Abstract
The influence of geochemical processes and quality of groundwater in a rural tract of Damodar Valley region were investigated. The study has distinguished the groundwater as fresh, soft to moderately hard and mainly CaHCO3 type. The paired samples student’s t test shows the significant seasonal variations of pH, HCO3−, and Fe. Amphoteric exchange has lessened HCO3− concentration in post-monsoon which subsequently has caused to drop pH. Quite the reverse, the monsoon precipitation has triggered the additional release of Fe from iron-bearing sediments. The contaminant Cl− is from the domestic wastewater as is evidenced by field observations. The inter-variable relations, cation and anion mechanisms, and mineral saturation indices reveal that the dissolutions of silicate and carbonate minerals are the primary sources of major ions in groundwater. The chloro-alkaline indices showed the role of ion exchange too in water chemistry. The R-mode factor analysis also successfully identified two dominant processes regulating water chemistry—geogenic sources (Ca2+, Mg2+, Na+, and HCO3−) and anthropogenic inputs (mainly Cl−). The groundwater is found unsuitable for drinking at 82 and 93% of wells in pre- and post-monsoon seasons, respectively mainly due to elevated Fe content. The water from more than 90% of wells is appropriate for irrigation uses. The study recommends the proper treatment of contaminated water for consumption and measures to protect the groundwater from the waste water infiltration.
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Ako AA, Shimada J, Hosono T, Ichiyanagi K, Nkeng GE, Fantong WY, Eyong GET, Roger NN (2011) Evaluation of groundwater quality and its suitability for drinking, domestic, and agricultural uses in the Banana Plain (Mbanga, Njombe, Penja) of the Cameroon Volcanic Line. Environ Geochem Health 33:559–575. https://doi.org/10.1007/s10653-010-9371-1
Al-Khashman OA, Jaradat AQ (2014) Assessment of groundwater quality and its suitability for drinking and agricultural uses in arid environment. Stoch Environ Res Risk Assess 28:743–753. https://doi.org/10.1007/s00477-013-0787-x
Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution, 2nd edn. A.A. Balkema, Rotterdam
Batabyal AK (2017) Hydrogeochemical processes and contaminants enrichment with special emphasis on fluoridein Groundwater of Birbhum district, West Bengal, India. Environ Earth Sci 76:285. https://doi.org/10.1007/s12665-017-6584-y
Batabyal AK, Chakraborty S (2015) Hydrogeochemistry and water quality index in the assessment of groundwater quality for drinking uses. Water Environ Res 87(7):607–617
Batabyal AK, Gupta S (2017) Fluoride-contaminated groundwater of Birbhum district, West Bengal, India: interpretation of drinking and irrigation suitability and major geochemical processes using principal component analysis. Environ Monit Assess 189:369. https://doi.org/10.1007/s10661-017-6041-0
BIS (1981) Indian Standard—Methods of sampling and microbiological examination of water. Bureau of Indian Standards, IS 1622:1–25
BIS (1991) Indian Standard—Drinking water specification. Bureau of Indian Standards, IS 10500:1–8
BIS (1992) Indian Standard—Methods of sampling and test (physical and chemical) for water and wastewater. Bureau of Indian Standards, IS 3025(Part 43 Phenols):1–4
Celesceri L, Greenberg AE, Eaten AD (1998) Standard and methods for the examination of water and wastewater. American Public Health Association, Washington, DC
Chung SY, Venkatramanan S, Kim TH, Kim DS, Ramkumar T (2015) Influence of hydrogeochemical processes and assessment of suitability for groundwater uses in Busan City, Korea. Environ Dev Sustain 17:423–441. https://doi.org/10.1007/s10668-014-9552-7
Das S, Biswas AB (1969) Geology and groundwater conditions of the alluvial tract, east of Durgapur, Burdwan District, West Bengal: a preliminary study. Indian Geohydrol 5(1):71–89
Davis JC (2002) Statistics and data analysis in geology, 3rd edn. Wiley, New York, p 638
Devic G, Djordjevic D, Sakan S (2014) Natural and anthropogenic factors affecting the groundwater quality in Serbia. Sci Total Environ 468–469:933–942
Doneen LD (1964) Notes on water quality in agriculture. Published as a water science and engineering paper 4001, Department of Water Sciences and Engineering, University of California, Davis, p 48
Fetter CW (1994) Applied hydrogeology, 3rd edn. Macmillan College Publication, New York
Fijani E, Moghaddam AA, Tsai FT-C, Tayfur G (2016) Analysis and assessment of hydrochemical characteristics of Maragheh-Bonab Plain aquifer, Northwest of Iran. Water Resour Manag. https://doi.org/10.1007/s11269-016-1390-y
Freeze AR, Cherry JA (1979) Groundwater. Prentice-Hall, New Jersey
Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 17:1088–1090
Houatmia F, Azouzi R, Charef A, Be´dir M (2016) Assessment of groundwater quality for irrigation and drinking purposes and identification of hydrogeochemical mechanisms evolution in Northeastern Tunisia. Environ Earth Sci 75:746. https://doi.org/10.1007/s12665-016-5441-8
Huang G, Sun J, Zhang Y, Chen Z, Liu F (2013) Impact of anthropogenic and natural processes on the evolution of groundwater chemistry in a rapidly urbanized coastal area, South China. Sci Total Environ 463–464:209–221. https://doi.org/10.1016/j.scitotenv.2013.05.078
Kim SE, Seo IW, Choi SY (2017) Assessment of water quality variation of a monitoring network using exploratory factor analysis and empirical orthogonal function. Environ Modell Softw 94:21–35
Lapworth DJ, Krishan G, MacDonald AM, Rao MS (2017) Groundwater quality in the alluvial aquifer system of northwest India: new evidence of the extent of anthropogenic and geogenic contamination. Sci Total Environ 599–600:1433–1444. https://doi.org/10.1016/j.scitotenv.2017.04.223
Liu CW, Jang CS, Chen CP, Lin CN, Lou KL (2008) Characterization of groundwater quality in Kinmen Island using multivariate analysis and geochemical modeling. Hydrol Process 22:376–383
Love D, Hallbauer D, Amos A, Hranova R (2004) Factor analysis as a tool in groundwater quality management: two southern African case studies. Phys Chem Earth 29:1135–1143
McArthur JM, Sikdar PK, Hoque MA, Ghosal U (2012) Waste-water impacts on groundwater: Cl/Br ratios and implications for arsenic pollution of groundwater in the Bengal Basin and Red River Basin, Vietnam. Sci Total Environ 437:390–402
Nagarajan R, Rajmohan N, Mahendran U, Senthamilkumar S (2010) Evaluation of groundwater quality and its suitability for drinking and agricultural use in Thanjavur city, Tamil Nadu, India. Environ Monit Assess 171:289–308. https://doi.org/10.1007/s10661-009-1279-9
Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. United States Geological Survey, water-resources investigations report, 99-4259
Piper AM (1944) A graphic procedure in the geochemical interpretation of water analysis. Trans Am Geophys Union 25:914–928
Ramesh K, Elango L (2012) Groundwater quality and its suitability for domestic and agricultural use in Tondiar river basin, Tamil Nadu, India. Environ Monit Assess 184:3887–3899. https://doi.org/10.1007/s10661-011-2231-3
Richard LA (1954) Diagnosis and improvement of saline and alkali Soils. United States Department of Agriculture, Washington DC, Agricultural hand book 60, p 160
Schoeller H (1967) Geochemistry of groundwater. In: An International guide for research and practice (chap 15, pp. 1–18). UNESCO
Todd DK (1980) Groundwater hydrology, 2nd edn. Wiley, New York
United States Salinity Laboratory (1954). Diagnosis and improvement of saline and alkali soils. US Department of Agricultural soils. USDA hand book 60, Washington
Vengosh A, Keren R (1996) Chemical modifications of groundwater contaminated by recharge of treated sewage effluent. J Cont Hydrol 23:347–360
Wayland KG, Long DT, Hyndmann DW, Pijanowski BC, Woodhams SM, Haack SK (2003) Identifying relationships between baseflow geochemistry and land use with synoptic sampling and R-Mode factor analysis. J Environ Qual 32:180–190
WHO (2011) Guidelines for drinking-water quality, 4th edn. World Health Organization, Geneva
Wilcox LV (1955) Classification and use of irrigation waters. United States Department of Agriculture, Circular 969, Washington, DC
Acknowledgements
The author is grateful to the Director, CSIR-Central Mechanical Engineering Research Institute (CSIR-CMERI), Durgapur for giving permission to publish this paper. The author is thankful to CSIR-CMERI for funding the research work in the form of in-house project. The author acknowledges Dr.Surajit Chakraborty, Assistant Professor, IISWBM, Kolkata for the preparation of land use/land cover map of the study area.
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Batabyal, A.K. Hydrogeochemistry and quality of groundwater in a part of Damodar Valley, Eastern India: an integrated geochemical and statistical approach. Stoch Environ Res Risk Assess 32, 2351–2368 (2018). https://doi.org/10.1007/s00477-018-1552-y
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DOI: https://doi.org/10.1007/s00477-018-1552-y