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Research progress of hydroxyethyl cellulose materials in oil and gas drilling and production

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Abstract

As a non-ionic surfactant, hydroxyethyl cellulose (HEC) is widely utilized in the oil and gas industry owing to its numerous advantages, which include excellent suspensibility, robust viscosifying properties, and distinguished plugging effect. However, the direct application of HEC faces certain challenges such as high dosage, suboptimal temperature resistance, and slow degradation. Various solutions have been proposed to tackle these issues, including the blending of HEC with other materials to enhance its performance. The viscosifying ability of the material is significantly improved, and the oil displacement effect is remarkable after the modification of hydroxyethyl cellulose (HEC).Thus, materials based on HEC, such as the HEC compounding system and HEC-modified materials, have considerable research value. This review aims to discuss the current research status of HEC-based materials, focusing on viscosity stabilization, anti-tampering and plugging, oil drive, and production increase. The synthesis method and properties of the material are analyzed, highlighting the weak temperature resistance, insufficient salt resistance, and limited self-adaptability of HEC. Hence, it is suggested that future development should concentrate on hydrophobic modification of HEC long carbon chains and compounding with polymers to produce HEC-based composites that are suitable for wider application.

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References

  • Akinade AE, Wilfred OC, Akin-Taylor AM (2018) Improving the rheological properties of drilling mud using local based materials. Am J Eng Res 7:58–63

    Google Scholar 

  • Bai Y et al (2018) Experimental study on hydrophobically associating hydroxyethyl cellulose flooding system for enhanced oil recovery. Energy Fuels 32:6713–6725. https://doi.org/10.1021/acs.energyfuels.8b01138

    Article  CAS  Google Scholar 

  • Beheshti N et al (2006) Characterization of interactions in aqueous solutions of hydroxyethylcellulose and its hydrophobically modified analogue in the presence of a cyclodextrin derivative. Phys Chem B 110:6601–6608. https://doi.org/10.1021/jp056828v

    Article  CAS  Google Scholar 

  • Benyounes K, Remlis S, Benmounah A (2018) Rheological behavior of hydroxyethylcellulose (HEC) solutions. IOP Conf Ser 1045(1):012008

    Article  Google Scholar 

  • Bray WS, et al. Application of methylhydroxyethyl cellulose as cement additive [P]. CN103476729A, 2013–12–25

  • Bülichen D, Plank J (2011) Mechanistic study on carboxymethyl hydroxyethyl cellulose as fluid loss control additive in oil well cement. Appl Polym Sci 124(3):2340–2347. https://doi.org/10.1002/app.35278

    Article  CAS  Google Scholar 

  • Bülichen D, Plank J (2012) Role of colloidal polymer associates for the effectiveness of hydroxyethyl cellulose as a fluid loss control additive in oil well cement. Appl Polym Sci 126:E25–E34. https://doi.org/10.1002/app.36529

    Article  CAS  Google Scholar 

  • Cai JH (2003) Testing research on temporarily blocked drilling fluid. China University of Geosciences, China

    Google Scholar 

  • Chen XY (2016) Preparation and characterization of water-soluble hydroxyethyl cellulose hydrophobic modified with succinic anhydride. Shandong Agricultural University, China

    Google Scholar 

  • Chen Z, DuanMiska MSZ et al (2007) Hydraulic predictions for polymer-thickened foam flow in horizontal and directional wells. Spe Drill Complet 24(1):40–49

    Article  Google Scholar 

  • Dai S et al (2006) A study on the solution behavior of IPBC-hydrophobically-modified hydroxyethyl cellulose. Appl Polym Sci 100:2824–2831. https://doi.org/10.1002/app.23743

    Article  CAS  Google Scholar 

  • El-hoshoudy AN, Zaki EG, Elsaeed SM (2019) Biopolymers composites as oil improving candidates-article review. Pet Coal 61:1365–1377

    CAS  Google Scholar 

  • Fan Y, Jin H, Fang B et al (2019) Rheological properties and crosslinking properties of cellulose solution modified by amylpropyl dimethylamine erucic acid. Oilfield Chem 36(02):209–214

    CAS  Google Scholar 

  • Francesco DG, Manlio T, Claude O, Shen AQ (2017) When microrheology, bulk rheology, and microfluidics meet: broadband rheology of hydroxyethyl cellulose water solutions. Macromolecules 50(7):2951–2963

    Article  Google Scholar 

  • French AD (2017) Glucose, not cellobiose, is the repeating unit of cellulose and why that is important. Cellulose 24(11):4605–4609. https://doi.org/10.1007/s10570-017-1450-3

    Article  CAS  Google Scholar 

  • Gao MJ (2018) Synthesis and evaluation of polyvinyl alcohol oil well cement water loss reducer. China University of Petroleum, Beijing

    Google Scholar 

  • Hao SQ (2011) A study to optimize drilling fluids to improve borehole stability in natural gas hydrate frozen ground. Pet Sci Eng 76(3):109–115. https://doi.org/10.1016/j.petrol.2011.01.014

    Article  CAS  Google Scholar 

  • Hu CL et al (2007) Oil-soluble cationic broad-spectrum temporary plugging agent for drilling fluid [P]. CN101092556, 2007–12–26

  • Kang JS (2020) Lost loss prevention and plugging technology in drilling engineering. Chem Eng Des Commun 46:194–195

    Google Scholar 

  • Kang K et al (2020) The successful application of anti-gas channeling cementing technology in Jinzhuang oilfield of Ordos basin. China Pet Chem Stand Qual 40:231–232

    Google Scholar 

  • Kim U-J, Kimura S, Wada M (2019) Highly enhanced adsorption of congo red onto dialdehyde cellulose-crosslinked cellulose-chitosan foam. Carbohyd Polym 214:294–302. https://doi.org/10.1016/j.carbpol.2019.03.058

    Article  CAS  Google Scholar 

  • Kjøniksen AL et al (2008) Modified polysaccharides for use in enhanced oil recovery applications. Eur Polym J 44:959–967

    Article  Google Scholar 

  • Kong HQ, Chen XY, Lu QY et al (2015) Viscosity stability and enzymatic hydrolysis property of hydroxyethyl cellulose solution. Paint Coat Ind 45:63–67+70

    CAS  Google Scholar 

  • Li Q, Cai Y, Ye L, Huang RH, Dai H (2004) Synthesis of hydrophobic association hydroxyethyl cellulose. Polym Mater Sci Eng 02:93–96

    Google Scholar 

  • Li CZ et al (2011) A kind of temporary plugging agent and its preparation method and application in low permeability oil field [P]. CN102020984A, 2011–04–20

  • Li ZB, Fan ZL, Li Q et al (2019) Research status of hydroxyethyl cellulose modified materials. Mod Chem Ind 39:70–74

    Google Scholar 

  • Lin JD (2006) Preparation of siloxane modified acrylate polymer latex powder and mechanism of dispersion film formation. South China University of Technology, China

    Google Scholar 

  • Liu ZH (2014) Multi-effect latex anti-gas channeling agent for deep well cementing and its preparation method [P]. CN103834374A, 2014–06–04

  • Liu H et al (2010) An acid-resistant and oil-resistant foam backing agent [P]. CN101619208, 2010–01–06

  • Liu YL, Zhang GC, Zhang L, Wang H, Li GH, Chen WZ (2013) Rheological properties of hydrophobic modified hydroxyethyl cellulose based fluid with thickener of fracturing fluid. 2013 International Symposium Advances Oilfield Chemistry (ISOC2013).China University of Petroleum, East China

  • Liu P et al (2017) Experimental study of rheological properties and oil displacement efficiency in oilfields for a synthetic hydrophobically modified polymer. Sci Rep 7:1–11. https://doi.org/10.1038/s41598-017-09057-9

    Article  CAS  Google Scholar 

  • Ma H et al (2020) Research on drilling fluid leakage prevention and plugging technology. Petrochem Ind Technol 27:36+42

    Google Scholar 

  • Miao X, Liu RG, Wang XJ et al (2018) A hydrophobic modified hydroxy ethyl cellulose water loss reducer, preparation method and characterization method [P]. CN107814847A, 2018–03–20

  • Miao X, Wang XJ, Du XY et al (2019) Modified hydroxyethyl cellulose thickener for pesticide. J Rural Pract Technol 07:50

    Google Scholar 

  • Moumin M, Plank J (2017) Effectiveness of polycarboxylate dispersants in enhancing the fluid Loss performance of cellulose ethers. SPE Int Conf Oilf Chem. https://doi.org/10.2118/184542-MS

    Article  Google Scholar 

  • Ning F (2020) Preparation and characterization of cellulose-based superabsorbent resin. Nanchang University, China

    Google Scholar 

  • Ouaer H, Gareche M (2018) The rheological behaviour of a water-soluble polymer (HEC) used in drilling fluids. J Braz Soc Mech Sci 40:380. https://doi.org/10.1007/s40430-018-1301-7

    Article  CAS  Google Scholar 

  • Peng SL, Feng XG, Tian J et al (2012) Progress in study and application of drilling fluid viscosifier at home. Guangzhou Chem Ind 40(12):10–11+16

    CAS  Google Scholar 

  • Qiu DX (2011) Study on synthesis and properties of hydrophobic association hydroxyethyl cellulose. China University of Petroleum, East China

    Google Scholar 

  • Qiu DX (2014) Research progress of hydrophobically associating hydroxyethyl cellulose. Nei Jiang Sci Technol 35:90+125

    Google Scholar 

  • Qiu DX et al (2014) Study on the resistance coefficient and residual resistance coefficient of hydrophobically associating hydroxyethyl cellulose. Spec Petrochem 31:5–9

    CAS  Google Scholar 

  • Reddy BR et al (2012) Chemical modification of biopolymers to design cement slurries with temperature-activated viscosification—a laboratory study. SPE Drill Compl 27:94–102. https://doi.org/10.2118/141005-PA

    Article  CAS  Google Scholar 

  • Rellegadla S et al (2018) An effective approach for enhanced oil recovery using nickel nanoparticles assisted polymer flooding. Energy Fuels 32:11212–11221. https://doi.org/10.1021/acs.energyfuels.8b02356

    Article  CAS  Google Scholar 

  • Su XM, Lian ZH, Yuan Y (2019) Study on the effect of the oil-water ratio on the rheological properties of hydroxyethyl cellulose (HEC). Geofluids 2019:12. https://doi.org/10.1155/2019/7405702

    Article  CAS  Google Scholar 

  • Sui YH et al (2020a) A kind of coagulant plugging slurry [P]. CN110951471A, 2020–04–03

  • Sui YH et al (2020b) A kind of anti-leakage plugging and lifting adhesive [P]. CN110734746A, 2020–01–31

  • Sun JS et al (2020) Research progress and application prospects of smart materials in lost circulation control of drilling fluids. J. China Univ. Pet Ed Nat Sci 44:100–110. https://doi.org/10.3969/j.issn.1673-5005.2020.04.012

    Article  Google Scholar 

  • Wang YL et al (2011) The effects of alcohol on the viscosity and surface tension of hydrophobically modified hydroxyethyl cellulose. Petrochem Technol 40:527–531

    CAS  Google Scholar 

  • Wang LW, Lu YJ, Liu YT et al (2015) Crosslinking mechanism of hydroxyethyl carboxymethyl cellulose and metal lons. Sci Technol Eng 15:166–169

    Google Scholar 

  • Wang C et al (2018) Experimental study of key effect factors and simulation on oil displacement efficiency for a novel modified polymer BD-HMHEC. Sci Rep 8:1–9. https://doi.org/10.1038/s41598-018-22259-z

    Article  CAS  Google Scholar 

  • Wang G et al (2020) Research and application of micro expansion anti channeling cement slurry system in Agadem oilfield. China Pet Mach 48:15–22

    CAS  Google Scholar 

  • Xie DB (2018) Research on synthesis and performance of anti-high temperature oil well cement water loss reducer. Southwest Petroleum University, China

    Google Scholar 

  • Xu Q (2009) The rheology of water-soluble polymers, surfactants and salt solution. Jiangnan University, China

    Google Scholar 

  • Yan J et al (2018) Synthesis and evaluation of a nanophase wax emulsion plugging materia. Drill Fluid Complet Fluid 35:73–77

    CAS  Google Scholar 

  • Yuan BX (2018) Methods of enhancing oil recovery. China Pet Chem Stand Qual 38:34–35

    Google Scholar 

  • Zhang FY, et al (2010) Development of new oil-soluble temporary plugging solid-free workover fluid. Nat Gas Ind (Chengdu, China). 30: 77-79+134-135

  • Zhao M, Shao ZQ, Ao LL (2013) Properties, applications and market status of hydroxyethyl cellulose. Cellul Sci Technol 21:70–78

    CAS  Google Scholar 

  • Zhu YM (2016) Study on rheological properties of modified cellulose solution and rheological dynamics of crosslinking gel process. East China University of Science and Technology, China

    Google Scholar 

  • Zhu YM, Fang B, Lu YJ et al (2016) Rheology and drag reduction properties of epichlorohydrin modified cellulose solution. Drill Fluid Completion Fluid 33(06):95–100

    CAS  Google Scholar 

  • Zia F, Zia KM, Z-i-H N, Tabasum S, Zuber M (2020) Preparation of hydroxyethyl cellulose/halloysite nanotubes graft polylactic acid-based polyurethane bionanocomposites. Int J Biol Macromol 153:591–599. https://doi.org/10.1016/j.ijbiomac.2020.03.038

    Article  CAS  PubMed  Google Scholar 

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Acknowledgments

We thank the Education Department of Liaoning Province for its financial support. The author thanks Dr. Pan's lab for the data support.

Funding

This study was funded by the Educational Department of Liaoning Province (L2020026, LJKZ0417).

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Authors and Affiliations

  1. College of Petroleum and Natural Gas Engineering, Liaoning Petrochemical University, Fushun, 113001, Liaoning, China

    Yi Pan, Jie Wang & Shuangchun Yang

  2. College of Geophysics, China University of Petroleum, Beijing, 102249, China

    Jianwei Fu

  3. College of International Education, Liaoning Petrochemical University, Fushun, 113001, Liaoning, China

    Yvan Lebongo Eteme

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  1. Yi Pan
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Contributions

Conceptualization, YP and SY; validation, JF; investigation, JW and YLE; resources, JW; writing—original draft preparation, JW; writing—review and editing, YP and SY; supervision, JF; project administration, YP; funding acquisition, YP and SY. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Shuangchun Yang.

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Pan, Y., Wang, J., Yang, S. et al. Research progress of hydroxyethyl cellulose materials in oil and gas drilling and production. Cellulose 30, 10681–10700 (2023). https://doi.org/10.1007/s10570-023-05564-3

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