Abstract
Various energy devices with enhanced performance can be fabricated based on nanostructured carbons and conducting polymeric electrolytes. For instance, supercapacitors are attractive energy storage devices due to their high power density. In the present work, supercapacitors are fabricated using synthesized carbon aerogel as an active electrode in combination with different electrolytes. Electrolytes are important components in supercapacitors since their electrochemical properties directly influence the performance and the internal resistance of the capacitor. Aqueous electrolytes of KOH, H2SO4, H3PO4 and six different gel electrolytes PVA/KCL, PVA/H3PO4, PVA/H2SO4, PVA/KOH, and PVA/KOH–KCl–K3[Fe(CN)6] and PVA/KNO3 are used for making flexible supercapacitors. The electrochemical properties of the different electrolytes are compared using cyclic voltammetry, galvanostatic charge/discharge curves and impedance spectroscopy. The capacitor containing PVA–KOH–KCl–K3[Fe(CN)6] electrolyte membrane with a weight ratio of 60:23:23:4 shows the highest specific capacitance of 520 F g−1 and a long cycling life with retention of 98.1% after 1000 cycles, also its specific capacitance increases with increasing the temperature from 25 to 70 °C.
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M.D. Stoller, S. Park, Y. Zhu, J. An, R.S. Rouf, Graphene-based ultracapacitors. Nano Lett 8, 3498–3502 (2008)
H.P. Wu, D.W. He, Y.S. Wang, M. Fu, Z.L. Liu, J.G. Wang, H.T. Wang, Graphene as the electrode material in supercapacitors, 8th international vacuum electron sources conference and nanocarbon, IEEE, pp 465–466 (2010)
G. Xiong, C. Meng, R.G. Reifenberger, P.P. Irazoqui, T.S. Fisher, A review of graphene-based electrochemical microsupercapacitors. Electroanal 26, 30–51 (2014)
Z.S. Iro, C. Subramani, S.S. Dash, A brief review on electrode materials for supercapacitor. Int. J. Electrochem. Sci. 11, 10628–10643 (2016)
P. Simon, Y. Gogotsi, Materials for electrochemical capacitors. Nat. Mater. 7, 845–854 (2008)
R.F. Service, New ‘supercapacitor’ promises to pack more electrical punch. Sci. Mater. Sci. 313, 902 (2006)
A. Hammar, P. Venet, R. Lallemand, G. Coquery, G. Rojat, Study of accelerated aging of supercapacitors for transport applications. IEEE Trans. Ind. Electron. 57, 3972–3979 (2010)
Z. Yu, L. Tetard, L. Zhai, J. Thomas, Supercapacitor electrode materials: nanostructures from 0 to 3 dimensions. Energy Environ. Sci. 8, 702–730 (2015)
R. Ramkumar, M.M. Sundaram, Electrochemical synthesis of polyaniline cross-linked NiMoO4 nanofibre dendrites for energy storage devices. New J. Chem. 40, 7456–7464 (2016)
L. Bao, J. Zang, X. Li, Flexible Zn2SnO4/MnO2 core/shell nanocable-carbon microfiber hybrid composites for high-performance supercapacitor electrodes. Nano Lett. 11, 1215–1220 (2011)
X. Liu, G. Du, J. Zhu, Z. Zeng, X. Zhu, NiO/LaNiO3 film electrode with binder-free for high performance supercapacitor. Appl. Surf. Sci. 384, 92–98 (2016)
D. Hulicova-Jurcakova, M. Kodama, S. Shiraishi, H. Hatori, Z.H. Zhu, G.Q. Lu, Nitrogen-enriched nonporous carbon electrodes with extraordinary supercapacitance. Adv. Funct. Mater. 19, 1800–1809 (2009)
K.-X. Sheng, Y.-X. Xu, C. Li, G.-Q. Shi, High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide. New Carbon. Mater. 26, 9–15 (2011)
R.S. Dey, H.A. Hjuler, Q. Chi, Approaching the theoretical capacitance of graphene through copper foam integrated three-dimensional graphene networks. J. Mater. Chem. A 3, 6324–6329 (2015)
Y. Xu, K. Sheng, C. Li, G. Shi, Self-assembled graphene hydrogel via a one-step hydrothermal process. ACS Nano 4, 4324–4330 (2010)
L. Zhang, G. Shi, Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability. J. Phys. Chem. C 115, 17206–17212 (2011)
J. Chen, K. Sheng, P. Luo, C. Li, G. Shi, Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors. Adv. Mater. 24, 4569–4573 (2012)
X. Zhang, Z. Sui, B. Xu, S. Yue, Y. Luo, W. Zhan, B. Liu, Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources. J. Mater. Chem. 21, 6494–6497 (2011)
Z.S. Wu, A. Winter, L. Chen, Y. Sun, A. Turchanin, X. Feng, K. M¨ullen, Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors. Adv. Mater. 24, 5130–5135 (2012)
B.E. Conway, Electrochemical supercapacitors scientific fundamentals and technological applications (Plenum Press, New York, 1999)
D. Kalpana, N.G. Renganathan, S. Pitchumani, A new class of alkaline polymer gel electrolyte for carbon aerogel supercapacitors. J. Power Sources 157, 621–623 (2006)
X. Liu, T. Momma, T. Osaka, All-solid state electric double layer capacitor using polymer electrolyte and isotropic high density graphite electrodes. Chem. Lett. 25, 625–626 (1996)
C. Huang, J. Zhang, N.P. Young, H.J. Snaith, P.S. Grant, Solid-state supercapacitors with rationally designed heterogeneous electrodes fabricated by large area spray processing for wearable energy storage applications. Sci. Rep. 6, 25684 (1–15) (2016)
M.G. Hosseini, E. Shahryar, Fabrication of novel solid-state supercapacitor using a Nafion polymer membrane with graphene oxide/multiwalled carbon nanotube/polyaniline. J. Solid State Electrochem. 21, 2833–2848 (2017)
M. Genovese, H. Wu, A. Virya, J. Li, P. Shen, K. Lian, Ultrathin all-solid-state supercapacitor devices based on chitosan activated carbon electrodes and polymer electrolytes. Electrochim. Acta 273, 392–401 (2018)
Y.L. Li, P.C. Li, B.J. Li, M.K. Gao, F.Y. Zhao, L. Shao, J.F. Chen, L.H. Li, All-solid-state flexible supercapacitors based on screen-printed graphene electrodes. Int. J. Electrochem. Sci. 12, 10567–10576 (2017)
C. Yanga, L. Zhanga, N. Hua, Z. Yanga, H. Wei, Y. Wang, Y. Zhanga, High-performance flexible all-solid-state supercapacitors based on densely-packed graphene/polypyrrole nanoparticle papers. Appl. Surface Sci. 387, 666–673 (2016)
Z. Li, Z. Zhou, G. Yun, K. Shi, X. Lv, B. Yang, High-performance solid-state supercapacitors based on graphene-ZnO hybrid nanocomposites. Nanoscale Res. Lett. 8:473, 1–9 (2013)
N.A. Choudhury, S. Sampath, A.K. Shukla, Gelatin hydrogel electrolytes and their application to electrochemical supercapacitors. J. Electrochem. Soc. 155, A74–A81 (2008)
M. Rosi, F. Iskandar, M. Abdullah, Khairurrijal, hydrogel-polymer electrolytes based on polyvinyl alcohol and hydroxyethylcellulose for supercapacitor applications. Int. J. Electrochem. Sci. 9, 4251–4256 (2014)
Y.N. Sudhakar, M. Selvakumar, D.K. Bhat, Lithium salts doped biodegradable gel polymer electrolytes for supercapacitor application. J. Mater. Environ. Sci. 6, 1218–1227 (2015)
P. Sivakumar, M. Gunasekaran, M. Sasikumar, A. Jagadeesan, PVDF-HFP based porous polymer electrolyte for lithium battery applications. Inter. J. Sci. Res. 2, 2319–7064 (2013)
P.F.R. Ortega, J.P. C.Trigueiro, G.G. Silva, R.L. Lavall, Improving supercapacitor capacitance by using a novel gel nanocomposite polymer electrolyte based on nanostructured SiO2, PVDF and imidazolium ionic liquid. Electrochim. Acta 188, 809–817 (2016)
L. Nègre, B. Daffos, V. Turq, P.-L. Taberna, P. Simon, Ionogel-based solid-state supercapacitor operating over a wide range of temperature. Electrochim. Acta 206, 490–495 (2016)
X. Lu, M. Yu, G. Wang, T. Zhai, S. Xie, Y. Ling, Y. Tong, Y. Li, H-TiO2@MnO2//H-TiO2 @C Core–Shell nanowires for high performance and flexible asymmetric supercapacitors. Adv. Mater. 25, 267–272 (2013)
Hu Ruofei, J. Zhao, R. Jiang, J. Zheng, Preparation of high strain polyaniline/polyvinyl alcohol composite and its applications in stretchable supercapacitor. J. Mater. Sci. Mater. Electron. 28, 14568–14574 (2017)
T.S. Gaaz, A.B. Sulong, M.N. Akhtar, A.A.H. Kadhum, A.B. Mohamad, A.A. Al-Amiery, Properties and applications of polyvinyl alcohol, halloysite nanotubes and their nanocomposites. Molecules 20, 22833–22847 (2015)
C.Z. Meng, C.H. Liu, L.Z. Chen, C.H. Hu, S.S. Fan, Highly flexible and all-solid-state paperlike polymer supercapacitors. Nano Lett. 10, 4025–4031 (2010)
L.Y. Yuan, X.H. Lu, X. Xiao, T. Zhai, J.J. Dai, F.C. Zhang, B. Hu, X. Wang, L. Gong, J. Chen, C.G. Hu, Y.X. Tong, J. Zhou, Z.L. Wang, Flexible solid-state supercapacitors based on carbon nanoparticles/MnO2 nanorods hybrid structure. ACS Nano 6, 656–661 (2012)
B.G. Choi, J. Hong, W.H. Hong, P.T. Hammond, H. Park, Facilitated ion transport in all-solid-state flexible supercapacitors. ACS Nano 5, 7205–7213 (2011)
F.H. Meng, Y. Ding, Sub-micrometer-thick all-solid-state supercapacitors with high power and energy densities. Adv. Mater. 23, 4098–4102 (2011)
A. Lewandowski, M. Zajder, E. Frackowiak, F. Beguin, Supercapacitor based on activated carbon and polyethylene oxide–KOH–H2O polymer electrolyte. Electrochim. Acta 46, 2777–2780 (2001)
H.-S. Nam, N.-L. Wu, K.-T. Lee, K.M. Kim, C.G. Yeom, L.R. Hepowit, J.M. Ko, J.-D. Kim, Electrochemical capacitances of a nanowire-structured MnO2 in polyacrylate-based gel electrolytes. J. Electrochem. Soc. 159, A899–A903 (2012)
K.-T. Lee, N.-L. Wu, Manganese oxide electrochemical capacitor with potassium poly(acrylate) hydrogel electrolyte. J. Power Sources 179, 430–434 (2008)
K. ZinHtut, M. Kim, E. Lee, G. Lee, S.H. Baeck, S.E. Shim, Biodegradable polymer-modified graphene/ polyaniline electrodes for supercapacitors. Synth. Metals 227, 61–67 (2017)
G. Ma, J. Li, K. Sun, H. Peng, J. Mu, Z. Lei, High performance solid-state supercapacitor with PVA–KOH–K3[Fe(CN)6] gel polymer as electrolyte and separator. J. Power Sources 256, 281–287 (2014)
C. Ramasamy, J. Palma del vel, M. Anderson, An activated carbon supercapacitor analysis by using a gel electrolyte of sodium salt-polyethylene oxide in an organic mixture solvent. J. Solid State Electrochem. 18, 2217–2223 (2014)
H. Gao, F. Xiao, C.B. Ching, H. Duan, Flexible all-solid-state asymmetric supercapacitors based on free-standing carbon nanotube/graphene and Mn3O4 nanoparticle/graphene paper electrodes. ACS Appl. Mater. Interfaces 4, 7020–7026 (2012)
A. Hany, M.A. Mousa, T. El-Essawy, Studies on AC electrical conductivity, dielectric properties and ion transport in PVA polymeric electrolytes. J. Basic Environ. Sci. 4, 298–304 (2017)
L. Lei, Z. Fu, Y. Yi, X. Huang, H. Tu, Ch Wang, Preparation and characterization of RF aerogel on UV irradiation method. J. Sol Gel. Sci. Technol. 72, 553–558 (2014)
B.E. Conway, Electrochemical supercapacitors: scientific fundamentals and technological applications (Kluwer Academic/Plenum Publishers, New York, 1999)
L. Huang, D. Chen, Y. Ding, S. Feng, Z.L. Wang, M. Liu, Nickel–cobalt hydroxide nanosheets coated on NiCo2O4 nanowires grown on carbon fiber paper for high-performance pseudocapacitors. Nano Lett. 13, 3135–3139 (2013)
L.Q. Mai, A. Minhas-Khan, X. Tian, K.M. Hercule, Y.L. Zhao, X. Lin, X. Xu, Synergistic interaction between redox-active electrolyte and binder-free functionalized carbon for ultrahigh supercapacitor performance. Nat. Commun. 4, 2923 (2013)
R. Vellacheri, A. Al-Haddad, H. Zhao, W. Wang, C. Wang, Y. Lein, High performance supercapacitor for efficient energy storage under extreme environmental temperatures. Nano Energy 8, 231–237 (2014)
R. Vellacheri, A. Al-Haddad, H. Zhao, W. Wang, C. Wang, Y. Lei, High performance supercapacitor for efficient energy storage under extreme environmental temperatures. Nano Energy 8, 231–237 (2014)
B.E. Conway, W.G. Pell, Double-layer and pseudocapacitance types of electrochemical capacitors and their applications to the development of hybrid devices. J. Solid State Electrochem. 7, 637–644 (2003)
M.L. Verma, M. Minakshi, N.K. Singh, Structural and electrochemical properties of nanocomposite polymer electrolyte for electrochemical devices. Ind. Eng. Chem. Res. 53, 14993–15001 (2014)
A.A. Łatoszyńska, G.Z. Źukowska, I.A. Rutkowska, P.-L. Taberna, P. Simon, P.J. Kulesza, W. Wieczorek, Non-aqueous gel polymer electrolyte with phosphoric acid ester and its application for quasi solid-state supercapacitors. J. Power Sources 274, 1147–1154 (2015)
J.B. Wagner, C. Wagner, Electrical conductivity measurements on cuprous halides. J. Chem. Phys. 26, 1597–1601 (1957)
S. Bindu, M.S. Suresh, Measurement of bulk resistance of conducting polymer films in presence of rectifying contacts. Inter. J. Sci. Res. 4(8), 1–6 (2014). ISSN 2250-3153
L. Lai, H. Yang, L. Wang, B.K. Teh, J. Zhong, H. Chou, L. Chen, W. Chen, Z. Shen, R.S. Ruoff, J. Lin, Preparation of supercapacitor electrodes through selection of graphene surface functionalities. ACS Nano 6, 5941–5951 (2012)
F. Yu, T. Wang, Z. Wen, H. Wang, High performance all-solid-state symmetric supercapacitor based on porous carbon made from a metal-organic framework compound. J. Power Source 364, 9–15 (2017)
X. Sun, X. Zhang, H. Zhang, D. Zhang, Y. Ma, A comparative study of activated carbon-based symmetric supercapacitors in Li2SO4 and KOH aqueous electrolytes. J. Solid State Electrochem. 16, 2597–2603 (2012)
K. Wang, M. Xu, Y. Gu, Z. Gu, Q.H. Fan, Symmetric supercapacitors using urea-modified lignin derived N-doped porous carbon as electrode materials in liquid and solid electrolytes. J. Power Source 332, 180–186 (2016)
H.T. Jeong, Y.R. Kim, B.C. Kim, Flexible polycaprolactone (PCL) supercapacitor based on reduced graphene oxide (rGO)/single-wall carbon nanotubes (SWNTs) composite electrodes. J. Alloy Compds. 727, 721–727 (2017)
P. Staiti, F. Lufrano, Nafion® and Fumapem® polymer electrolytes for the development of advanced solid-state supercapacitors. Electrochim. Acta 206, 432–439 (2016)
X. Yang, L. Zhang, F. Zhang, T. Zhang, Y. Huang, Y. Chen, A high-performance all-solid-state supercapacitor with graphene-doped carbon material electrodes and a graphene oxide-doped ion gel electrolyte. Carbon 72, 381–386 (2014)
D. Wang, L. Yu, B. He, L. Wang, A high-performance carbon–carbon(C/C) quasi-solid-state supercapacitor with conducting gel electrolyte. Int. J. Electrochem. Sci. 13, 2530–2543 (2018)
B.S. Lalia, M. Alkaabi, R. Hashaikeh, Sulfated cellulose/polyvinyl alcohol composites as proton conducting electrolyte for capacitors. Energy Proc. 75, 1869–1874 (2015)
P. Staitiz, F. Lufrano, Design, fabrication, and evaluation of a 1.5 F and 5 V prototype of solid-state electrochemical supercapacitor. J. Electrochem. Soc. 152, A617–A621 (2005)
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Esawy, T., Khairy, M., Hany, A. et al. Flexible solid-state supercapacitors based on carbon aerogel and some electrolyte polymer gels. Appl. Phys. A 124, 566 (2018). https://doi.org/10.1007/s00339-018-1967-9
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DOI: https://doi.org/10.1007/s00339-018-1967-9