Abstract
Nickel and cobalt oxides, sulfides, selenides are widely studied as active materials in the application of energy storage and enhanced capacity are obtained as the atomic number of the non-metal element increase. In this study, Nickel and cobalt oxides (NiCoO2), sulfides and selenides are prepared via ion-exchange method and they are investigated as electrode materials for aqueous battery applications. From the perspective of electrochemistry, a detailed study of the fundamental relationships between composition, properties, and electrochemical performance are carried out. The results reveal that the enhanced charge capacity is associated with a more active property of nickel and cobalt as well as higher diffusivity of electrolyte after introducing different anions (S or Se). However, the reversible specific capacity decreases for sulfides and selenides and X-ray photoelectron spectroscopy results after long-term cycling tests indicate that the dissolution of S and Se may be responsible for the severe degrading in charge capacity.
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References
Li YG, Hasin P, Wu YY (2010) Ni x Co3−x O4 nanowires arrays for electrocatalytic oxygen evolution. Adv Mater 22:1926–1929
Gao MR, Xu YF, Jiang J, Yu SH (2013) Nanostructured metal chalcogenides: synthesis, modification, and applications in energy conversion and storage devices. Chem Soc Rev 42:2986–3017
Chhowalla M, Shin HS, Eda G, Li LJ, Loh KP, Zhang H (2013) The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets. Nat Chem 5:263–275
Lai C-H, Lu M-Y, Chen L-J (2012) Metal sulfide nanostructures: synthesis, properties and applications in energy conversion and storage. J Mater Chem 22:19–30
Shen LF, Che Q, Li HS, Zhang XG (2014) Mesoporous NiCo2O4 nanowires arrays grown on carbon textiles as binder-free flexible electrodes for energy storage. Adv Funct Mater 24:2630–2637
Wan L, Xiao JW, Xiao F, Wang S (2014) Nanostructured (Co, Ni)-based compounds coated on a highly conductive three dimensional hollow carbon nanorod array (HCNA) scaffold for high performance pseudocapacitors. ACS Appl Mater Interfaces 6:7735–7742
Yu L, Zhang L, Wu HB, Lou XW (2014) Formation of Ni x Co3−x S4 hollow nanoprisms with enhanced pseudocapacitive properties. Angew Chem Int Ed 126:3785–3788
Pu J, Cui FL, Chu SB, Wang TT, Sheng EH, Wang ZH (2014) Preparation and electrochemical characterization of hollow hexagonal NiCo2S4 nanoplates as pseudocapacitor materials. ACS Sustain Chem Eng 2:809–815
Chen HC, Jiang JJ, Zhang L, Wan HZ, Qi T, Xia DD (2013) Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors. Nanoscale 5:8879–8883
Chen HC, Jiang JJ, Zhang L, Xia DD, Zhao YD, Guo DQ, Qi T, Wan HZ (2014) In situ growth of NiCo2S4 nanotube arrays on Ni foam for supercapacitors: maximizing utilization efficiency at high mass loading to achieve ultrahigh areal pseudocapacitance. J Power Sources 254:249–257
Xia XH, Zhu CR, Luo JS, Zeng ZY, Guan C, Ng CF, Zhang H, Fan HJ (2014) Synthesis of free-standing metal sulfide nanoarrays via anion exchange reaction and their electrochemical energy storage application. Small 10:766–773
Gao MR, Jiang J, Yu SH (2012) Solution-based synthesis and design of late transition metal chalcogenide materials for oxygen reduction reaction (ORR). Small 8:13–27
Banerjee A, Bhatnagar S, Upadhyay KK, Yadav P, Ogale S (2014) Hollow Co0.85Se nanowires array on carbon fiber paper for high rate pseudocapacitor. ACS Appl Mater Interfaces 6:18844–18852
Wei WT, Mi LW, GaoY Zheng Z, Chen WH, Guan XX (2014) Partial ion-exchange of nickel-sulfide-derived electrodes for high performance supercapacitors. Chem Mater 26:3418–3426
Zhao WW, Zhang C, Geng FY, Zhuo SF, Zhang B (2014) Nanoporous hollow transition metal chalcogenide nanosheets synthesized via the anion-exchange reaction of metal hydroxides with chalcogenide ions. ACS Nano 8:10909–10919
Li YH, Cao LJ, Qiao L, Zhou M, Yang Y, Xiao P, Zhang YH (2014) Ni-Co sulfide nanowires on nickel foam with ultrahigh capacitance for asymmetric supercapacitors. J Mater Chem A 2:6540–6548
Mei L, Yang T, Xu C, Zhang M, Chen LB, Li QH, Wang TH (2014) Hierarchical mushroom-like CoNi2S4 arrays as a novel electrode material for supercapacitors. Nano Energy 3:36–45
Zhu T, Wu HB, Wang YB, Xu R, Lou XW (2012) Formation of 1D hierarchical structures composed of Ni3S2 nanosheets on CNTs backbone for supercapacitors and photocatalytic H2 production. Adv Energy Mater 2:1497–1502
Wang B, Park J, Su DW, Wang CY, Ahn H, Wang GX (2012) Solvothermal synthesis of CoS2-graphene nanocomposite material for high-performance supercapacitors. J Mater Chem 22:15750–15756
Zhao XY, Yang Y, Li YH, Cui X, Zhang YH, Xiao P (2015) NiCo-selenide as a novel catalyst for water oxidation. J Mater Sci. doi:10.1007/s10853-015-9690-9
Yang F, Yao JY, Liu FL, He HC, Zhou M, Xiao P, Zhang YH (2013) Ni-Co oxides nanowires arrays grown on ordered TiO2 nanotubes with high performance in supercapacitors. J Mater Chem A 1:594–601
Peng Z, Jia DS, Al-Enizi AM, Elzatahry AA, Zheng GF (2015) From water oxidation to reduction: homologous Ni-Co based nanowires as complementary water splitting electrocatalysts. Adv Energy Mater 5:1402031
Liu LF (2013) Porous Co16S16O96 nanosheets as a new electrode material for use in supercapacitors. J Power Sources 239:24–29
Tao F, ZhaoYQ Zhang GQ, Li HL (2007) Electrochemical characterization on cobalt sulfide for electrochemical supercapacitors. Electrochem Commun 9:1282–1287
Carim AI, Saadi FH, Soriaga MP, Lewis NS (2014) Electrocatalysis of the hydrogen-evolution reaction by electrodeposited amorphous cobalt selenide films. J Mater Chem A 2:13835–13839
Kong DS, Wang HT, Lu ZY, Cui Y (2014) CoSe2 nanoparticles grown on carbon fiber paper: an efficient and stable electrocatalyst for hydrogen evolution reaction. J Am Chem Soc 136:4897–4900
Zheng YR, Gao MR, Gao Q, Li HH, Xu J, Wu ZY, Yu SH (2014) An efficient CeO2/CoSe2 nanobelt composite for electrochemical water oxidation. Small 11:182–188
Zhao DJ, Zhang S, Yin GP, Du CY, Wang ZB, Wei J (2013) Tungsten doped Co-Se nanocomposites as an efficient non precious metal catalyst for oxygen reduction. Electrochim Acta 91:179–184
Lu XF, Wu DJ, Li RZ, Li Q, Ye SH, Tong YX, Li GR (2014) Hierarchical NiCo2O4 nanosheets@hollow microrod arrays for high-performance asymmetric supercapacitors. J Mater Chem A 2:4706–4713
Yin HH, Song CQ, Wang Y, Li SC, Zeng M, Zhang ZL, Zhu ZQ, Yu K (2013) Influence of morphologies and pseudocapacitive contributions for charge storage in V2O5 micro/nano-structures. Electrochim Acta 111:762–770
Li YH, Zhou M, Cui X, Yang Y, Xiao P, Cao LJ, Zhang YH (2015) Hierarchical structures of nickel, cobalt-based nanosheets and iron oxyhydroxide nanorods arrays for electrochemical capacitors. Electrochim Acta 161:137–143
Muller GQ, Cook JB, Kim HS, Tolbert SH, Dunn B (2015) High performance pseudocapacitor based on 2D layered metal chalcogenide nanocrystals. Nano Lett 15:1911–1917
Li YH, Li Q, Cao LJ, Cui X, Yang Y, Xiao P, Zhang YH (2015) The impact of morphologies and electrolyte solutions on the supercapacitive behavior for Fe2O3 and the charge storage mechanism. Electrochim Acta 178:171–178
Sathiya M, Prakash AS, Ramesha K, Tarascon JM, Shukla AK (2011) V2O5-anchored carbon nanotubes for enhanced electrochemical energy storage. J Am Chem Soc 133:16291–16299
Sankar KV, Selvan RK (2015) The ternary MnFe2O4/graphene/polyaniline hybrid composite as negative electrode for supercapacitors. J Power Sources 275:399–407
Vialat P, Mousty C, Taviot-Gueho C, Renaudin G, Martinez H, Dupin JC, Elkaim E, Leroux F (2014) High-performing monometallic cobalt layered double hydroxide supercapacitor with defined local structure. Adv Funct Mater 24:4831–4842
Zhu YG, Wang Y, Shi YM, Huang ZX, Fu L, Yang HY (2014) Phase transformation induced capacitance activation for 3D grapheme-CoO nanorod pseudocapacitor. Adv Energy Mater 4:1301788
Wang HY, Hsu YY, Chen R, Chan TS (2015) Chen HM and Liu B (2015) Ni3+-induced formation of active NiOOH on the spinel Ni-Co oxide surface for efficient oxygen evolution reaction. Adv Energy Mater 5:1500091
Acknowledgements
This work was supported by the fundamental research funds for the Central Universities (Project No. 106112015CDJZR305501) and the Defense Key Disciplines Lab of Novel Micro-nano Devices and System Technology Foundation.
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Li, Y., Peng, H., Yang, L. et al. Investigating the effect of sulfur and selenium on the electrochemical properties of nickel–cobalt oxides: enhanced charge capacity and composition–property relationships. J Mater Sci 51, 7108–7118 (2016). https://doi.org/10.1007/s10853-016-9968-6
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DOI: https://doi.org/10.1007/s10853-016-9968-6