowledgements

The authors thank Hakim Sabzevari University for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Hakim Sabzevari University, Sabzevar, 96179-76487, Iran

    Seyedeh Fatemeh Hojati, Atefeh Sadat Kaheh & Fatemeh Daghestani

  2. Department of Chemistry, University of Maragheh, Maragheh, 55181-83111, Iran

    Maryam Moosavifar

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  1. Seyedeh Fatemeh Hojati
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  2. Atefeh Sadat Kaheh
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Correspondence to Seyedeh Fatemeh Hojati.

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Hojati, S.F., Kaheh, A.S., Moosavifar, M. et al. The Application of Encapsulated Trinuclear Cobalt Cluster Complex in Y Zeolite in the One-Pot Multi-Component Synthesis of Spiro Indoline Derivatives. J Clust Sci 33, 1387–1397 (2022). https://doi.org/10.1007/s10876-021-02063-y

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