Abstract
Cadmium was continuously extracted with diluted nitric acid from legumes and dried fruit samples using a simple, rapid and continuous ultrasound-assisted extraction system. A minicolumn packed with a chelating resin (Chelite P, with aminomethylphosphoric acid groups) was placed between the extraction unit and the detector for cadmium preconcentration. The cadmium content in the acid extract was retained into the minicolumn, and elution was carried out with hydrochloric acid, with this trace metal continuously monitored by flame atomic absorption spectrometry. An experimental design (Plackett-Burman 26×3/16) was used to optimize the continuous leaching procedure and the preconcentration step. The method allowed a total sampling frequency of 10 and 14 samples per hour for legumes and dried fruit, respectively. The procedure displayed good precision (2.0 and 2.5%, respectively, expressed as relative standard deviations) for samples containing 0.202±0.005 μg g−1 Cd (broad bean) and 0.239±0.004 μg g−1 Cd (peanut). Detection limits of 0.014 μg g−1 Cd for 60 mg of legume samples and 0.011 μg g−1 Cd for 80 mg of dried fruit samples were obtained. The method was successfully applied to the determination of trace amounts of cadmium in legumes and dried fruit samples.
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References
Robards K, Worsfold P (1991) Analyst 116:549–568
Amoedo L, Capelo JL, Lavilla I, Bendicho C (1999) J Anal Atom Spectrom 14:1221–1226
Ashley K, Andrews RN, Cavazos L, Demange M (2001) J Anal Atom Spectrom 16:1147–1153
Lima EC, Barbosa F, Krug FJ, Silva M, Vale MGR (2000) J Anal Atom Spectrom 15:995–1000
El Azouzi H, Cervera ML, de la Guardia M (1998) J Anal Atom Spectrom 13:533–538
Bermejo-Barrera P, Moreda-Piñeiro A, Bermejo-Barrera A (2000) J Anal Atom Spectrom 15:121–130
Brasil JL, Lima EC, Veses RC, Tissot MM (2004) Atom Spectrosc 25:94–101
Moreno-Cid A, Yebra MC (2002) Spectrochim Acta B 57:967–974
Yebra MC, Moreno-Cid A (2003) Anal Chim Acta 477:149–155
Moreno-Cid A, Yebra MC, Cancela S, Cespón RM (2003) Anal Bioanal Chem 377:730–734
Moreno-Cid A, Yebra MC (2004) Anal Bioanal Chem 379:77–82
Tewari PK, Singh AK (2001) Talanta 53:823–833
Pourreza N, Zavvar MH (2004) Anal Chim Acta 503:279–282
Miller JC, Miller JN (1984) Statistics for analytical chemistry. Ellis Horwood, Chichester, UK
Acknowledgments
The authors are grateful for the financial support provided by the Instituto Nacional de Investigación y Tecnología Agraria y Alimentaria (INIA). Ministerio de Ciencia y Tecnología (Project No. CAL01-043). S.C. acknowledges a grant from the Xunta de Galicia (Spain).
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Yebra, M.C., Cancela, S. Continuous ultrasound-assisted extraction of cadmium from legumes and dried fruit samples coupled with on-line preconcentration-flame atomic absorption spectrometry. Anal Bioanal Chem 382, 1093–1098 (2005). https://doi.org/10.1007/s00216-005-3237-x
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DOI: https://doi.org/10.1007/s00216-005-3237-x