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Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes

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Abstract

Microsphere polymer material finds a wide range of applications in fields such as adsorbent, drug carrier, catalyst and coating, and receives continuous attention. We here report a novel strategy of quick synthesis of polymethacrylate microsphere via photoinitiated polymerization of methacrylate monomer in a high internal phase emulsion (HIPE). A low cost and environmentally friendly natural product of β-cyclodextrin (β-CD) has been directly used as Pickering emulsifier to stabilize the methacrylate monomer in water to prepare the HIPE. The factors to control the particle size such as the dosage of β-CD, volume fraction of monomer internal phase and amount of inert diluting solvent, have been investigated in detail. Meanwhile, the approach has been validated by using various methacrylate monomers. Our results indicate that using a diluting solvent can not only change the surface morphology but also control the inner microstructure of the microsphere. By using a poor solvent of cyclohexane as diluting agent, porous microsphere other than solid microsphere has been prepared, and it could be directly applied as adsorbent to decolor oil. Moreover, the obtained poly(glycidyl methacrylate) microsphere was post-modified to exhibit satisfactory adsorption efficiencies towards organic dye contaminates in water. Those results indicate powerful platform of the obtained microsphere with reactive groups for further modification to prepare functional materials for desired purposes. Based on the fast synthesis, high yield, low energy cost as well as no harmful waste, the preparation strategy reported in this work could be scalable, and the obtained microsphere may find promising potential applications.

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Acknowledgements

The financial support from the Science and Technology Major Program of Fujian Province of China (No. 2022H6001) is acknowledged.

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  1. Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, China

    Yipeng Zhang, Ruohai Jiang, Yujie Zhang & Xiaopeng Xiong

  2. Technology Center of China Tobacco Fujian Industrial Co., Ltd., Xiamen, 361022, China

    Chaozhang Huang

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ZYP was involved in preliminary investigation, data analysis, visualization and writing-original draft. JRH and ZYJ was involved in data curation, formal analysis and writing-original draft. HCZ was involved in methodology, funding acquisition and review. XXP was involved in conceptualization, methodology, funding acquisition and writing-review and editing. All authors have read and agreed to the published version of the manuscript.

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Zhang, Y., Jiang, R., Zhang, Y. et al. Photoinitiated polymerization of beta-cyclodextrin-stabilized Pickering high internal phase emulsion for preparation of polymethacrylate microsphere and its adsorption towards dyes. J Mater Sci 58, 16002–16018 (2023). https://doi.org/10.1007/s10853-023-09041-x

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