Abstract
Hydrotalcites are layered double metal hydroxides (LDH) that are widely used in many fields, owing to their large specific surface area, rich interface, and stable structure. Of these, NiFe-LDH is the most typical material used in the field of electromagnetic wave absorption. In this study, NiFe-LDH was synthesized by hydrothermal synthesis and subjected to liquid-phase shearing with graphite to synthesize the composite material C/NiFe-LDH. The results show that C/NiFe-LDH displays a strong electromagnetic wave absorption capacity, with a maximum reflection loss of − 51.8 dB at a thickness of 3.5 mm. The maximum effective absorption bandwidth is 4 GHz (10.8–14.8 GHz). Therefore, C/NiFe-LDH is expected to become a candidate material for efficient electromagnetic wave absorption.
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Abbreviations
- EM:
-
Electromagnetic
- f E :
-
Effective absorption bandwidth
- H c :
-
Coercivity
- HRTEM:
-
High-resolution transmission electron microscopy
- LDH:
-
Layered double metal hydroxide
- M s :
-
Saturation magnetization
- RL:
-
Reflection loss
- SEM:
-
Scanning electron microscopy
- TEM:
-
Transmission electron microscopy
- VNA:
-
Vector network analyzer
- VSM:
-
Vibrating sample magnetometry
- XPS:
-
X-ray photoelectron spectroscopy
- XRD:
-
X-ray diffraction
References
L.J. Yang, X.D. Zhou, Z.R. Jia, H.L. Lv, Y.T. Zhu, J.C. Liu, Z.H. Yang, Selective tailoring of covalent bonds on graphitized hollow carbon spheres towards controllable porous structure and wideband electromagnetic absorption. Carbon 167, 843–851 (2020)
M.A. Kazakova, N.V. Semikolenova, E.Y. Korovin, V.A. Zhuravlev, A.G. Selyutin, D.A. Velikanov, S.I. Moseenkov, A.S. Andreev, O.B. Lapina, V.I. Suslyaev, M.A. Matsko, V.A. Zakharov, J.B.D. de Lacaillerie, Co/multi-walled carbon nanotubes/polyethylene composites for microwave absorption: tuning the effectiveness of electromagnetic shielding by varying the components ratio. Compos. Sci. Technol. 207, 108731 (2021)
Y.Y. Zhou, L.Y. Ma, R. Li, D. Chen, Y.Y. Lu, Y.Y. Cheng, X.X. Luo, H. Xie, W.C. Zhou, Enhanced heat-resistance property of aluminum-coated carbonyl iron particles as microwave absorption materials. J. Magn. Magn. Mater. 524, 167681 (2021)
C. Wang, T.T. Xu, C.A. Wang, Microwave absorption properties of C/(C@CoFe) hierarchical core-shell spheres synthesized by using colloidal carbon spheres as templates. Ceram. Int. 42, 9178–9182 (2016)
Y.H. Hou, H.L. Yuan, X.L. Qu, H. Chen, L.C. Li, Synthesis and high-performance electromagnetic wave absorption of SiC@C composites. Mater. Lett. 209, 90–93 (2017)
Y. Lu, P.G. Yang, Y.H. Li, D.D. Wen, J.S. Luo, S.H. Wang, F. Wu, L. Fang, Y. Pang, A facile synthesis of NiFe-layered double hydroxide and mixed metal oxide with excellent microwave absorption properties. Molecules 26, 5046 (2021)
Z.X. Zhou, W.J. Zhao, Z.W. Zhao, H.Q. Fu, Boosted interfacial polarization from the multidimensional core-shell-flat heterostructure CNP@PDA@GO/rGO for enhanced microwave absorption. Ind. Eng. Chem. Res. 60, 12343–12352 (2021)
Z.H. Wang, L.X. Yang, Y. Zhou, C. Xu, M. Yan, C. Wu, NiFe LDH/MXene derivatives interconnected with carbon fabric for flexible electromagnetic wave absorption. ACS Appl. Mater. Interfaces 13, 16713–16721 (2021)
T.T. Yu, J.F. Qiu, J. Liao, X.Y. Wang, W. Chen, Y. Cheng, W. Wang, Y.F. Song, Topological transformation strategy for layered double hydroxide@carbon nanofibers as highly efficient electromagnetic wave absorber. J. Alloy. Compd. 867, 159046 (2021)
Y.R. Lai, S.Y. Wang, D.L. Qian, S.T. Zhong, Y.P. Wang, S.J. Han, W. Jiang, Tunable electromagnetic wave absorption properties of nickel microspheres decorated reduced graphene oxide. Ceram. Int. 43, 12904–12914 (2017)
X. Zhang, J. Xu, X.Y. Liu, S. Zhang, H.R. Yuan, C.L. Zhu, X.T. Zhang, Y.J. Chen, Metal organic framework-derived three-dimensional graphene-supported nitrogen-doped carbon nanotube spheres for electromagnetic wave absorption with ultralow filler mass loading. Carbon 155, 233–242 (2019)
J. Yan, X.D. Zhang, W.R. Zheng, L.Y.S. Lee, Interface engineering of a 2D–C3N4/NiFe-LDH heterostructure for highly efficient photocatalytic hydrogen evolution. ACS Appl. Mater. Interfaces 13, 24723–24733 (2021)
Z.Y. Zhao, Q. Shao, J.Y. Xue, B.L. Huang, Z. Niu, H.W. Gu, X.Q. Huang, J.P. Lang, Multiple structural defects in ultrathin NiFe-LDH nanosheets synergistically and remarkably boost water oxidation reaction. Nano Res. 15, 310–316 (2021)
B.B. Jiang, W.C. Cheong, R.Y. Tu, K. Sun, S.J. Liu, K.L. Wu, H.S. Shang, A.J. Huang, M. Wang, L.R. Zheng, X.W. Wei, C. Chen, Regulating the electronic structure of NiFe layered double hydroxide/reduced graphene oxide by Mn incorporation for high-efficiency oxygen evolution reaction. Sci. China Mater. 64, 2729–2738 (2021)
Q. Chang, H.S. Liang, B. Shi, X.L. Li, Y.T. Zhang, L.M. Zhang, H.J. Wu, Ethylenediamine-assisted hydrothermal synthesis of NiCo2O4 absorber with controlled morphology and excellent absorbing performance. J. Colloid Interface Sci. 588, 336–345 (2021)
Q.L. Sun, L. Sun, Y.Y. Cai, W. Ye, S.J. Xu, T. Ji, G.Q. Yuan, Fe3O4-intercalated reduced graphene oxide nanocomposites with enhanced microwave absorption propertiesm. Ceram. Int. 45, 18298–18305 (2019)
Q.L. Sun, Y. Ji, L.F. He, X.Y. Long, In situformation of Fe3O4/N-doped carbon coating on the surface of carbon fiber with improved electromagnetic wave-absorption property. RSC Adv. 10, 30443–30450 (2020)
C. Li, Y. Huang, J.J. Chen, Dopamine-assisted one-pot synthesis of graphene@Ni@C composites and their enhanced microwave absorption performance. Mater. Lett. 154, 136–139 (2015)
D. An, L.Z. Bai, S.S. Cheng, Z.Y. Zhang, X.Y. Duan, Z.J. Sun, Y.Q. Liu, Synthesis and electromagnetic wave absorption properties of three-dimensional nano-flower structure of MoS2/polyaniline nanocomposites. J. Mater. Sci. Mater. Electron. 30, 13948–13956 (2019)
C. Liu, J. Qiao, X. Zhang, D.M. Xu, N.N. Wu, L.F. Lv, W. Liu, J.R. Liu, Bimetallic MOF-derived porous CoNi/C nanocomposites with ultra-wide band microwave absorption properties. New J. Chem. 43, 16546–16554 (2019)
Z.G. Gao, J.Q. Zhang, S.J. Zhang, D. Lan, Z.H. Zhao, K.C. Kou, Strategies for electromagnetic wave absorbers derived from zeolite imidazole framework (ZIF-67) with ferrocene containing polymers. Polymer 202, 122679 (2020)
Y. Liu, X.M. Du, C.Y. Wu, Y.N. Liu, Y.Q. Liu, G.Z. Zhao, Reduced graphene oxide decorated with ZnO microrods for efficient electromagnetic wave absorption performance. J. Mater. Sci. Mater. Electron. 31, 8637–8648 (2020)
M. Qin, L.M. Zhang, X.R. Zhao, H.J. Wu, Lightweight Ni foam-based ultra-broadband electromagnetic wave absorber. Adv. Funct. Mater. 31, 2103436 (2021)
Y.C. Du, W.W. Liu, R. Qiang, Y. Wang, X.J. Han, J. Ma, P. Xu, Shell thickness-dependent microwave absorption of core-shell Fe3O4@C composites. ACS Appl. Mater. Interfaces 6, 12997–13006 (2014)
F.Y. Wang, N. Wang, X.J. Han, D.W. Liu, Y.H. Wang, L.R. Cui, P. Xu, Y.C. Du, Core-shell FeCo@carbon nanoparticles encapsulated in polydopamine-derived carbon nanocages for efficient microwave absorption. Carbon 145, 701–711 (2019)
Z.J. Shen, H.L. Yang, Z.Q. Xiong, Y. Xie, C.B. Liu, Hollow core-shell CoNi@C and CoNi@NC composites as high-performance microwave absorbers. J. Alloy. Compd. 871, 159574 (2021)
Z.J. Qu, Y. Wang, W. Wang, D. Yu, Robust magnetic and electromagnetic wave absorption performance of reduced graphene oxide loaded magnetic metal nanoparticle composites. Adv. Powder Technol. 32, 194–203 (2021)
Y.Q. Ge, C.P. Li, G.I.N. Waterhouse, Z.M. Zhang, ZnFe2O4@PDA@polypyrrole composites with efficient electromagnetic wave absorption properties in the 18–40 GHz region. J. Mater. Sci. 56, 10876–10891 (2021)
H.H. Liu, Y.J. Li, M.W. Yuan, G.B. Sun, H.F. Li, S.L. Ma, Q.L. Liao, Y. Zhang, In situ preparation of cobalt nanoparticles decorated in N-doped carbon nanofibers as excellent electromagnetic wave absorbers. ACS Appl. Mater. Interfaces 10, 22591–22601 (2018)
M.L. Ma, W.T. Li, Z.Y. Tong, Y. Ma, Y.X. Bi, Z.J. Liao, J. Zhou, G.L. Wu, M.X. Li, J.W. Yue, X.Y. Song, X.Y. Zhang, NiCo2O4 nanosheets decorated on one-dimensional ZnFe2O4@SiO2@C nanochains with high-performance microwave absorption. J. Colloid Interface Sci. 578, 58–68 (2020)
H.R. Yuan, F. Yan, C.Y. Li, C.L. Zhu, X.T. Zhang, Y.J. Chen, Nickel nanoparticle encapsulated in few-layer nitrogen-doped graphene supported by nitrogen-doped graphite sheets as a high-performance electromagnetic wave absorbing material. ACS Appl. Mater. Interfaces 10, 1399–1407 (2018)
Q. Wu, B.L. Wang, Y.G. Fu, Z.F. Zhang, P.F. Yan, T. Liu, MOF-derived Co/CoO particles prepared by low temperature reduction for microwave absorption. Chem. Eng. J. 410, 128378 (2021)
H.F. Qiu, X.Y. Zhu, P. Chen, J.L. Liu, X.L. Zhu, Self-etching template method to synthesize hollow dodecahedral carbon capsules embedded with Ni-Co alloy for high-performance electromagnetic microwave absorption. Compos. Commun. 20, 100354 (2020)
S.H. Zhou, Y. Huang, X.D. Liu, J. Yan, X.S. Feng, Synthesis and microwave absorption enhancement of CoNi@SiO2@C hierarchical structures. Ind. Eng. Chem. Res. 57, 5507–5516 (2018)
X.K. Wang, Y.K. Guan, R.R. Zhang, P.P. Zhou, Z. Song, M. Wang, L.X. Wang, Q.T. Zhang, Facile synthesis of cobalt nanoparticles embedded in a rod-like porous carbon matrix with excellent electromagnetic wave absorption performance. Ceram. Int. 47, 643–653 (2021)
D. Ding, Y. Wang, X.D. Li, R. Qiang, P. Xu, W.L. Chu, X.J. Han, Y.C. Du, Rational design of core-shell Co@C microspheres for high-performance microwave absorption. Carbon 111, 722–732 (2017)
M.L. Dong, M.Y. Peng, W. Wei, H.J. Xu, C.T. Liu, C.Y. Shen, Improved microwave absorption performance of double helical C/Co@CNT nanocomposite with hierarchical structures. J. Mater. Chem. C 9, 2178–2189 (2021)
D. Lan, Z.G. Gao, Z.H. Zhao, G.L. Wu, K.C. Kou, H.J. Wu, Double-shell hollow glass microspheres@Co2SiO4 for lightweight and efficient electromagnetic wave absorption. Chem. Eng. J. 408, 127313 (2021)
W.Y. Dai, F. Chen, H. Luo, Y. Xiong, X. Wang, Y.Z. Cheng, R.Z. Gong, Synthesis of yolk-shell structured carbonyl iron@void@nitrogen doped carbon for enhanced microwave absorption performance. J. Alloy. Compd. 812, 152083 (2020)
S. Li, L.F. Lin, L.X. Yao, H.F. Zheng, Q. Luo, W.J. Xu, C.Y. Zhang, Q.S. Xie, L.S. Wang, D.L. Peng, MOFs-derived Co-C@C hollow composites with high-performance electromagnetic wave absorption. J. Alloy. Compd. 856, 158183 (2021)
H. Zhang, A.J. Xie, C.P. Wang, H.S. Wang, Y.H. Shen, X.Y. Tian, Room temperature fabrication of an RGO-Fe3O4 composite hydrogel and its excellent wave absorption properties. RSC Adv. 4, 14441–14446 (2014)
D. Li, H.Y. Liao, H. Kikuchi, T. Liu, Microporous Co@C nanoparticles prepared by dealloying CoAl@C precursors: achieving strong wideband microwave absorption via controlling carbon shell thickness. ACS Appl. Mater. Interfaces 9, 44704–44714 (2017)
Y. Liu, X.F. Zhou, Z.R. Jia, H.J. Wu, G.L. Wu, Oxygen vacancy-induced dielectric polarization prevails in the electromagnetic wave-absorbing mechanism for Mn-based MOFs-derived composites. Adv. Funct. Mater. 2204499, 1–10 (2022)
Y. Guo, X. Jian, L. Zhang, C.H. Mu, L.J. Yin, J.L. Xie, N. Mahmood, S.X. Dou, R.C. Che, L.J. Deng, Plasma-induced FeSiAl@Al2O3@SiO2 core-shell structure for exceptional microwave absorption and anti-oxidation at high temperature. Chem. Eng. J. 384, 123371 (2020)
Z.J. Li, H. Lin, S.Q. Ding, H.L. Ling, T. Wang, Z.Q. Miao, M. Zhang, A. Meng, Q.D. Li, Synthesis and enhanced electromagnetic wave absorption performances of Fe3O4@C decorated walnut shell-derived porous carbon. Carbon 167, 148–159 (2020)
R.L. Wang, M. He, Y.M. Zhou, S.X. Nie, Y.J. Wang, W.Q. Liu, Q. He, W.T. Wu, X.H. Bu, X.M. Yang, Metal-organic frameworks self-templated cubic hollow Co/N/C@MnO2 composites for electromagnetic wave absorption. Carbon 156, 378–388 (2020)
Y. Yuan, S.C. Wei, Y. Liang, B. Wang, Y.J. Wang, W. Xin, X.L. Wang, Y. Zhang, Solvothermal assisted synthesis of CoFe2O4/CNTs nanocomposite and their enhanced microwave absorbing properties. J. Alloy. Compd. 867, 159040 (2021)
K. Manna, S.K. Srivastava, Fe3O4@carbon@polyaniline trilaminar core-shell composites as superior microwave absorber in shielding of electromagnetic pollution. ACS Sustain. Chem. Eng. 5, 10710–10721 (2017)
M.T. Qiao, X.F. Lei, Y. Ma, L.D. Tian, X.W. He, K.H. Su, Q.Y. Zhang, Application of yolk-shell Fe3O4@N-doped carbon nanochains as highly effective microwave-absorption material. Nano Res. 11, 1500–1519 (2018)
Funding
This study was financially supported by the Nantong Science and Technology Project (JC2020083) and Basic Science (natural science) research project of Jiangsu Province (21KJA430010).
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RW was involved in methodology, investigation, writing the original draft, and writing—review and editing. QS was responsible for conceptualization and supervision. XL contributed to resources and funding acquisition. WY carried out data curation and validation. GY took part in conceptualization and formal analysis.
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Wang, R., Sun, Q., Long, X. et al. Synthesis of C/NiFe-LDH composites for enhanced electromagnetic wave absorption. J Mater Sci: Mater Electron 33, 24581–24593 (2022). https://doi.org/10.1007/s10854-022-09169-7
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DOI: https://doi.org/10.1007/s10854-022-09169-7