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Palladium-Alumoxane Framework as a Novel and Reusable Nanocatalyst for Suzuki–Miyaura, Stille and Heck Cross Coupling Reactions

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Abstract

Herein for the first time, a Schiff base alumoxane-supported palladium (SBA-Pd°) were successfully synthesized and reported as a new mesoporous nanocatalyst for C–C cross coupling reactions. The SBA-Pd° nanocatalyst could be dispersed in poly(ethylene glycol) and showed excellent catalytic activity for Suzuki–Miyaura, Stille and Heck coupling reactions. In addition, the nanocatalyst could be recovered and reused several times without significant loss of its catalytic activity. Pd leaching from SBA-Pd° is very negligible for this coupling reaction.

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Acknowledgements

Authors thank Ilam University and Iran National Science Foundation (INSF) for financial support of this research project.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, Ilam University, Ilam, Iran

    Arash Ghorbani-Choghamarani, Ali Ashraf Derakhshan & Maryam Hajjami

  2. Polymer Research Laboratory, Department of Chemical Engineering, Razi University, Kermanshah, Iran

    Laleh Rajabi

Authors
  1. Arash Ghorbani-Choghamarani
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  2. Ali Ashraf Derakhshan
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  3. Maryam Hajjami
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  4. Laleh Rajabi
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Correspondence to Arash Ghorbani-Choghamarani.

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Ghorbani-Choghamarani, A., Derakhshan, A.A., Hajjami, M. et al. Palladium-Alumoxane Framework as a Novel and Reusable Nanocatalyst for Suzuki–Miyaura, Stille and Heck Cross Coupling Reactions. Catal Lett 147, 110–127 (2017). https://doi.org/10.1007/s10562-016-1904-5

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  • DOI: https://doi.org/10.1007/s10562-016-1904-5

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