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Highly Efficient Synthesis of C2+ Oxygenates from CO Hydrogenation Over Rh–Mn–Li/SiO2 Catalyst: The Effect of TiO2 Promoter

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Abstract

The effect of titanium promotion on the catalytic performance of Rh–Mn–Li catalyst supported on PVP-modified SiO2 for C2+ oxygenates synthesis from CO hydrogenation was investigated. The highest selectivity toward C2+ oxygenates (51.3%) was achieved over the RML/0.5Ti/SiO2 catalyst. Characterization results indicates that the addition of Ti promotes the adsorption of geminal CO and the formation of Rh+, which is favorable for the CO insertion into metal-CHx band, and finally increases the selectivity of C2+ oxygenates.

Graphical Abstract

The effect of titanium promotion on the catalytic performance of Rh–Mn–Li catalyst supported on PVP-modified SiO2 for C2+ oxygenates synthesis from CO hydrogenation was investigated. The highest selectivity toward C2+ oxygenates (51.3%) was achieved over the RML/0.5Ti/SiO2 catalyst

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Acknowledgements

The authors gratefully acknowledge financial support from the Leading Academic Discipline Project of Shanghai Education Committee (J51503) and Shanghai Municipal Science and Technology Commission (13ZR1461900).

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Authors and Affiliations

  1. Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai, 201418, China

    Dan Ding, Jun Yu, Qiangsheng Guo, Xiaoming Guo, Haifang Mao & Dongsen Mao

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  1. Dan Ding
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  2. Jun Yu
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  3. Qiangsheng Guo
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  4. Xiaoming Guo
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  5. Haifang Mao
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  6. Dongsen Mao
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Correspondence to Jun Yu or Dongsen Mao.

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Ding, D., Yu, J., Guo, Q. et al. Highly Efficient Synthesis of C2+ Oxygenates from CO Hydrogenation Over Rh–Mn–Li/SiO2 Catalyst: The Effect of TiO2 Promoter. Catal Lett 148, 2619–2626 (2018). https://doi.org/10.1007/s10562-018-2444-y

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  • DOI: https://doi.org/10.1007/s10562-018-2444-y

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