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Influence of Surface Polarity on Catalytic Properties of Aminopyridine Functionalized Polyacrylonitrile Fiber Catalyst

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Abstract

This work has been developed to study the effect of fiber catalyst surface polarity on catalyst performance. Taking 4-dimethyl amine pyridine (DMAP) derivative functionalized polyacrylonitrile fiber catalyst (PANDMAPF) as the template catalyst, its surface property was adjusted through the introduction of phenyl and hydroxyl groups on PANDMAPF. Elemental analysis (EA), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and mechanical strength test are used to characterize and demonstrate the successful synthesis of different fiber catalysts. The catalytic performance of different fiber catalysts was tested by the reaction of one-pot three-component synthesis 2-amino-2-chromenes. The results showed that reducing the surface polarity of the catalyst could not only improve the activity of the catalyst, but also make the three-component reaction which could only be carried out in high polar solvents (water and methanol), but also proceed effectively in lower polar solvents (such as ethanol and n-butanol). Therefore, the activity and selectivity of the catalyst can be effectively regulated by introducing different polar auxiliary functional groups on the surface of the fiber catalyst, which provides a theoretical basis for the design and synthesis of high activity and selectivity fiber catalyst.

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Acknowledgements

We gratefully acknowledge the support from the National Natural Science Foundation of China (Nos. 21671205, 21771164, U1407103 and 21802034). Natural Science Foundation of Henan Province (182300410143). Collaborative Innovation Centre of Henan Textile and Clothing Industry, Innovation Scientists and Technicians Troop Construction Projects of Henan Province (Grant Nos. 164100510007 and CXTD2015018), and Zhengzhou University (Grant Nos. 1421316035 and 2016xjxm258), Program for interdisciplinary Direction Team in Zhongyuan University of Technology, China.

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Authors and Affiliations

  1. School of Material and Chemical Engineering, Centre for Advanced Materials Research, Zhongyuan University of Technology, Zhengzhou, 450007, People’s Republic of China

    Pengyu Li, Yu Yang & Liwei Mi

  2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin, 300072, People’s Republic of China

    Ke Gao & Minli Tao

  3. School of Chemistry, Zhengzhou University, Zhengzhou, 450001, People’s Republic of China

    Weihua Chen

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  1. Pengyu Li
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  2. Yu Yang
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  3. Liwei Mi
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  4. Ke Gao
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  5. Minli Tao
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Correspondence to Pengyu Li or Yu Yang.

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Li, P., Yang, Y., Mi, L. et al. Influence of Surface Polarity on Catalytic Properties of Aminopyridine Functionalized Polyacrylonitrile Fiber Catalyst. Catal Lett 151, 2056–2064 (2021). https://doi.org/10.1007/s10562-020-03443-1

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  • DOI: https://doi.org/10.1007/s10562-020-03443-1

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