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Bimetallic Ni—Mo Sulfide Catalysts Based on Mesoporous Aluminosilicate (Al-HMS) in Shale Oil Hydrocracking

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Chemistry and Technology of Fuels and Oils Aims and scope

The activity and selectivity of bimetallic Ni—Mo sulfide catalysts based on mesoporous aluminosilicate (Al-HMS) with a Si/Al ratio of 5 in shale oil hydrocracking were investigated in a fixed-bed catalytic reactor. The temperature dependences of the activity and selectivity of NiS—MoS2/Al-HMS (Si/Al = 5) were studied. It was shown that this catalyst in the temperature range 330-400°C at an H2 pressure of 5 MPa converted the shale oil heavy fraction into fuel fractions with high selectivity for the middle distillate and reduced by 78% the sulfur content in the liquid hydrocracking products.

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Acknowledgments

The work was performed under FTP Research and Development on Priority Development Areas of the Russian Scientific-Technical Complex for 2014-2020 with financial support from the Ministry of Education and Science of the RF (Project No. 14.607.21.0051, unique applied scientific research identifier RFMEFI60714X0051). We thank Khromos Co. for supplying the equipment (Khromos GKh-1000 GC).

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, Moscow, Russia

    E. A. Karakhanov, A. V. Vutolkina, S. V. Kardashev, Yu. S. Kardasheva, S. V. Egazar’yants, K. A. Suprankov & N. A. Sinikova

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  1. E. A. Karakhanov
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  2. A. V. Vutolkina
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  3. S. V. Kardashev
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  4. Yu. S. Kardasheva
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  5. S. V. Egazar’yants
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  6. K. A. Suprankov
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  7. N. A. Sinikova
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Corresponding author

Correspondence to E. A. Karakhanov.

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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 12 – 16, November – December, 2016.

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Karakhanov, E.A., Vutolkina, A.V., Kardashev, S.V. et al. Bimetallic Ni—Mo Sulfide Catalysts Based on Mesoporous Aluminosilicate (Al-HMS) in Shale Oil Hydrocracking. Chem Technol Fuels Oils 52, 638–645 (2017). https://doi.org/10.1007/s10553-017-0755-0

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  • DOI: https://doi.org/10.1007/s10553-017-0755-0

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