Abstract
In this study, bismuth oxide (Bi2O3) and carbon quantum dots (CQDs) were synthesized, structural, morphological and optical properties of the obtained samples were investigated. Novel polymer nanocomposite films were obtained by using the casting method with introducing the produced Bi2O3 and CQDs nanoparticles to polyvinyl alcohol (PVA) at different rates. The structural features of the resulting polymer nanocomposite films were investigated by X-ray diffraction technique. The optical parameters of composite films were investigated using the absorption and transmittance spectra. The increase in the amount of Bi2O3 additives in the composite PVA films decreased the optical transmittance and energy band gap. Again, the increasing Bi2O3-doped to the composite films increased the reflectance, absorption coefficient and extinction coefficient values. The refractive index increased from 1.946 to 1.980 for Bi2O3 doped samples and the refractive index reached 2.468 with introducing CQDs to polymer composite film. The yellowness of polymer nanocomposite films was remarkably enhanced with CQDs addition. This novel material has potential use in fields in different fields, including optoelectronics and sensors.
Similar content being viewed by others
Data availability
Not Applicable.
Code availability
Not Applicable.
References
H.M. Gayitri, M.Q.A. Al-Gunaid, F. H. AL-Ostoot, N. Al-Zaqri, A. Boshaala, and A. P. Gnanaprakash, Investigation on opto-electrical, structural and electro-chemical performance of PVA/ZnBi2MoO7 hybrid nanocomposites. Polym. Bull. 80, 773 (2023)
H. Eskalen, H. Yaykaşlı, M. Kavgacı, A. Kayış, J. Mater. Sci.: Mater. Electron. 33, 4643 (2022)
Y. Kavun, H. Eskalen, S. Kerli, M. Kavgaci, Appl. Radiat. Isot. 177, 109918 (2021)
H. Eskalen, M. Çeşme, S. Kerli, Ş Özğan, J. Chem. Res. 45, 428 (2021)
M.V. Muthamma, S.G. Bubbly, S.B. Gudennavar, K.C.S. Narendranath, J. Appl. Polym. Sci. 136(37), 47949 (2019)
P. Tiamduangtawan, C. Kamkaew, S. Kuntonwatchara, E. Wimolmala, K. Saenboonruang, Radiat. Phys. Chem. 177, 109164 (2020)
M. Yildirim, M. Gökçen, T. Tunç, I. Uslu, Ş Altindal, Polym. Eng. Sci. 54, 1811 (2014)
M. Irfan, M. Aslam, Z.A. Raza, Polym. Bull. 80, 791 (2023)
Y. Badali, Y. Azizian-Kalandaragh, İ Uslu, Ş. Altindal 31, 8033 (2020)
F. Sedaghatdoust-Bodagh, Y. Azizian-Kalandaragh, J. Optoelectron. Adv. Mater. 19, 663 (2017)
W.E. Mahmoud, A.A. Al-Ghamdi, F. Al-Agel, Polym. Adv. Technol. 22, 2055 (2011)
B.M. Abunahel, S. Iskandar, N.Z. Mustafa, N. Azman, Appl. Phys. 124, 828 (2018)
A Singh, R Prasad, KP, SP and undefined 2018, in Ieeexplore.Ieee.Org (2018 International conference on applied electromagnetics, signal processing and communication (AESPC), nd)
Y. Wang, J. Su, T. Li, P. Ma, H. Bai, Y. Xie, M. Chen, W. Dong, ACS Appl. Mater. Interfaces 9, 36281 (2017)
M. Çeşme, H. Eskalen, Bilecik Seyh Edebali University J. Sci. 8, 924 (2021)
M. Aslan, H. Eskalen, Fullerenes. Nanotubes Carbon Nanostructures 29, 1026 (2021)
S.K. Başkaya, B. Tahta, S. Uruş, H. Eskalen, M. Çeşme, Ş Özğan, Biomass. Convers. Biorefin. 1, 1 (2022)
M. Çeşme, H. Eskalen, Cumhuriyet Sci. J. 41, 808 (2020)
H. Eskalen, Appl. Phys.. A Mater. Sci. Process 126, 1 (2020)
H.U. Castañeda-Serna, G. Calderón-Domínguez, A. García-Bórquez, M. de la P. Salgado-Cruz, and R. R. Farrera Rebollo, Structural and luminescent properties of CQDs produced by microwave and conventional hydrothermal methods using pelagic Sargassum as carbon source. Opt. Mater. (Amst) 126, 112156 (2022)
H. Eskalen, M. Kavgaci, A. Kayiş, Ş Özğan, Eskişehir Techl University J. ScI. Technol. Appl. Sci. Eng. 22, 366 (2021)
H. Eskalen, S. Uruş, S. Cömertpay, A.H. Kurt, Ş Özgan, Ind. Crops. Prod. 147, 112209 (2020)
M. Çeşme, H. Eskalen, S.K. Başkaya, Fruits and Vegetable Wastes: Valorization to Bioproducts and Platform Chemicals, in Fluorescent Carbon Dots from Vegetable and Fruit Wastes and Their Applications. ed. by R.C. Ray (Springer Nature Singapore, Singapore, 2022)
S. Sharma, S.K. Mehta, A.O. Ibhadon, S.K. Kansal, J. Colloid. Interface. Sci. 533, 227 (2019)
Z.K. Heiba, A.M. El-naggar, M.B. Mohamed, Y. Altowairqi, A.M. Kamal, Appl. Phys. A Mater. Sci. Process 127, 1 (2021)
M. Koosha, S. Hamedi, Prog. Org. Coat. 127, 338 (2019)
P. Terzioğlu, F. Güney, F.N. Parın, İ Şen, S. Tuna, Food Packag Shelf Life 30, 100742 (2021)
A.Z. Szeremeta, S. Pawlus, A. Nowok, K. Grzybowska, M. Zubko, A. Molak, J. Am. Ceram. Soc. 103, 3732 (2020)
V.N. Sonkusare, R.G. Chaudhary, G.S. Bhusari, A.R. Rai, H.D. Juneja, Nano-Str. Nano-Objects 13, 121 (2018)
T.A. Gadhi, A. Hernández-Gordillo, M. Bizarro, P. Jagdale, A. Tagliaferro, S.E. Rodil, Ceram Int. 42, 13065 (2016)
J. Krishna Reddy, B. Srinivas, V. Durga Kumari, M. Subrahmanyam, Chem. Cat. Chem. 1(4), 492 (2009)
K. Jlassi, A. Khalaf Ahmed, H. Mutahir, A. M. Abdullah, M. M. Chehimi, and I. Krupa, (n.d.).
H. Eskalen, M. Kavgacı, A. Kayış, Ş Özğan, Eskişehir Techl. Univ. J Sci. Technol. Appl.. SciEng. 22, 366 (2021)
Y. Ni, P. Zhou, Q. Jiang, Q. Zhang, X. Huang, Y. Jing, Dyes Pigm. 197, 109923 (2022)
H. Eskalen, S. Uruş, M. Kavgacı, H.V. Kalmış, B. Tahta, Biomass Convers. Biorefin. 1, 1 (2023)
I. Mondal, D. Samanta, M. Shaw, M. Abdus Salam Shaik, M. Kr Mahto, R. Basu, A. Bhattacharya, and A. Pathak, Spectrochim. Acta A Mol. Biomol. Spectrosc. 294, 122530 (2023)
J. Shen, S. Shang, X. Chen, D. Wang, Y. Cai, Mater. Sci. Eng., C 76, 856 (2017)
K. Qu, J. Wang, J. Ren, X. Qu, Chem. A Eur. J. 19, 7243 (2013)
J. Jia, W. Lu, S. Cui, C. Dong, S. Shuang, Microchim. Acta 188, 1 (2021)
G. Liu, Z. Chen, X. Jiang, D.Q. Feng, J. Zhao, D. Fan, W. Wang, Sens Actuators. B Chem. 228, 302 (2016)
K. Huang, Q. He, R. Sun, L. Fang, H. Song, L. Li, Z. Li, Y. Tian, H. Cui, J. Zhang, Chem. Phys. Lett. 731, 136586 (2019)
F. Akhgari, N. Samadi, K. Farhadi, J. Fluoresc. 27, 921 (2017)
A.F. Shaikh, M.S. Tamboli, R.H. Patil, A. Bhan, J.D. Ambekar, B.B. Kale, J. Nanosci. Nanotechnol. 19, 2339 (2018)
A. Kurdekar, L.A.A. Chunduri, E.P. Bulagonda, M.K. Haleyurgirisetty, V. Kamisetti, I.K. Hewlett, Microfluid Nanofluidics 20, 1 (2016)
M. Mohammadi, A. Tavajjohi, A. Ziashahabi, N. Pournoori, S. Muhammadnejad, H. Delavari, R. Poursalehi, Micro. Nano Lett. 14, 239 (2019)
Z.K. Heiba, M.B. Mohamed, J. Mol. Struct. 1181, 507 (2019)
S.S. Najm, Mater. Today Proc. 61, 632 (2022)
S.B. Aziz, A.Q. Hassan, S.J. Mohammed, W.O. Karim, M.F.Z. Kadir, H.A. Tajuddin, N.N.M.Y. Chan, Nanomaterials 9(2), 216 (2019)
N.J. Mohammed, Z.S. Rasheed, A.S. Hassan, Al-Mustansiriyah J. Sici. 29, 118 (2018)
G. Abdul Hadi Abdul Jabbar, A. Abdulmunem Saeed, and M. F. Hadi AL-Kadhemy 2022 Int. J. Nanoelectron. Mater.
M.I. Mohammed, I.S. Yahia, S.A. El-Mongy, J. Appl. Polym. Sci. 140, e53821 (2023)
M.F. Zaki, A. Tayel, A.B. El Basaty, Bull. Mater. Sci. 45, 1 (2022)
F.M. Ali, F. Maiz, Physica B Condens. Matter. 530, 19 (2018)
A.M. Al-Fa’ouri, O.A. Lafi, H.H. Abu-Safe, M. Abu-Kharma, Arabian. J. Chem. 16, 104535 (2023)
Z. Faiza, A. Malik, A.A. Khattak, Alahmadi, and S. U. Butt, Materials 15(15), 5154 (2022)
S.H. Zyoud, A. Almoadi, T.H. AlAbdulaal, M.S. Alqahtani, F.A. Harraz, M.S. Al-Assiri, I.S. Yahia, H.Y. Zahran, M.I. Mohammed, Sh. Mohamed, Abdel-wahab, Polymers 15(15), 1351 (2023)
S.A.M. Issa, D.E. Abulyazied, A.W. Alrowaily, H.A. Saudi, E.S. Ali, A.M.A. Henaish, H.M.H. Zakaly, J. Rare Earths (2023). https://doi.org/10.1016/j.jre.2023.02.013
A. Atta, A.M. Abdel Reheem, E. Abdeltwab, Ion beam irradiation effects on surface morphology and optical properties of ZnO/PVA composites. Surf Rev Letters (2020). https://doi.org/10.1142/S0218625X19502147
P. Dhatarwal, R.J. Sengwa, Physica B Condens. Matter. 613, 412989 (2021)
H.E. Ali, M. Abdel-Aziz, A.M. Ibrahiem, M.A. Sayed, H.S.M. Abd-Rabboh, N.S. Awwad, H. Algarni, M. Shkir, M.Y. Khairy, Microstructure Study and Linear/Nonlinear Optical Performance of Bi-Embedded PVP/PVA Films for Optoelectronic and Optical Cut-Off Applications. Polymers 14(9), 1741 (2022)
T.H. AlAbdulaal, A. Almoadi, I.S. Yahia, H.Y. Zahra, M.S. Alqahtani, E.S. Yousef, K.I. Hussein, M. Jalalah, F.A. Harraz, M.S. Al-Assiri, Optik (Stuttg) 268, 169741 (2022)
T.S. Soliman, S.A. Vshivkov, J. Non. Cryst. Solids 519, 119452 (2019)
M.S. Ismail, A.A. Elamin, F. Abdel-Wahab, Y.H. Elbashar, M.M. Mahasen, Opt. Mater. (Amst) 131, 112639 (2022)
G. A. Hadi Abdul Jabbar, A. A. Saeed, and M. F. Hadi AL-Kadhemy, Kuwait (2023) J. Sci.
S. Alashrah, Y. El-Ghoul, F.M. Almutairi, M.A.A. Omer, Development, characterization and valuable use of novel dosimeter film based on PVA polymer doped nitro blue tetrazolium dye and AgNO3 for the accurate detection of low X-ray doses. Polymers 13, 3140 (2021)
I. Dudeja, R. K. Mankoo, A. Singh, and J. Kaur, (n.d.).
Y. Amaregouda, K. Kamanna, T. Gasti, V. Kumbar, J. Polym. Environ. 30, 2559 (2022)
S.R. Kanatt, M.S. Rao, S.P. Chawla, A. Sharma, Food Hydrocoll 29, 290 (2012)
Acknowledgements
This study was supported by the Scientific Research Projects Coordination Unit of Kahramanmaraş Sütçü İmam University. Project number 2021/1-7 YLS.
Funding
Kahramanmaraş Sütçü Imam Üniversitesi, 2021/1-7 YLS., Hasan Eskalen
Author information
Authors and Affiliations
Contributions
The manuscript was written with the contributions of all authors. All authors have approved the final version of the manuscript. MK: Experimental measurements, investigation, HE: Experimental measurements, investigation, review & editing, supervision.
Corresponding author
Ethics declarations
Conflict of interest
The authors declared that they have no conflicts of interest to this work. We declare that we do not have any commercial or associative interest that represents a conflict of interest in connection with the work submitted.
Ethical approval
Not Applicable.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Kavgacı, M., Eskalen, H. Morphology, structure and optical properties of PVA nanocomposites reinforced with bismuth oxide nanoparticles and carbon quantum dots. J Mater Sci: Mater Electron 34, 1229 (2023). https://doi.org/10.1007/s10854-023-10617-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10854-023-10617-1