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Studies on growth and characterization of (E)-N′-[4-(dimethylamino) benzylidene]-4-hydroxybenzohydrazide hemihydrate: a nonlinear optical material

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Abstract

Hydrazone compound (E)-N′-[4-(dimethylamino) benzylidene]-4-hydroxybenzohydrazide hemihydrate (DMABHBH) was synthesized and single crystals of DMABHBH were grown by solvent evaporation method at room temperature. Molecular structure of DMABHBH compound was confirmed by 1H and 13C nuclear magnetic resonance techniques. The presence of functional groups was confirmed by Fourier transform infrared and FT Raman spectral analyses. The X-ray crystal structure was elucidated at 173 K by single crystal X-ray diffraction and the results were compared with the corresponding values obtained at 298 K. The compound crystallizes in the chiral monoclinic space group P21. Mechanical stability of the grown crystals was estimated from the Vicker’s microhardness test. Powder second harmonic generation efficiency of DMABHBH is about 1.1 times that of potassium dihydrogen phosphate. DMABHBH is found to show optical limiting behavior at high input light intensities, the third order nonlinear optical absorption coefficient measured using open aperture Z-scan studies, is 0.95 × 10−11 m/W. Anti-bacterial activity was studied using the well and disc diffusion methods.

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Acknowledgements

One of the authors (AS) thanks the University Grant Commission, New Delhi for the award of a UGC: Meritorious Fellowship [File No. 4-1/2008 (BSR)]. The author (KR) thanks the Department of Physics and Nanotechnology for extending its facilities created under DST-FIST. Authors thank Central Instrumentation Facility, Pondicherry University, Pondicherry, Department of Visual Communication, Srimad Andavan Arts and Science and College and Advanced Instrumentation Research Facility, Jawaharlal Nehru University, New Delhi for extending the instrumentation facilities.

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Authors and Affiliations

  1. PG and Research Department of Physics, Srimad Andavan Arts and Science College, Tiruchirappalli, 620 005, India

    A. Subashini

  2. Crystal Growth and Thin Film Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli, 620 024, India

    A. Subashini & R. Ramesh Babu

  3. Department of Environmental Biotechnology, Bharathidasan University, Tiruchirappalli, 620 024, India

    Poornima Priyadharsani, K. Thamaraiselvi & V. Veeramani

  4. Light and Matter Physics Group, Raman Research Institute, C. V. Raman Avenue, Sadashivanagar, Bangalore, 560 080, India

    Priya Rose & Reji Philip

  5. Institute of Physics, University of Neuchatel, Rue Emile-Argand 11, 2000, Neuchâtel, Switzerland

    Helen Stoeckli-Evans

  6. Department of Bio-medical Engineering, Aarupadai Veedu Institute of Technology, Vinayaga Mission’s Research Foundation, Vinayaga Nagar, Paiyanoor, Tamil Nadu, 603 104, India

    K. Ramamurthi

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  1. A. Subashini
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Subashini, A., Priyadharsani, P., Thamaraiselvi, K. et al. Studies on growth and characterization of (E)-N′-[4-(dimethylamino) benzylidene]-4-hydroxybenzohydrazide hemihydrate: a nonlinear optical material. J Mater Sci: Mater Electron 30, 2638–2646 (2019). https://doi.org/10.1007/s10854-018-0539-2

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