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Vertical Interpenetration of 1D Water Column and 1D Coordination Polymer Chain

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Abstract

Hydrothermal reaction of 1-amino-1-phenylmethane-1,1-diphosphonic acid (APhMDPH4), ZnO and 2,2′-bipyridyl (2,2-bipy) affords a novel zinc phosphonate compound, i.e. Zn3(L1H)2(2,2′-bipy)3 · 18H2O (1), in which the phosphonate ligand, L1H4, is generated via an in situ concentration reaction. This compound is a one-dimensional (1D) zigzag coordination polymer chain and a huge, complex 1D water column. The 1D water column and the 1D coordination polymer chain are joined together to form a vertical interpenetrating network, which is reported for the first time.

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Acknowledgments

This work was supported by grants of the National Nature Science Foundation of China (No. 20671074). We are thankful to Ming Li for helpful discussions.

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Authors and Affiliations

  1. College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, 430072, People’s Republic of China

    Shuo-Ping Chen, Yi-Xuan Yuan, Ling-Ling Pan & Liang-Jie Yuan

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  1. Shuo-Ping Chen
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  2. Yi-Xuan Yuan
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  3. Ling-Ling Pan
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Correspondence to Liang-Jie Yuan.

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Chen, SP., Yuan, YX., Pan, LL. et al. Vertical Interpenetration of 1D Water Column and 1D Coordination Polymer Chain. J Inorg Organomet Polym 18, 384–390 (2008). https://doi.org/10.1007/s10904-008-9215-y

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  • DOI: https://doi.org/10.1007/s10904-008-9215-y

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