Abstract
In recent years, aqueous zinc-ion batteries (AZIBs) have been rapidly developed and are favored by the public as a future large-scale energy storage system. Manganese-based compounds with multiple valence states and high electrochemical activity have been extensively investigated as cathodes for AZIBs due to their abundant reserves and high theoretical capacity. However, some problems hinder their application in AZIBs, such as low conductivity and sluggish kinetics. Defect engineering has been verified as an effective method to alleviate the above limitations. In this work, manganese oxide with oxygen defects (Od-MnO2) was successfully constructed and characterized by XRD, SEM, XPS, and TEM. Surface oxygen defects increase ion active transfer sites and improve electronic conductivity. Compared with MnO2, Od-MnO2 produced more localized electrons which could improve the electrochemical performance as cathodes for AZIBs. The discharge specific capacity of Od-MnO2 reaches 307.9 mAh g−1 in the first cycle at a current density of 0.1 A g−1 and maintains at 100.5 mAh g−1 at a current density of 10.0 A g−1. After 1000 cycles, the discharge specific capacity can still reach 82.5 mAh g−1 and the capacity retention rate is 82.1%.
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References
Thangarasu S, Seo H, Jung H-Y (2021) Feasibilities and electrochemical performance of surface-modified polyester separator for lead-acid battery applications. Electrochim Acta 388:138390
Zhu S, Wang Q, Ni JF (2023) Aqueous transition-metal ion batteries: materials and electrochemistry. Energychem 5(3):28
Selvakumaran D, Pan A, Liang S, Cao G (2019) A review on recent developments and challenges of cathode materials for rechargeable aqueous Zn-ion batteries. J Mater Chem A 7(31):18209–18236
He P, Chen Q, Yan M, Xu X, Zhou L, Mai L, Nan C-W (2019) Building better zinc-ion batteries: a materials perspective. EnergyChem 1(3):100022
Chen Y, Zhuo S, Li Z, Wang C (2020) Redox polymers for rechargeable metal-ion batteries. EnergyChem 2(2):100030
Alias N, Mohamad AA (2015) Advances of aqueous rechargeable lithium-ion battery: a review. J Power Sources 27:237–251
Liu YY, Yuan GQ, Wang XY, Liu JP, Zeng QY, Guo XT, Wang H, Liu CS, Pang H (2022) Tuning electronic structure of ultrathin V6O13 nanobelts via nickel doping for aqueous zinc-ion battery cathodes. Chem Eng J 428:132538
Diouf B, Pode R (2015) Potential of lithium-ion batteries in renewable energy. Renew Energy 76:375–380
Liu L, Hou Y, Wu X, Xiao S, Chang Z, Yang Y, Wu Y (2013) Nanoporous selenium as a cathode material for rechargeable lithium-selenium batteries. Chem Commun (Camb) 49(98):115–157
Zhang Y, Liu J, Li S-L, Su Z-M, Lan Y-Q (2019) Polyoxometalate-based materials for sustainable and clean energy conversion and storage. EnergyChem 1(3):100021
Nitta N, Wu F, Lee JT, Yushin G (2015) Li-ion battery materials: present and future. Mater Today 18(5):252–264
Wu X, Luo Y, Sun M, Qian J, Cao Y, Ai X, Yang H (2015) Low-defect Prussian blue nanocubes as high capacity and long life cathodes for aqueous Na-ion batteries. Nano Energy 13:117–123
Gao M, Xue Y, Zhang Y, Zhu C, Yu H, Guo X, Sun S, Xiong S, Kong Q, Zhang J (2022) Growing Co-Ni-Se nanosheets on 3D carbon frameworks as advanced dual functional electrodes for supercapacitors and sodium ion batteries. Inorg Chem Front 9(15):3933–3942
Xue Y, Guo X, Wu M, Chen J, Duan M, Shi J, Zhang J, Cao F, Liu Y, Kong Q (2021) Zephyranthes-like Co2NiSe4 arrays grown on 3D porous carbon frame-work as electrodes for advanced supercapacitors and sodium-ion batteries. Nano Res 14(10):3598–3607
Guo X, Duan M, Zhang J, Xi B, Li M, Yin R, Zheng X, Liu Y, Cao F, An X, Xiong S (2022) A general self-assembly induced strategy for synthesizing 2D ultrathin cobalt-based compounds toward optimizing hydrogen evolution catalysis. Adv Func Mater 32(51):2209397
Guo X, Liu S, Wan X, Zhang J, Liu Y, Zheng X, Kong Q, Jin Z (2022) Controllable solid-phase fabrication of an Fe2O3/Fe5C2/Fe-N-C electrocatalyst toward optimizing the oxygen reduction reaction in zinc-air batteries. Nano Lett 22(12):4879–4887
Wang X, Xu L, Chang YZ, Song H, Hou WJ, Zhang Y, Li YP, Zhu S, Xiao YM, Han GY (2023) Electrodeposition of polypyrrole for high-performance zinc ion battery. J Solid State Electrochem 27(6):1459–1467
Fang GZ, Zhu CY, Chen MH, Zhou J, Tang BY, Cao XX, Zheng XS, Pan AQ, Liang SQ (2019) Suppressing manganese dissolution in potassium manganate with rich oxygen defects engaged high-energy-density and durable aqueous zinc-ion battery. Adv Func Mater 29(15):1808375
Han MM, Huang JW, Liang SQ, Shan LT, Xie XS, Yi ZY, Wang YR, Guo S, Zhou J (2020) Oxygen defects in beta-MnO2 enabling high-performance rechargeable aqueous zinc/manganese dioxide battery. Iscience 23(1):100797
Xiong T, Yu ZG, Wu H, Du Y, Xie Q, Chen J, Zhang YW, Pennycook SJ, Lee WSV, Xue J (2019) Defect engineering of oxygen-deficient manganese oxide to achieve high-performing aqueous zinc ion battery. Adv Energy Mater 9(14):1803815
Xiong T, Zhang Y, Lee WSV, Xue J (2020) Defect engineering in manganese-based oxides for aqueous rechargeable zinc-ion batteries: a review. Adv Energy Mater 10(34):2001769
Zhao Y, Chang C, Teng F, Zhao Y, Chen G, Shi R, Waterhouse GIN, Huang W, Zhang T (2017) Defect-engineered ultrathin delta-MnO2 nanosheet arrays as bifunctional electrodes for efficient overall water splitting. Adv Energy Mater 7(18):1700005
Pan H, Shao Y, Yan P, Cheng Y, Han KS, Nie Z, Wang C, Yang J, Li X, Bhattacharya P, Mueller KT, Liu J (2016) Reversible aqueous zinc/manganese oxide energy storage from conversion reactions. Nat Energy 1(5):16039
Altaf NH, Anjam T, Sajid MM, Shad NA, Shukrullah S, Naz MY, Javed Y (2020) Characterization of manganese/cobalt oxide composites synthesized by chemical co-precipitation method. IOP Conf Ser: Mater Sci Eng 863(1):012021
Cheng F, Zhang T, Zhang Y, Du J, Han X, Chen J (2013) Enhancing electrocatalytic oxygen reduction on MnO2 with vacancies. Angew Chem Int Ed Engl 52(9):2474–2477
Heidari S, Balaghi SE, Sologubenko AS, Patzke GR (2021) Economic manganese-oxide-based anodes for efficient water oxidation: rapid synthesis and in situ transmission electron microscopy monitoring. ACS Catal 11(5):2511–2523
Li Y, Zhang D, Huang S, Yang HY (2021) Guest-species-incorporation in manganese/vanadium-based oxides: towards high performance aqueous zinc-ion batteries. Nano Energy 85:105969
Liu Y, Wu X (2022) Strategies for constructing manganese-based oxide electrode materials for aqueous rechargeable zinc-ion batteries. Chin Chem Lett 33(3):1236–1244
Tang H, Chen W, Li N, Hu Z, Xiao L, Xie Y, Xi L, Ni L, Zhu Y (2022) Layered MnO2 nanodots as high-rate and stable cathode materials for aqueous zinc-ion storage. Energy Storage Mater 48:335–343
Zhao YL, Zhu YH, Zhang XB (2020) Challenges and perspectives for manganese-based oxides for advanced aqueous zinc-ion batteries. Infomat 2(2):237–260
Dai Y, Wang X, Zhu X, Liu H, Wang P, Wang X, Zhang S, Sun Y, Gao D, Han R, Luo C (2020) Electrochemical assays for determination of H2O2 and prostate-specific antigen based on a nanocomposite consisting of CeO2 nanoparticle-decorated MnO2 nanospheres. Mikrochim Acta 187(8):428
Wu Y, Fee J, Tobin Z, Shirazi-Amin A, Kerns P, Dissanayake S, Mirich A, Suib SL (2020) Amorphous manganese oxides: an approach for reversible aqueous zinc-ion batteries. ACS Appl Energy Mater 3(2):1627–1633
Sada K, Barpanda P (2019) Layered sodium manganese oxide Na2Mn3O7 as an insertion host for aqueous zinc-ion batteries. Mrs Adv 4(49):2651–2657
Zhu S, Wang Y, Zhang J, Sheng J, Yang F, Wang M, Ni J, Jiang H, Li Y (2022) Jahn-Teller effect directed bandgap tuning of birnessite for pseudocapacitive application. Energy Environ Mater 6(3):e12382
Gou L, Yang Y, Zhang YF, Li JR, Fan XY, Li DL (2023) In situ synthesis of Bi3+-doped δ-MnO2 cathode to enhance the cycle stability for aqueous zinc-ion batteries. J Solid State Electrochem 27(6):1443–1450
Liu D, Wang C, Yu Y, Zhao B-H, Wang W, Du Y, Zhang B (2019) Understanding the nature of ammonia treatment to synthesize oxygen vacancy-enriched transition metal oxides. Chem 5(2):376–389
Ji D, Fan L, Tao L, Sun Y, Li M, Yang G, Tran TQ, Ramakrishna S, Guo S (2019) The Kirkendall effect for engineering oxygen vacancy of hollow Co3O4 nanoparticles toward high-performance portable zinc-air batteries. Angew Chem Int Ed Engl 58(39):13840–13844
Wang Y, Zhou T, Jiang K, Da P, Peng Z, Tang J, Kong B, Cai W-B, Yang Z, Zheng G (2014) Reduced mesoporous Co3O4 nanowires as efficient water oxidation electrocatalysts and supercapacitor electrodes. Adv Energy Mater 4(16):1400696
Lin KA, Oh WD, Zheng MW, Kwon E, Lee J, Lin JY, Duan X, Ghanbari F (2021) Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using manganese dioxide with different crystal structures: a comparative study. J Colloid Interface Sci 592:416–429
Ma J, Zhang S, Duan X, Wang Y, Wu D, Pang J, Wang X, Wang S (2021) Catalytic oxidation of sulfachloropyridazine by MnO2: effects of crystalline phase and peroxide oxidants. Chemosphere 267:129287
Ma S, Guo J, Ye X, Tian B, Jiang X, Gao T (2022) Mechanistic and thermodynamic insights into the SO2 oxidation on MnO2 catalysts: a combined theoretical and experimental study. Chemosphere 307(Pt 2):135885
Funding
This work was supported by the Natural Science Foundation of Jiangsu Province (Grant No. BK20201472), Changzhou Science and Technology Bureau (CM20223017), and the National Natural Science Foundation of China (No. 51972151, 52171212).
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Qiaohui Li: data curation, writing—original draft preparation. Zhixiang Cao and Aohua Wu: visualization, software. Xinyue Zhang, Jiaqi Zhang, and Jiajie Gu: investigation. Wutao Mao: conceptualization, methodology, formal analysis. Keyan Bao: writing, reviewing. Zhongcheng Song: editing, project administration, validation.
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Li, Q., Cao, Z., Wu, A. et al. Construction of MnO2 with oxygen defects as cathode material for aqueous zinc ion batteries. J Solid State Electrochem (2024). https://doi.org/10.1007/s10008-024-05856-z
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DOI: https://doi.org/10.1007/s10008-024-05856-z