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Supercapacitors based on ternary nanocomposite of TiO2&Pt@graphenes

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Abstract

The electrochemical properties of graphene can be significantly enhanced due to the incorporating of hetero-atoms into the graphene. In this article Crumpled-like TiO2–Pt/graphene nanocomposite from graphene oxide (GO), titanium (III) chloride (TiCl3) and Hydrogen hexa chloro palatinate (H2PtCl6) was synthesized via a simple reflux strategy and employed as a simple capacitor electrode material. The nanocomposite was characterized by XRD, XPS, FESEM, HRTEM and the electrochemical properties were investigated by cyclic voltammetry (CV). Electrochemical characterization for introduced nanocomposite indicated that the corresponding specific capacitance is 160 F/g (at 5 mV/s) with good stability. The high electrochemical performance is recognized to the presence of Pt nanoparticles on the nanocomposite and graphene distinct characteristics. To the best of our knowledge this is the first report on TiO2–Pt/graphene nanocomposite as an electrical double layer capacitor material.

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Acknowledgments

This Research was financially supported by National Research Foundation of Korea (NRF) Grant funded by the Korean Government (MSIP) (No. 2014R1A4A1008140) and Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (No. NRF-2014R1A1A2008489).

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Correspondence to Nasser A. M. Barakat or Hak Yong Kim.

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Ghouri, Z.K., Barakat, N.A.M., Saud, P.S. et al. Supercapacitors based on ternary nanocomposite of TiO2&Pt@graphenes. J Mater Sci: Mater Electron 27, 3894–3900 (2016). https://doi.org/10.1007/s10854-015-4239-x

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