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Electrochemical behavior of cerium (III) hydroxide thin-film electrode in aqueous and non-aqueous electrolyte for supercapacitor applications

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Abstract

Cerium (III) hydroxide, Ce(OH)3 thin films were synthesized by the simple successive ionic layer adsorption reaction (SILAR) method at room temperature. Their physicochemical properties were characterized by scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and Fourier transform infrared spectroscopy (FTIR). The electrochemical properties of Ce(OH)3 electrodes for supercapacitors were investigated by cyclic voltammetry (CV) and galvanostatic charge discharge (GCD) analysis in aqueous and non-aqueous electrolytes. The surface morphological studies from SEM depicted that the sponge-like morphology transformed to thread-like structure after potential cycling. The sharp peaks in the FTIR spectrum determined the existence of Ce–O stretching mode. The maximum specific capacitance of electrode material is 78 Fg−1 and power density is 13.33 KW Kg−1 in non-aqueous electrolyte. The calculated b value (< 0.5) from cyclic voltammetry indicated the capacitance arrived because of the diffusion control process.

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Acknowledgements

Authors (JM and SG) are grateful to DST-FIST (SR/FST/CSI-273/2016C), Ministry of Science & Technology, Govt. of India for proving instrumental facilities.

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Authors have not received any funding from any source for this research work.

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Authors and Affiliations

  1. Department of Physics, JJT University, Jhunjhunu, 333001, Rajasthan, India

    P. A. Sonar & Sandhya Nitin

  2. Department of Chemistry, Rani Channamma University, PB NH-4, Belagavi, 591156, Karnataka, India

    S. G. Sanjeevagol & J. Manjanna

  3. Department of Physics, Rani Channamma University, PB NH-4, Belagavi, 591156, Karnataka, India

    V. D. Patake

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  1. P. A. Sonar
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  2. S. G. Sanjeevagol
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  4. V. D. Patake
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Contributions

PAS contributed to preparation and data acquisition, SGS contributed to data acquisition, JM contributed to writing, reviewing, and editing of the manuscript. VDP contributed to conceptualization, methodology, and writing of the original draft, SN contributed to reviewing and editing of the manuscript and conceptualization.

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Correspondence to V. D. Patake or Sandhya Nitin.

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Sonar, P.A., Sanjeevagol, S.G., Manjanna, J. et al. Electrochemical behavior of cerium (III) hydroxide thin-film electrode in aqueous and non-aqueous electrolyte for supercapacitor applications. J Mater Sci: Mater Electron 33, 25787–25795 (2022). https://doi.org/10.1007/s10854-022-09270-x

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