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Impedance Spectroscopy

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Modern Techniques of Spectroscopy

Abstract

Impedance spectroscopy (IS) is a powerful technique used for characterizing the electrical properties of systems in which the overall behavior is determined by several strongly coupled processes. Impedance studies have become popular since high quality impedance bridges and automated measuring devices covering wide range of frequencies from mHz to few MHz are easily available. Thus, material scientists, engineers, electrochemists are fascinated to understand the theoretical background of these studies and gain skills in interpreting impedance data. In IS, the linear electrical response of materials including electrode effects are measured and subsequently the response is analyzed to obtain valuable information about the physiochemical features of the system. The analysis is performed in the frequency domain or in time domain. In time domain, the measurements are converted into frequency domain by Fourier transform. IS not only measures data at the impedance (Z) level but can include admittance (Y), complex dielectric constant (ε) or its inverse i.e. complex modulus (M). It plots these functions in the complex plane.

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References

  1. J.R. Macdonald, Annals Bio. Eng. 20, 289–305 (1992)

    Article  Google Scholar 

  2. A.J. Bard, M. Dekker (eds.), Electroanalytical Chemistry (New York, 1966)

    Google Scholar 

  3. N.S.K. Kumar, T.S. Shahid, G. Govindaraj, Phys. B 488, 99–107 (2016)

    Article  ADS  Google Scholar 

  4. R. Punia, R.S. Kundu, M. Dult, S. Murugavel, N. Kishore, J. Appl. Phys. 112, 083701 (2012)

    Article  ADS  Google Scholar 

  5. B. Behera, P. Nayak, R.N.P. Choudhary, J. Alloys Compd. 436, 226 (2007)

    Article  Google Scholar 

  6. J.R. Macdonald, M.K. Brachman, Rev. Mod. Phys. 28, 393–422 (1956)

    Article  ADS  MathSciNet  Google Scholar 

  7. K.S. Cole, R.H. Cole, J. Chem. Phys. 9, 341–351 (1941)

    Article  ADS  Google Scholar 

  8. J. Schrama, Ph.D. thesis, University of Leiden, Netherlands (1957).

    Google Scholar 

  9. P.B. Macedo, C.T. Moynihan, R. Bose, Physics Chem. Glasses 13, 171–179 (1972)

    Google Scholar 

  10. I.M. Hodge, M.D. Ingram, A.R. West, J. Electroanal. Chem. 58, 429–432 (1975)

    Article  Google Scholar 

  11. I.M. Hodge, M.D. Ingram, A.R. West, J. Electroanal. Chem. 74, 125–143 (1976)

    Article  Google Scholar 

  12. N.G. McCrum, B.E. Read, G. Williams, Anelastic and Dielectric Effects in Polymeric Solids (Wiley, London, 1976), p. 111

    Google Scholar 

  13. W. Cao, R. Gerhardt, Solid State Ionics 42, 213–221 (1990)

    Article  Google Scholar 

  14. M.J. Pulikkathumbayil, G. Govindaraj, Materials Lett. 264, 127314 (2020)

    Article  Google Scholar 

  15. J.E. Bauerle, J. Phys. Chem. Solids 30, 2657–2670 (1969)

    Article  ADS  Google Scholar 

  16. D.D. Macdonald, Transient Techniques in Electrochemistry (Plenum Press, New York, 1977).

    Book  Google Scholar 

  17. U. Bertocci, Corrosion 35, 211–215 (1979)

    Article  Google Scholar 

  18. D.D. Macdonald, M.C.H. McKubre, Electrochemical Corrosion Testing, (Florian Mansfield and Ugo Bertocci, STP 727 (ASTM, Philadelphia, 1981).

    Google Scholar 

  19. L.E. Eiselstein, M.C.H. McKubre, R.D. Caligiuri, Prediction of Crack Growth in Aqueous Environments, First Annual Report by SRI to the Office of Naval Research, N00014-82-K-0343 (1983)

    Google Scholar 

  20. B.C. Syrett, D.D. Macdonald, Corrosion 35, 505–508 (1979)

    Article  Google Scholar 

  21. B. Hague, AC Bridge Methods (Pitman, London, 1957).

    Google Scholar 

  22. R.D. Armstrong, W.P. Race, H.R. Thirsk, Electrochim. Acta 13, 215 (1968)

    Article  Google Scholar 

  23. R.D. Armstrong, T. Dickinson, P.M. Willis, J. Electroanal. Chem. 53, 389–405 (1974)

    Article  Google Scholar 

  24. R. Calvert, Electron. Eng. 20, 28–29 (1948)

    Google Scholar 

  25. J.G. Berberian, R.H. Cole, Rev. Sci. Instrum. 40, 811 (1969)

    Article  ADS  Google Scholar 

  26. M.C.H. McKubre, D.D. Macdonald, in A Comprehensive Treatise of Electrochemistry, ed. J. O’M. Bockris, B.E. Conway, E. Yeager (Plenum Press, New York, 1984) pp. 1–98

    Google Scholar 

  27. R. Brown, D.E. Smith, G. Booman, Anal. Chem. 40, 1411 (1968)

    Article  Google Scholar 

  28. E. Barsoukov, J.R. Macdonald, Impedance Spectroscopy-Theory (Experiemnt and Applications, Wiley, New Jersey, 2005).

    Book  Google Scholar 

  29. Gabrielli and M. Keddam, Electrochim. Acta 19, 355 (1974)

    Google Scholar 

  30. Gabrielli, M. Keddam, H. Perrot, R. Torresi, J. Electroanal. Chem. 378, 85–92 (1994)

    Google Scholar 

  31. R.D. Armstrong, M.F. Bell, A.A. Metcalfe, J. Electroanal. Chem. 84, 61 (1977)

    Article  Google Scholar 

  32. M.C.H. McKubre, An Impedance Study of the Membrane Polarization Effect in Simulated Rock Systems, Ph.D. thesis, Victoria University, Wellington, N.Z. (1976)

    Google Scholar 

  33. R. Liang, B.G. Pound, D.D. Macdonald, Ext. Abst. Electrochem. Soc. 84–2, 356 (1984)

    Google Scholar 

  34. X.-Z. Yuan, C. Song, H. Wang, J. Zhang, Electrochemical Impedance Spectroscopy in PEM Fuel Cells Fundamentals and Applications (Springer, London, 2010).

    Book  Google Scholar 

  35. P. Debye, Polar Molecules (Chemical Catalog Co., New York, 1929).

    MATH  Google Scholar 

  36. A. Lasia, Electrochemical Spectroscopy and Its Applications (Sringer, New York, 2014).

    Book  Google Scholar 

  37. V.F. Lvovich, Impedance Spectroscopy-Applications to Electrochemical and Dielectric Phenomena (Wiley, New Jersey, 2012).

    Book  Google Scholar 

  38. A. Dwivedi, R. Dhar, M.B. Pandey, I.M.L. Das, R. Dabrowski, J. Mol. Liq. 148, 1–5 (2009)

    Article  Google Scholar 

  39. W. Hasse, S. Wrobel, Relaxation Phenomena (Springer, Berlin, 2003).

    Book  Google Scholar 

  40. N. Yadav, S. Kumar, R. Dhar, RSC Adv. 5, 78823 (2015)

    Article  ADS  Google Scholar 

  41. M.B. Pandey, R. Dhar, R. Dabrowski, J. Phys, Condens. Matter. 20, 115207–115211 (2008)

    Article  ADS  Google Scholar 

  42. C J. F. Bottcher, P. Bordewijk, Theory of Electric Polarisation, Vol. II (Elsevier, Amsterdam, 1978), p 72

    Google Scholar 

  43. F. Gouda, K. Skarp, S.T. Lagerwall, Ferroelectrics 113, 165–206 (1991)

    Article  Google Scholar 

  44. S.L. Srivastava, R. Dhar, Indian J. Pure & Appl. Phys. 29, 745–751 (1991)

    Google Scholar 

  45. N. Yadav, V.P. Panov, V. Swaminathan, S.P. Sreenilayam, J.K. Vij, T.S. Perova, R. Dhar, A. Panov, D. Rodriguez-Lojo, P.J. Stevenson, Phys. Rev. E. 95, 062704 (2017)

    Article  ADS  Google Scholar 

  46. S.L. Srivastava, Proc. Natl. Acad. Sci. (India) 63, 311 (1993); R. Dhar, Indian J. Pure & Appl. Phys. 42, 56–61 (2004)

    Google Scholar 

  47. A. Dwivedi, R. Dhar, R. Dabrowski, M. Tykarska, J. Phys. D: Appl. Phys. 42, 095402 (2009)

    Article  ADS  Google Scholar 

  48. N. Yadav, R. Dabrowski, R. Dhar, Liq. Cryst. 41, 1803 (2014)

    Article  Google Scholar 

  49. M. Shahin, S.S.N. Murthy, J. Chem. Phys. 118, 7495 (2003)

    Google Scholar 

  50. Z. Wojnarowska, K.J. Paluch, L. Tajner, K. Grzybowska, K.L. Ngai, M. Paluch, Phys. Chem. Chem. Phys. 15, 9205 (2013)

    Article  Google Scholar 

  51. M. Gupta, R. Dhar, V.K. Agrawal, R. Dabrowski, M. Tykarska, Phys. Rev. E 72, 021703 (2005)

    Article  ADS  Google Scholar 

  52. F. Kremer, A. Schönhals (eds.), Broadband Dielectric Spectroscopy (Springer, Berlin, Heidelberg, 2003)

    Google Scholar 

  53. B.D. Cahan, C.-T. Chen, J. Electrochem. Soc. 129, 474–480 (1982)

    Article  ADS  Google Scholar 

  54. S.P. Sreenilayam, D.M. Agra-Kooijman, V.P. Panov, V. Swaminathan, J.K. Vij, Yu.P. Panarin, A. Kocot, A. Panov, D. Rodriguez-Lojo, P.J. Stevenson, M.R. Fisch, S. Kumar, Phys. Rev. E 95, 032701 (2017)

    Article  ADS  Google Scholar 

  55. J.R. Macdonald, L.D. Potter, Solid State Ionics 23, 61–79 (1987)

    Article  Google Scholar 

  56. J.R. Macdonald, in C. Gabrielli, (ed.) Proceedings of the First International Symposium on Electrochemical Impedance Spectroscopy. Electrochim. Acta, 1990, vol 35, pp. 1483–1492

    Google Scholar 

  57. J.H. Sluyters, J.J.C. Oomen, Rec. Trav. Chim. 79, 1101–1110 (1960)

    Article  Google Scholar 

  58. S. Brahma, R.N.P. Choudhary, A.K. Thakur, Phys. B 355, 188–201 (2005)

    Article  ADS  Google Scholar 

  59. B.P. McGettrick, J.K. Vij, C.B. McArdle, Int. J. Adhesion Adhesives 14, 211–236 (1994)

    Article  Google Scholar 

  60. B.K. Barick, K.K. Mishra, A.K. Arora, R.N.P. Choudhary, D.K. Pradhan, J. Phys. D: Appl. Phys. 44, 355402 (2011)

    Article  Google Scholar 

  61. G. Ranga Mohan, D. Ravinder, A.V. Ramana Reddy, B.S. Boyanov, Mater. Lett. 40, 39 (1999)

    Google Scholar 

  62. N. Ponpandian, A. Narayanasamy, J. Appl. Phys. 92, 2770 (2002)

    Article  ADS  Google Scholar 

  63. L. Zhang, Z.-J. Tang, Phys. Rev. B 70, 174306 (2004)

    Article  ADS  Google Scholar 

  64. N.S.K. Kumar, T.S. Shahid, G. Govindaraj, Phys. B Phys. Condens. Matter 488, 99 (2016)

    Article  ADS  Google Scholar 

  65. G.P. Johari, M. Kim, S. Shanker, J. Pharm. Sci. 94, 2207–2223 (2005)

    Article  Google Scholar 

  66. K. Kaminski, S. Maslanka, J. Ziolo, M. Paluch, K.J. McGrath, and C. M. Roland Phys. Rev. E 75, 0119031–0119037 (2007)

    Google Scholar 

  67. C.R. Mariappana, G. Govindaraja, B. Roling, Solid State Ionics 176, 723–729 (2005)

    Article  Google Scholar 

  68. H.H.M. Elkhalgi, S. Khandka, N. Yadav, R. Dhar, R. Dabrowski, J. Mol. Liq. 268, 223–228 (2018)

    Article  Google Scholar 

  69. R. Uttam, N. Yadav, S. Kumar, R. Dhar, J. Mol. Liq. 294, 111609 (2019)

    Article  Google Scholar 

  70. S.K. Prasad, M.V. Kumar, T. Shilpa, C.V. Yelamaggad, RSC Adv. 4, 4453–4462 (2014)

    Article  ADS  Google Scholar 

  71. R. Dhar, A.S. Pandey, M.B. Pandey, S. Kumar, R. Dabrowski, Appl. Phys. Express 1, 121501 (2008)

    Article  ADS  Google Scholar 

  72. S.L. Srivastava, R. Dhar, Radiat. Phys. Chem. 47, 287–293 (1996)

    Article  ADS  Google Scholar 

  73. A.K. Jonscher, Nature 267, 673 (1977)

    Article  ADS  Google Scholar 

  74. M. Mishra, S. Kumar, R. Dhar, RSC. Adv. 4, 62404–62412 (2014)

    Article  ADS  Google Scholar 

  75. J. Janata, R.J. Huber (eds.), Solid State Chemical Sensors (Academic Press, New York, 1985)

    Google Scholar 

  76. H. Abe, M. Esashi, T. Matsuo, IEEE Trans. Electron Devices ED-26, 1939–1944 (1979)

    Google Scholar 

  77. E.H. Nicollian, A. Goetzberger, Bell Syst. Tech. J. 46, 1055–1133 (1967)

    Article  Google Scholar 

  78. J.L. Diot, J. Joseph, J.R. Matin, P. Clechet, Electroanal. Chem. 193, 75–88 (1985)

    Article  Google Scholar 

  79. N. Matsui, Solid State Ionics 3(4), 525–529 (1981)

    Article  Google Scholar 

  80. S.P.S. Badwal, J. Electroanal. Chem. 146, 425–429 (1983)

    Article  Google Scholar 

  81. A.J. Bard, L.R. Faulkner, Electrochemical Methods: Fundamentals and Applications (Wiley, New York, 1980).

    Google Scholar 

  82. J.F. McCann, S.P.S. Badwal, J. Electrochem. Soc. 129, 551–559 (1982)

    Article  ADS  Google Scholar 

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Acknowledgements

We are grateful to Prof. S. L. Srivastava, formerly Head of the Physics Department, University of Allahabad, Allahabad for his valuable comments and suggestions. Thanks to Mr. Rahul Uttam, a Research Scholar at Centre of Materials Sciences for his help in preparing some of the figures.

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Yadav, N., Dhar, R. (2021). Impedance Spectroscopy. In: Singh, D.K., Pradhan, M., Materny, A. (eds) Modern Techniques of Spectroscopy. Progress in Optical Science and Photonics, vol 13. Springer, Singapore. https://doi.org/10.1007/978-981-33-6084-6_19

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