Skip to main content
Log in

Reuse of waste welding powder in Fenton-like process for RO16 dye removal and Cr(VI) reduction

  • Published:
Environment, Development and Sustainability Aims and scope Submit manuscript

Abstract

Waste minimization is one of the important issued nowadays. In this study, the usability of waste welding powders (WWPs) was investigated in the Fenton-like process for Cr(VI) and reactive orange 16 (RO16) dye removal from aqueous solution. Solution pH, amount of catalyst, amount of H2O2, initial pollutants concentrations, reaction time and temperature parameters were optimized. 100% RO16 dye removal efficiency was obtained at pH: 2, dye concentration: 100 mg/L, catalyst amount: 1 g/L, and H2O2 amount: 2.5 µL/L. Besides, 99.7% Cr(VI) removal efficiency was obtained at pH: 2, Cr(VI) concentration: 10 mg/L, catalyst amount: 0.25 g/L, and H2O2 amount: 2.5 µL/L. In addition, the characterization of WWP was also carried out by SEM, EDX, XRD, XRF, and zeta potential analyses. WWP can be considered to be a viable catalyst for both dye and Cr(VI) removal from aqueous solution. WWP’s effectiveness was also tested in real wastewater. As a result of the experiments with real wastewater, 100% removal efficiency was obtained both textile wastewater for 60 min and Cr(VI) containing wastewater for 45 min. These results have revealed that WWP is a promising catalyst for the treatment of real wastewater.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Availability of data and materials

The datasets used and/or analyzed during the current study are available from the corresponding author on reasonable request.

References

  • Agarkoti, C., Thanekar, P. D., & Gogate, P. R. (2021). Cavitation based treatment of industrial wastewater: A critical review focusing on mechanisms, design aspects, operating conditions and application to real effluents. Journal of Environmental Management, 300, 113786.

    Article  CAS  Google Scholar 

  • Aghajani, K., & Tayebi, H. A. (2017). Adaptive neuro-fuzzy inference system analysis on adsorption studies of reactive red 198 from aqueous solution by SBA-15/CTAB composite. Spectrochimica Acta Part a: Molecular and Biomolecular Spectroscopy, 171, 439–448.

    Article  CAS  Google Scholar 

  • Çalık, Ç., & Çifçi, D. İ. (2022). Comparison of kinetics and costs of Fenton and photo-Fenton processes used for the treatment of a textile industry wastewater. Journal of Environmental Management, 304, 114234.

    Article  Google Scholar 

  • Chen, M., Wang, Y., Liang, T., Yang, J., & Yang, Z. (2017). Hydrogen production from steam reforming of ethylene glycol over iron loaded on MgO. In AIP conference proceedings (Vol. 1794, No. 1, p. 050002). AIP Publishing LLC.

  • Chen, H., Chen, W., Lin, Y., Xie, Y., Liu, S. H., & Yin, J. (2021). Visible and near-infrared light activated azo dyes. Chinese Chemical Letters, 32(8), 2359–2368.

    Article  CAS  Google Scholar 

  • De Luna, M. D. G., Retumban, J. D., Garcia-Segura, S., & Lu, M. C. (2017). Degradation of imidacloprid insecticide in a binary mixture with propylene glycol by conventional fenton process. Journal of Advanced Oxidation Technologies, 20(2), 20170012.

    Google Scholar 

  • Dhar, P. K., Saha, P., Hasan, M. K., Amin, M. K., & Haque, M. R. (2021). Green synthesis of magnetite nanoparticles using Lathyrus sativus peel extract and evaluation of their catalytic activity. Cleaner Engineering and Technology, 3, 100117.

    Article  Google Scholar 

  • Diao, Z. H., Qian, W., Zhang, Z. W., Jin, J. C., Chen, Z. L., Guo, P. R., Dong, F. X., Yan, L., Kong, L. J., & Chu, W. (2020). Removals of Cr (VI) and Cd (II) by a novel nanoscale zero valent iron/peroxydisulfate process and its Fenton-like oxidation of pesticide atrazine: Coexisting effect, products and mechanism. Chemical Engineering Journal, 397, 125382.

    Article  CAS  Google Scholar 

  • Ding, J., Jiang, M., Zhao, G., Wei, L., Wang, S., & Zhao, Q. (2021). Treatment of leachate concentrate by electrocoagulation coupled with electro-Fenton-like process: Efficacy and mechanism. Separation and Purification Technology, 255, 117668.

    Article  CAS  Google Scholar 

  • Elgarahy, A. M., Elwakeel, K. Z., Mohammad, S. H., & Elshoubaky, G. A. (2021). A critical review of biosorption of dyes, heavy metals and metalloids from wastewater as an efficient and green process. Cleaner Engineering and Technology, 4, 100209.

    Article  Google Scholar 

  • Eskikaya, O., Arslan, H., Özdemir, S., Gonca, S., & Dizge, N. (2022). Investigation of the effect of sintering of waste welding powder on antioxidant and antimicrobial activity. Water, Air, & Soil Pollution, 233(12), 1–12.

    Article  Google Scholar 

  • Falconi, I. B., Baltazar, M. D. P., Espinosa, D. C., & Tenório, J. A. S. (2020). Degradation of surfactant used in iron mining by oxidation technique: Fenton, photo-Fenton, and H2O2/UV—A comparative study. The Canadian Journal of Chemical Engineering, 98(5), 1069–1083.

    Article  CAS  Google Scholar 

  • Fan, X., Cao, Q., Meng, F., Song, B., Bai, Z., Zhao, Y., Chen, D., Zhou, Y., & Song, M. (2021). A Fenton-like system of biochar loading Fe–Al layered double hydroxides (FeAl-LDH@ BC)/H2O2 for phenol removal. Chemosphere, 266, 128992.

    Article  Google Scholar 

  • Gökcecik, G., & Dulkadiroğlu, H. (2021). Elektrik ark ocağı ile üretim yapan bir demir-çelik tesisinin mevcut en iyi teknikler kapsamında değerlendirilmesi. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 10(2), 465–471.

    Google Scholar 

  • Haber, F., & Weiss, J. (1934). The catalytic decomposition of hydrogen peroxide by ironsalts. Proceedings of the Royal Society of London Series A, 147, 332–351.

    CAS  Google Scholar 

  • Heidmann, I., & Calmano, W. (2008). Removal of Cr(VI) from model wastewaters by electrocoagulation with Fe electrodes. Separation and Purification Technology, 61, 15–21.

    Article  CAS  Google Scholar 

  • Hoang, A. T., Nižetić, S., Cheng, C. K., Luque, R., Thomas, S., Banh, T. L., & Nguyen, X. P. (2022). Heavy metal removal by biomass-derived carbon nanotubes as a greener environmental remediation: A comprehensive review. Chemosphere, 287, 131959.

    Article  CAS  Google Scholar 

  • Hu, X., Li, R., & Xing, Y. (2022). Photo-assisted degradation of Rhodamine B by a heterogeneous Fenton–like process: Performance and Kinetics. Environmental Technology, (just-accepted), 1–34.

  • Hu, C. Y., Hou, Y. Z., Lin, Y. L., Deng, Y. G., Hua, S. J., Du, Y. F., Chen, C. W., & Wu, C. H. (2020). Investigation of iohexol degradation kinetics by using heat-activated persulfate. Chemical Engineering Journal, 379, 122403.

    Article  CAS  Google Scholar 

  • Hussain, S., Aneggi, E., & Goi, D. (2021a). Catalytic activity of metals in heterogeneous Fenton-like oxidation of wastewater contaminants: A review. Environmental Chemistry Letters, 19(3), 2405–2424.

    Article  CAS  Google Scholar 

  • Hussain, S., Aneggi, E., Maschio, S., Contin, M., & Goi, D. (2021b). Steel scale waste as a heterogeneous fenton-like catalyst for the treatment of landfill leachate. Industrial & Engineering Chemistry Research, 60(31), 11715–11724.

    Article  CAS  Google Scholar 

  • Isik, Z., Bouchareb, R., Saleh, M., & Dizge, N. (2022). Iron oxide particles loaded activated carbon cloth and comparison of adsorption and fenton reaction for efficient cationic and anionic dyes removal. Water, Air, & Soil Pollution, 233(5), 1–11.

    Article  Google Scholar 

  • Jafarinejad, S. (2019). Cost-effective catalytic materials for AOP treatment units. Applications of Advanced Oxidation Processes (AOPs) in Drinking Water Treatment (pp. 309–343).

  • Li, W., Sun, T., & Li, F. (2014). Highly Efficient Iron Nanocatalyst Stabilized by Double-Walled Carbon Nanotubes and Mixed Metal Oxides for Degradation of Cationic and Anionic Dyes by a Fenton-like Process. Industrial & Engineering Chemistry Research, 53(47), 18095–18103. https://doi.org/10.1021/ie503300r

  • Li, D., Yang, T., Li, Y., Liu, Z., & Jiao, W. (2020). Facile and green synthesis of highly dispersed tar-based heterogeneous Fenton catalytic nanoparticles for the degradation of methylene blue. Journal of Cleaner Production, 246, 119033.

    Article  CAS  Google Scholar 

  • Liu, B., Pan, S., Liu, Z., Li, X., Zhang, X., Xu, Y., Sun, Y., Yu, Y., & Zheng, H. (2020). Efficient removal of Cu (II) organic complexes by polymer-supported, nanosized, and hydrated Fe (III) oxides through a Fenton-like process. Journal of Hazardous Materials, 386, 121969.

    Article  CAS  Google Scholar 

  • Liu, Y., & Wang, J. (2019). Reduction of nitrate by zero valent iron (ZVI)-based materials: A review. Science of the Total Environment, 671, 388–403.

    Article  CAS  Google Scholar 

  • Lu, K., Gao, M., Sun, B., Wang, M., Wang, S., & Wang, X. (2022). Simultaneous removal of Cr and organic matters via coupling Cr-Fenton-like reaction with Cr flocculation: The key role of Cr flocs on coupling effect. Chemosphere, 287, 131991.

    Article  CAS  Google Scholar 

  • Luong, T. H., Nguyen, T. H., Nguyen, B. V., Nguyen, N. K., Nguyen, T. Q., & Dang, G. H. (2022). Efficient degradation of methyl orange and methylene blue in aqueous solution using a novel Fenton-like catalyst of CuCo-ZIFs. Green Processing and Synthesis, 11(1), 71–83.

    Article  CAS  Google Scholar 

  • Ma, B., Yao, J., Knudsen, T. Š, Chen, Z., Liu, B., Zhao, C., & Zhu, X. (2022). Simultaneous removal of typical flotation reagent 8-hydroxyquinoline and Cr (VI) through heterogeneous Fenton-like processes mediated by polydopamine functionalized ATP supported nZVI. Journal of Hazardous Materials, 424, 126698.

    Article  CAS  Google Scholar 

  • Mao, G., Han, Y., Liu, X., Crittenden, J., Huang, N., & Ahmad, U. M. (2022). Technology status and trends of industrial wastewater treatment: A patent analysis. Chemosphere, 288, 132483.

    Article  CAS  Google Scholar 

  • Mashayekh-Salehi, A., Akbarmojeni, K., Roudbari, A., van der Hoek, J. P., Nabizadeh, R., Dehghani, M. H., & Yaghmaeian, K. (2021). Use of mine waste for H2O2-assisted heterogeneous Fenton-like degradation of tetracycline by natural pyrite nanoparticles: Catalyst characterization, degradation mechanism, operational parameters and cytotoxicity assessment. Journal of Cleaner Production, 291, 125235.

    Article  CAS  Google Scholar 

  • Mia, M. S., Yao, P., Zhu, X., Lei, X., Xing, T., & Chen, G. (2021). Degradation of textile dyes from aqueous solution using tea-polyphenol/Fe loaded waste silk fabrics as Fenton-like catalysts. RSC Advances, 11(14), 8290–8305.

    Article  CAS  Google Scholar 

  • Milenković, D. A., Dimić, D. S., Avdović, E. H., Amić, A. D., Marković, J. M. D., & Marković, Z. S. (2020). Advanced oxidation process of coumarins by hydroxyl radical: Towards the new mechanism leading to less toxic products. Chemical Engineering Journal, 395, 124971.

    Article  Google Scholar 

  • Natsir, M., Putri, Y. I., Wibowo, D., Maulidiyah, M., Salim, L. O. A., Azis, T., Bijang, C. M., Mustapa, F., Irwan, I., Arham, Z., & Nurdin, M. (2021). Effects of Ni–TiO2 pillared clay-montmorillonite composites for photocatalytic enhancement against reactive orange under visible light. Journal of Inorganic and Organometallic Polymers and Materials, 31, 3378–3388.

    Article  CAS  Google Scholar 

  • Olayiwola, S. O., & Dejam, M. (2019). A comprehensive review on interaction of nanoparticles with low salinity water and surfactant for enhanced oil recovery in sandstone and carbonate reservoirs. Fuel, 241, 1045–1057.

    Article  CAS  Google Scholar 

  • Ozkan, Z. Y., Cakirgoz, M., Kaymak, E. S., & Erdim, E. S. R. A. (2018). Rapid decolorization of textile wastewater by green synthesized iron nanoparticles. Water Science and Technology, 77(2), 511–517.

    Article  CAS  Google Scholar 

  • Saleh, M., Yalvac, M., Arslan, H., & Dizge, N. (2022). Investigation of basalt properties as heterogeneous catalyst for Fenton oxidation of textile wastewater. Clean-Soil, Air, Water, 50(1), 2000432.

    Article  CAS  Google Scholar 

  • Sharafinia, S., Farrokhnia, A., & Lemraski, E. G. (2022). The adsorption of cationic dye onto ACPMG@ ZIF-8 core-shell, optimization using central composite response surface methodology (CCRSM). Colloids and Surfaces a: Physicochemical and Engineering Aspects, 634, 128039.

    Article  CAS  Google Scholar 

  • Sista, K. S., & Dwarapudi, S. (2018). Iron powders from steel industry by-products. ISIJ International, 58(6), 999–1006.

    Article  CAS  Google Scholar 

  • Subhiksha, V., Kokilavani, S., & Khan, S. S. (2022). Recent advances in degradation of organic pollutant in aqueous solutions using bismuth based photocatalysts: A review. Chemosphere, 290, 133228.

    Article  CAS  Google Scholar 

  • Sun, D., Yang, J., Chen, F., Chen, Z., & Lv, K. (2022). Hollow nanospheres organized by ultra-small CuFe2O4/C subunits with efficient photo-fenton-like performance for antibiotic degradation and Cr (VI) reduction. Catalysts, 12(7), 687.

    Article  CAS  Google Scholar 

  • Sun, Y., Ni, L., Papadaki, M., Jiao, Z., Zhu, W., Jiang, J., Mashuga, C., Mannan, M. S., & Wilhite, B. (2020). Reaction hazard and mechanism study of H2O2 oxidation of 2-butanol to methyl ethyl ketone using DSC, Phi-TEC II and GC-MS. Journal of Loss Prevention in the Process Industries, 66, 104177.

    Article  CAS  Google Scholar 

  • Takai, Z. I., Mustafa, M. K., Asman, S., & Sekak, K. A. (2019). Preparation and characterization of magnetite (Fe3O4) nanoparticles by sol-gel method. International Journal of Nanoelectronics and Materials, 12, 37–46.

    Google Scholar 

  • Teixeira, P., Bacariza, C., Mohamed, I., & Pinheiro, C. I. (2022). Improved performance of modified CaO-Al2O3 based pellets for CO2 capture under realistic Ca-looping conditions. Journal of CO2 Utilization, 61, 102007.

    Article  CAS  Google Scholar 

  • Trendafilova, I., Šuligoj, A., Ristić, A., Van de Velde, N., Dražić, G., Opresnik, M., Zabukovec Logar, N., Pintar, A., & Novak Tušar, N. (2020). Evolution of surface catalytic sites on bimetal silica-based fenton-like catalysts for degradation of dyes with different molecular charges. Nanomaterials, 10(12), 2419.

    Article  CAS  Google Scholar 

  • Vu, A. T., Xuan, T. N., & Lee, C. H. (2019). Preparation of mesoporous Fe2O3· SiO2 composite from rice husk as an efficient heterogeneous Fenton-like catalyst for degradation of organic dyes. Journal of Water Process Engineering, 28, 169–180.

    Article  Google Scholar 

  • Wang, C., Sun, R., & Huang, R. (2021). Highly dispersed iron-doped biochar derived from sawdust for Fenton-like degradation of toxic dyes. Journal of Cleaner Production, 297, 126681.

    Article  CAS  Google Scholar 

  • Wang, J., Wang, S., He, X., Zhou, Y., An, C., Zhang, M., Zhou, Y., Han, Y., Chen, X., Zhou, J., & Yang, Z. (2022). Pressure engineering of colossal magnetoresistance in the ferrimagnetic nodal-line semiconductor Mn3Si2Te6. Physical Review B, 106(4), 045106.

    Article  CAS  Google Scholar 

  • Wang, N., Zheng, T., Zhang, G., & Wang, P. (2016). A review on Fenton-like processes for organic wastewater treatment. Journal of Environmental Chemical Engineering, 4(1), 762–787.

    Article  CAS  Google Scholar 

  • Wu, D., Tian, N., Sun, X., Wang, M., Huang, J., Deng, H., Yu, D., Wu, M., Ni, H., Pei, K., Jia, Y., & Ye, P. (2021). Enhanced fenton-like catalysis by facilely prepared nano-scale NCFOH/HKUST composites with synergistic effect for dye degradation. Materials Chemistry and Physics, 258, 123980.

    Article  CAS  Google Scholar 

  • Wu, X., Xia, F., & Nan, Z. (2020). Facile synthesis of double-mesoporous-shelled hollow spheres of Cu–CuFe2O4/SiO2 composite as excellent Fenton catalyst. Materials Chemistry and Physics, 242, 122490.

    Article  CAS  Google Scholar 

  • Xiao, M., Qi, Y., Feng, Q., Li, K., Fan, K., Huang, T., Qu, P., Gai, H., & Song, H. (2021). P-cresol degradation through Fe (III)-EDDS/H2O2 Fenton-like reaction enhanced by manganese ion: Effect of pH and reaction mechanism. Chemosphere, 269, 129436.

    Article  CAS  Google Scholar 

  • Xie, Z. H., He, C. S., Zhou, H. Y., Li, L. L., Liu, Y., Du, Y., Liu, W., Mu, Y., & Lai, B. (2022). Effects of molecular structure on organic contaminants’ degradation efficiency and dominant ROS in the advanced oxidation process with multiple ROS. Environmental Science & Technology, 56(12), 8784–8795.

    Article  CAS  Google Scholar 

  • Yan, M., Ma, J., & Ji, G. (2016). Examination of effects of Cu (II) and Cr (III) on Al (III) binding by dissolved organic matter using absorbance spectroscopy. Water Research, 93, 84–90.

    Article  CAS  Google Scholar 

  • Yang, Y., Zhang, P., Hu, K., Zhou, P., Wang, Y., Asif, A. H., Duan, X., Sun, H., & Wang, S. (2022). Crystallinity and valence states of manganese oxides in Fenton-like polymerization of phenolic pollutants for carbon recycling against degradation. Applied Catalysis b: Environmental, 315, 121593.

    Article  CAS  Google Scholar 

  • Zhang, N., Tsang, E. P., Chen, J., Fang, Z., & Zhao, D. (2020). Critical role of oxygen vacancies in heterogeneous Fenton oxidation over ceria-based catalysts. Journal of Colloid and Interface Science, 558, 163–172.

    Article  Google Scholar 

  • Zhao, L., Lin, Z. R., Ma, X. H., & Dong, Y. H. (2018). Catalytic activity of different iron oxides: Insight from pollutant degradation and hydroxyl radical formation in heterogeneous Fenton-like systems. Chemical Engineering Journal, 352, 343–351.

    Article  CAS  Google Scholar 

  • Zhao, W., & Zhou, B. (2021). Assessing the role of CNTs in H2O2/Fe (III) Fenton-like process: Mechanism, DFT calculations and ecotoxicity evaluation. Separation and Purification Technology, 259, 118218.

    Article  CAS  Google Scholar 

  • Zheng, R., Li, J., Zhu, R., Wang, R., Feng, X., Chen, Z., Wei, W., Yang, D., & Chen, H. (2022). Enhanced Cr (VI) reduction on natural chalcopyrite mineral modulated by degradation intermediates of RhB. Journal of Hazardous Materials, 423, 127206.

    Article  CAS  Google Scholar 

  • Ziembowicz, S., & Kida, M. (2022). Limitations and future directions of application of the Fenton-like process in micropollutants degradation in water and wastewater treatment: A critical review. Chemosphere, 296, 134041.

    Article  CAS  Google Scholar 

  • Zwolak, A., Sarzyńska, M., Szpyrka, E., & Stawarczyk, K. (2019). Sources of soil pollution by heavy metals and their accumulation in vegetables: A review. Water, Air, & Soil Pollution, 230(7), 1–9.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This project was supported by Mersin University (Project No: 2022-2-TP2-4758).

Funding

This project was supported by Mersin University (BAP) Scientific Research Projects Unit with Project Number 2022-2-TP2-4758.

Author information

Authors and Affiliations

Authors

Contributions

HB, OE, PB, and ZI performed methodology and data curation. HA and ND performed investigation and writing- original draft. HA and ND performed conceptualization, writing—original draft, formal analysis, and review and editing. All authors read and approved the final manuscript.

Corresponding author

Correspondence to Nadir Dizge.

Ethics declarations

Ethics approval and consent to participate

Not applicable.

Consent for publication

Not applicable.

Competing interests

The authors declare that they have no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bulut, H., Eskikaya, O., Belibagli, P. et al. Reuse of waste welding powder in Fenton-like process for RO16 dye removal and Cr(VI) reduction. Environ Dev Sustain (2023). https://doi.org/10.1007/s10668-023-03834-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10668-023-03834-5

Keywords

Navigation