Abstract
A quick and sensitive method was developed for the trace determination of Cd(II), Pb(II) and Cu(II) ions in water and bean samples. It is based on a combination of magnetic solid phase extraction (MSPE) and graphite furnace atomic absorption spectrometry (GFAAS). Allylthiourea (which contains abundant sulfur and nitrogen atoms) was copolymerized with ethylene dimethacrylate on the surface of magnetite (Fe3O4) nanoparticles to prepare a new adsorbent for use in MSPE. Various technologies were used to characterize the morphology, spectroscopic and magnetic properties of the adsorbent, and several parameters that affect the extraction performance were optimized. The adsorbent can enrich Cd(II), Pb(II) and Cu(II) ions via chelation interaction. Following elution with 0.1 mol·L−1 HNO3, the ions were quantified by GFAAS. Under the most favorable conditions, the limits of detection are from 3.3–7.2 ng·L−1 for water samples, and 1.1–1.5 μg·kg−1 for beans. The method displays wide linear analytical ranges and good precision. It was successfully applied to the determination of the metal ions in water and bean samples. The recoveries from spiked samples ranged between 80.5 and 114% in water, and from 82.2 to 118% in bean samples. The relative standard deviations of reproducibility were < 10%.
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References
Bings NH, von Niessen JOO, Schaper JN (2014) Liquid sample introduction in inductively coupled plasma atomic emission and mass spectrometry-critical review. Spectrochim Acta B 100:14–37
Pohl P, Dzimitrowicz A, Jamroz P, Greda K (2018) Development and optimization of simplified method of fast sequential HR-CS-FAAS analysis of apple juices on the content of Ca, Fe, K, Mg, Mn and Na with the aid of response surface methodology. Talanta 189:182–189
Bauer OB, Koeppen C, Sperling M, Schurek HJ, Ciarimbol G, Karst U (2018) Quantitative bioimaging of platinum via online isotope dilution laser ablation-inductively coupled plasma mass spectrometry. Anal Chem 90:7033–7039
Comino F, Ayora-Canada MJ, Aranda V, Diaz A, Dominguez-Vida A (2018) Near-infrared spectroscopy and X-ray fluorescence data fusion for olive leaf analysis and crop nutritional status determination. Talanta 188:676–684
Peng HY, Zhang N, He M, Chen BB, Hu B (2015) Simultaneous speciation analysis of inorganic arsenic, chromium. And selenium in environmental waters by 3-(2-aminoethylamino) propyltrimethoxysilane modified multi-wall carbon nanotubes packed microcolumn solid phase extraction and ICP-MS. Talanta 131:266–272
Dimpe KM, Ngila JC, Nomngongo PN (2018) Preparation and application of a Tyre-based activated carbon solid phase extraction of heavy metals in wastewater samples. Phys Chem Earth 105:161–169
Zhou QX, Lei M, Liu YL, Wu YL, Yuan YY (2017) Simultaneous determination of cadmium, lead and mercury ions at trace level by magnetic solid phase extraction with Fe@Ag@Dimercaptobenzene coupled to high performance liquid chromatography. Talanta 175:194–199
Molaei K, Bagheri H, Asgharinezhad AA, Ebrahimzadeh H, Shamsipur M (2017) SiO2-coated magnetic graphene oxide modified with polypyrrole-polythiophene: a novel and efficient nanocomposite for solid phase extraction of trace amounts of heavy metals. Talanta 167:607–616
Hemmati M, Rajabi M, Asghari A (2018) Magnetic nanoparticle based solid-phase extraction of heavy metal ions: a review on recent advances. Microchim Acta 185:160
Rohanifar A, Rodriguez LB, Devasurendra AM, Alipourasiabi N, Anderson JL, Kirchhoff JR (2018) Solid-phase microextraction of heavy metals in natural water with a polypyrrole/carbon nanotube/1, 10-phenanthroline composite sorbent material. Talanta 188:570–577
Kaur V, Malik AK (2009) Speciation of chromium metal ions by RP-HPLC. Chromatogr Sci 47(3):238–242
Ataee M, Ahmadi-Jouibari T, Fattahi N (2016) Application of microwave-assisted dispersive liquid-liquid microextraction and graphite furnace atomic absorption spectrometry for ultra-trace determination of lead and cadmium in cereals and agricultural products. Int J Environ Anal Chem 96(3):271–283
Citak D, Tuzen M (2010) A novel preconcentration procedure using cloud point extraction for determination of lead, cobalt and copper in water and food samples using flame atomic absorption spectrometry. Food Chem Toxicol 48(5):1399–1404
Zhao PF, Wang ZK, Li KJ, Guo XJ, Zhao LS (2018) Multi-residue enantiomeric analysis of 18 chiral pesticides in water, soil and river sediment using magnetic solid-phase extraction based on amino modified multiwalled carbon nanotubes and chiral liquid chromatography coupled with tandem mass spectrometry. J Chromatogr A 1568:8–21
Wang Q, Wang Y, Zhang ZZ, Tong Y, Zhang L (2017) Waxberry-like magnetic porous carbon composites prepared from a nickel-organic framework for solid-phase extraction of fluoroquinolones. Microchim Acta 184(10):4107–4115
Zhang SN, Han PP, Xia Y (2017) +Facile extraction of azide in sartan drugs using magnetized anion-exchange metal-organic frameworks prior to ion chromatography. J Chromatogr A 1514:29–35
Suleiman JS, Hu B, Peng Hy HCZ (2009) Separation/preconcentration of trace amounts of Cr, Cu and Pb in environmental samples by magnetic solid-phase extraction with Bismuthiol-II-immobilized magnetic nanoparticles and their determination by ICP-OES. Talanta 77(5):1579–1583
Fan L, Deng M, Lin CX, Xu C, Liu Y, Shi ZN, Wang YX, Xu ZS, Li L, He M (2018) A multifunctional composite Fe3O4/MOF/Lcysteine for removal, magnetic solid phase extraction and fluorescence sensing of Cd(II). RSC Adv 8(19):10561–10572
Safari M, Yamini Y, Masoomi MY, Morsali A, Mani-Varnosfaderani A (2017) Magnetic metal-organic frameworks for the extraction of trace amounts of heavy metal ions prior to their determination by ICP-AES. Microchim Acta 184(5):1555–1564
Mehdinia A, Shoormeij Z, Jabbari A (2017) Trace determination of lead(II) ions by using a magnetic nanocomposite of the type Fe3O4/TiO2/PPy as a sorbent, and FAAS for quantitation. Microchim Acta 184(5):1529–1537
Habila MA, ALOthman Z, El-Toni AM, Labis JP, Li XM, Zhang F, Soylak M (2016) Mercaptobenzothiazole-functionalized magnetic carbon nanospheres of type Fe3O4@SiO2@C for the preconcentration of nickel, copper and lead prior to their determination by ICP-MS. Microchim Acta 183(8):2377–2384
Liu C, Liao YM, Huang XJ (2017) Fabrication of polymeric ionic liquid-modified magnetic adsorbent for extraction of apolar and polar pollutants in complicated samples. Talanta 172:23–30
Guidelines for drinking-water quality, Fourth edition, Edited by World Health Organization
National Health Commission of the People’s Republic of China, China Food and Drug Administration (GB 2762–2017)
Yebra MC, Cancela S (2005) Continuous ultrasound-assisted extraction of cadmium from legumes and dried fruit samples coupled with on-line preconcentration-flame atomic absorption spectrometry. Anal Bioanal Chem 382(4):1093–1098
Tokalıoglu S, Yavuz E, Demir S, Patat S (2017) Zirconium-based highly porous metal-organic framework (MOF-545) as an efficient adsorbent for vortex assisted-solid phase extraction of lead from cereal, beverage and water samples. Food Chem 237:707–715
Kılınça E, Dündar A, Özdemir S, Okumus V (2013) Solid phase extraction based on the use of agaricus arvensis as a fungal biomass for the peconcentrations of Pb and Al prior to their determination in vegetables by ICP-OES. At Spectrosc 34(3):78–88
Tokalıoglu S, Ayhanöz H (2011) Use of Cu(II) and Fe(III) N-benzoyl-N-phenylhydroxylamine coprecipitants for preconcentration of some trace metal ions in food samples. Food Chem 127(1):359–363
Acknowledgements
This work was supported by National Natural Science Foundation of China (grant: 21777133, 21577111); Fundamental Research Funds for the Central Universities (grant: 20720180107, 20720180108).
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Huang, Y., Peng, J. & Huang, X. Allylthiourea functionalized magnetic adsorbent for the extraction of cadmium, copper and lead ions prior to their determination by atomic absorption spectrometry. Microchim Acta 186, 51 (2019). https://doi.org/10.1007/s00604-018-3101-2
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DOI: https://doi.org/10.1007/s00604-018-3101-2