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Measurement model for analysis of electrochemical impedance data

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Abstract

A tutorial is presented for the recently published measurement model program, made available under the open-source license GNU GPL Version 3, which allows free use for scientific purposes but limits commercial use. The program may be used to identify the portion of the measured frequency range suitable for subsequent regression analysis, the stochastic error structure used to weight the regressions, and some key parameters such as the ohmic resistance and capacitance, enabling calculation of the critical frequency associated with electrode-geometry-induced frequency dispersion. The equation-based custom-model part of the program enables regression of models that are not limited to electrical circuits. The measurement model enables a more sophisticated analysis of impedance data, allowing researchers to take full advantage of the information that can be extracted from electrochemical impedance spectroscopy measurements.

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Data availability

The impedance data used for the present work are available as a zipped file. Please see https://www.che.ufl.edu/Download/Orazem-Data.zip.

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Acknowledgements

The author thanks his colleague Prof. Won Tae Choi and Prof. Choi’s student Seokjun Han for providing the electrodes used in this study, his graduate students Cynthia Eluagu, Yunhan Chuai, and Bernard Biney for performing the impedance measurements, and his former undergraduate William Watson for writing the code that was used in the regression analysis.

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  1. Department of Chemical Engineering, University of Florida, Gainesville, FL, 32611, USA

    Mark E. Orazem

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  1. Mark E. Orazem
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Orazem, M.E. Measurement model for analysis of electrochemical impedance data. J Solid State Electrochem 28, 1273–1289 (2024). https://doi.org/10.1007/s10008-023-05755-9

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