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A review of lanthanide-based fluorescent nanofiber membranes by electrospinning and their applications

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Abstract

In recent years, rare earth complexes have become famous for their unique luminescence characteristics, such as clear emission bands, long lifetimes, and high luminous quantum efficiency. Since lanthanide ions have relatively small absorption areas in the ultraviolet region, they absorb light weakly. However, the excitation can be improved via coordination with organic ligands and subsequent energy transfer from the ligand triplet state to a coordinated metal ion. Electrospinning is a processing method that can readily combine rare earth complexes with matrix materials, to obtain fiber membranes with high fluorescence efficiency and stable mechanical properties. Here, we report the application of fluorescent nanofibers to color-tunable materials and oxygen sensing materials by discussing the electrospinning techniques used to produce electrospun nanofibers containing lanthanide complexes. We then focus on the mechanism of luminescence of fluorescent nanofibers, discussing polymer-based membranes and ceramic-based membranes based on the main constituent materials of the fiber membranes.

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Acknowledgements

This work was supported by the (1) Natural Scientific Foundation of China (Grant No. 51878361, 52070104); Natural Scientific Foundation of Shandong Province (Grant No. ZR2019MEM048); (2) State Key Project of International Cooperation Research (2016YFE0110800, 2017YFE0108300); the National Program for Introducing Talents of Discipline to Universities (“111” plan); 1st class discipline program of Materials Science of Shandong Province, The Double-Hundred Foreign Expert Program of Shandong Province(2019-2021).

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  1. Linjun Huang

    Present address: Institute of Hybrid Materials, National Center of International Research for Hybrid Materials Technology, National Base of International Science and Technology Cooperation, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, People’s Republic of China

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  1. Institute of Hybrid Materials, National Center of International Research for Hybrid Materials Technology, National Base of International Science and Technology Cooperation, College of Materials Science and Engineering, Qingdao University, Qingdao, 266071, People’s Republic of China

    Zhenzhen Huang, Yanxin Wang, Bingyang Li, Xianhang Yan, Yao Wang & Jianguo Tang

  2. Department of Chemical and Biological Engineering, Colorado State University, Fort Collins, CO, 80523, USA

    Matt J. Kipper

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Huang, Z., Wang, Y., Huang, L. et al. A review of lanthanide-based fluorescent nanofiber membranes by electrospinning and their applications. J Mater Sci 57, 3892–3922 (2022). https://doi.org/10.1007/s10853-021-06758-5

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