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Molybdenum Carbonyl Grafted on Amine-Functionalized MCM-22 as Potential Catalyst for Iso-Eugenol Oxidation

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Abstract

Different concentrations of molybdenum carbonyl were incorporated on the surface of amine-functionalized MCM-22. The obtained samples were thoroughly characterized by Fourier-transform infrared spectroscopy (FTIR), powder X-Ray diffraction (XRD), high-resolution transition electron microscopy (HRTEM), N2-sorption and thermo-gravimetric analysis (TGA) methods. HRTEM images confirmed the uniform distribution of active molybdenum species on the functionalized MCM-22. The resultant materials were explored for liquid-phase oxidation of iso-eugenol at ambient reaction conditions. The catalyst with 6 wt% Mo(CO)6 loaded materials showed comparable conversion (87%) with vanillin as the major product (selectivity of 61%) for the chosen reaction. The better catalytic activity of MCM-22-DA-Mo catalyst having 6 wt% loading of Mo carbonyl could be due to the uniform distribution of molybdenum species on MCM-22-DA surface. Importantly, the catalyst retained its activity even after several runs.

Graphic Abstract

Molybdenum carbonyl were incorporated on the surface of amine-functionalized MCM-22 by the post-synthesis method. The resultant MCM-22-DA-Mo showed promising activity on iso-eugenol oxidation with a conversion of 87%.

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Acknowledgements

The author thanks DST-SERB-CRG (Project No: CRG/2019/004624) for financial support. Preeti and Sreenavya are grateful to Central University of Kerala for the fellowship and Lab facilities.

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Author notes

  1. Preeti Sahu and Alex Tincy have equally contributed.

Authors and Affiliations

  1. Inorganic Materials & Heterogeneous Catalysis Laboratory, Department of Chemistry, School of Physical Sciences, Central University of Kerala, Kasaragod, Kerala, 671320, India

    Preeti Sahu, Alex Tincy, Awadakkam Sreenavya & Ayyamperumal Sakthivel

  2. Materials Science & Catalysis Division, Poornaprajna Institute of Scientific Research (PPISR), Bidalur Post, Devanahalli, Bengaluru, 562164, India

    Ganapati Shanbhag

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  1. Preeti Sahu
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  2. Alex Tincy
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  3. Awadakkam Sreenavya
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  4. Ganapati Shanbhag
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  5. Ayyamperumal Sakthivel
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Correspondence to Ayyamperumal Sakthivel.

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Sahu, P., Tincy, A., Sreenavya, A. et al. Molybdenum Carbonyl Grafted on Amine-Functionalized MCM-22 as Potential Catalyst for Iso-Eugenol Oxidation. Catal Lett 151, 1336–1349 (2021). https://doi.org/10.1007/s10562-020-03388-5

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  • DOI: https://doi.org/10.1007/s10562-020-03388-5

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