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Effect of soldering time on the microstructure and mechanical properties of SnBi/SACBN/Cu solder joint

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Abstract

To improve the mechanical properties of SnBi solder joints, Sn–Ag–Cu–Bi–Ni (SACBN) bumps were pre-soldered on the Cu pads, and thus the SnBi/SACBN/Cu solder joints were obtained in this work. By comparing with SnBi/Cu, the effects of soldering time on the microstructure and mechanical properties of SnBi/SACBN/Cu solder joint were investigated. Experimental results show that increasing soldering time suppresses the composition segregation in SnBi bulk, but it leads to the coarsening of β-Sn and Bi-rich phases. As the soldering time increases, the interfacial IMC layers in the SnBi/Cu and the SnBi/SACBN/Cu solder joints gradually become thicker. The growth of the (Cu, Ni)6Sn5 interfacial IMC in SnBi/SACBN/Cu is mainly based on solid–solid diffusion. Its growth rate is lower than that of the IMC whose growth is dominantly due to liquid–solid diffusion in SnBi/Cu. The addition of SACBN bulk decreases the hardness of the SnBi bulk. Meanwhile, the hardness shows a decreasing trend as the soldering time increases. When the soldering time is 40 s and 160 s, SACBN bulk suppresses the propagation of fracture in SnBi bulk and improves the shear strength of the solder joint. As the soldering time reaches 280 s, the shear strength of the SnBi/SACBN/Cu solder joint decreases, and the fracture is mainly located in the SnBi bulk.

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The datasets generated during and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  1. G. Ren, I.J. Wilding, M.N. Collins, Alloying influences on low melt temperature SnZn and SnBi solder alloys for electronic interconnections. J. Alloy. Compd. 665, 251–260 (2016)

    Article  CAS  Google Scholar 

  2. Y. Liu, B. Ren, M. Zhou, X. Zeng, F. Sun, Microstructure, mechanical, and thermal behaviors of SnBi/Cu solder joint enhanced by porous Cu. J. Mater. Sci-Mater. El. 31, 8258–8267 (2020)

    Article  CAS  Google Scholar 

  3. Z. Lai, D. Ye, Microstructure and properties of Sn-10Bi-xCu solder alloy/joint. J. Electron. Mater. 45, 3702–3711 (2016)

    Article  CAS  Google Scholar 

  4. Y.A. Shen, S. Zhou, J. Li, C.H. Yang, S. Huang, S.K. Lin, H. Nishikawa, Sn-3.0 Ag-0.5Cu/Sn-58Bi composite solder joint assembled using a low-temperature reflow process for PoP technology. Mater. Des. 183, 108144 (2019)

    Article  CAS  Google Scholar 

  5. X. Zhao, M. Muraoka, M. Saka, Length-dependent electromigration behavior of Sn58Bi solder and critical length of electromigration. J. Electron. Mater. 46, 1287–1292 (2017)

    Article  CAS  Google Scholar 

  6. L. Zhao, Z. He, Z. Wang, L. Su, X. Lu, Simulation and experimental investigation on active thermography test of the solder balls. IEEE. T. Ind. Inform. 16, 1617–1624 (2019)

    Article  Google Scholar 

  7. C. Wu, J. Shen, C. Peng, Effects of trace amounts of rare earth additions on the microstructures and interfacial reactions of Sn57Bi1Ag/Cu solder joints. J. Mater. Sci. Mater. El. 23, 14–21 (2012)

    Article  CAS  Google Scholar 

  8. J. Shen, C. Wu, S. Li, Effects of rare earth additions on the microstructural evolution and microhardness of Sn30Bi0.5Cu and Sn35Bi1Ag solder alloys. J. Mater. Sci. Mater. El. 23, 156–163 (2012)

    Article  CAS  Google Scholar 

  9. D.L. Ma, P. Wu, Effects of Zn addition on mechanical properties of eutectic Sn-58Bi solder during liquid-state aging. Trans. Nonferr. Metal. Soc. 25, 1225–1233 (2015)

    Article  CAS  Google Scholar 

  10. W. Zhu, W. Zhang, W. Zhou, P. Wu, Improved microstructure and mechanical properties for SnBi solder alloy by addition of Cr powders. J. Alloy. Compd. 789, 805–813 (2019)

    Article  CAS  Google Scholar 

  11. Z. Wang, Q.K. Zhang, Y.X. Chen, Z.L. Song, Influences of Ag and In alloying on Sn-Bi eutectic solder and SnBi/Cu solder joints. J. Mater. Sci. Mater. El. 30, 18524–18538 (2019)

    Article  CAS  Google Scholar 

  12. S.Y. Zhao, Z.H. Cai, Y.P. Zhang, Y.H. Zhang, Effect of Sb doping on microstructure and mechanical properties of tin-bismuth near-eutectic solder. Welding Technology. 39, 47–50 (2010)

    Google Scholar 

  13. X. Hu, H. Qiu, X. Jiang, Effect of Ni addition into the Cu substrate on the interfacial IMC growth during the liquid-state reaction with Sn-58Bi solder. J. Mater. Sci. Mater. El. 30, 1907–1918 (2019)

    Article  CAS  Google Scholar 

  14. L. Yang, S. Ma, G. Mu, Improvements of microstructure and hardness of lead-free solders doped with Mo nanoparticles. Mater. Lett. 304, 130654 (2021)

    Article  CAS  Google Scholar 

  15. S.M. Lee, J.W. Yoon, S.B. Jung, Interfacial reaction and mechanical properties between low melting temperature Sn–58Bi solder and various surface finishes during reflow reactions. J. Mater. Sci. Mater. El. 26, 1649–1660 (2015)

    Article  CAS  Google Scholar 

  16. W.R. Myung, Y. Kim, S.B. Jung, Evaluation of the bondability of the epoxy-enhanced Sn-58Bi solder with ENIG and ENEPIG surface finishes. J. Electron. Mater. 44, 4637–4645 (2015)

    Article  CAS  Google Scholar 

  17. J. Kim, W.R. Myung, S.B. Jung, Effects of aging treatment on mechanical properties of Sn-58Bi epoxy solder on ENEPIG-surface-finished PCB. J. Electron. Mater. 45, 5895–5903 (2016)

    Article  CAS  Google Scholar 

  18. H.F. Zou, Q.K. Zhang, Z.F. Zhang, Interfacial microstructure and mechanical properties of SnBi/Cu joints by alloying Cu substrate. Mater. Sci. Eng. A 532, 167–177 (2012)

    Article  CAS  Google Scholar 

  19. F. Wang, D.Y. Li, Z.J. Zhang, Improvement on interfacial structure and properties of Sn-58Bi/Cu joint using Sn-30Ag-05Cu solder as barrier. J. Mater. Sci. Mater. El. 28, 19051–19060 (2017)

    Article  CAS  Google Scholar 

  20. Y. Liu, R. Xu, H. Zhang, F. Sun, Microstructure and shear behavior of solder joint with Sn58Bi/Sn3.0Ag0.5Cu/Cu superposition structure. J. Mater. Sci. Mater. El. 30, 14077–14084 (2019)

    Article  CAS  Google Scholar 

  21. Y. Liu, J. Chang, M. Zhou, Y. Xue, X. Zeng, F. Sun, Microstructure and shear behavior of Sn58Bi/Cu solder joint enhanced by SnAgCuBiNi bump. Mod. Phys. Lett. B 34, 2050413 (2020)

    Article  CAS  Google Scholar 

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The authors declare that no funds, grants, or other support were received during the preparation of this manuscript.

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YL: conceptualization, methodology, investigation, and writing—review & editing. JC: investigation, writing—original draft. YX: supervision. RC: investigation. HL: review & editing. SZ: review & editing. XZ: supervision.

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Correspondence to Yuxiong Xue.

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Liu, Y., Chang, J., Xue, Y. et al. Effect of soldering time on the microstructure and mechanical properties of SnBi/SACBN/Cu solder joint. J Mater Sci: Mater Electron 33, 8270–8280 (2022). https://doi.org/10.1007/s10854-022-07981-9

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  • DOI: https://doi.org/10.1007/s10854-022-07981-9

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