Abstract
Fabrication of waterproof decorative paintings has attracted a great deal of interest. In this work, in situ reaction using poly(glycidyl methacrylate) (PGMA) and polyhedral oligomeric silsesquioxane with amino group at end (amino-POSS) was utilized to fabricate coatings at surfaces of papery/cloth decorative paintings via spray, which endowed the decorative paintings with excellent hydrophobicity, transparency, and weather ability. Firstly, ring opening of epoxy groups in PGMA, cross-linking structure in coatings, and strong coating/painting interface adhesion were achieved. Then, surface morphology of coatings was observed, and high surface roughness was confirmed. Next, high transparency and thermal stability of coatings were confirmed. Finally, surface water-contact-angles (WCAs) of coatings with various substrates were tested as a function of POSS content. Weathering resistances of coating surface on cloth substrate were studied. Coatings exhibit excellent properties such as high light transmittance (over 80%), high glass-transition temperature (upper limit ~ 113 ℃), high hydrophobicity (maximum WCA ~ 149°), and strong weathering resistances (the aged WCAs over 140°). Work innovation lies in simultaneously gained high hydrophobicity, good transparency, and strong weather ability. This work might pave a road for fabricating excellent coatings for protecting decorative paintings.
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References
Katsibiri O, Howe RF (2010) Microscopic, mass spectrometric and spectroscopic characterisation of the mordants used for gilding on wall paintings from three post-Byzantine monasteries in Thessalia, Greece. Microchem J 94(1):83–89
Song M (2009) The history and characteristics of traditional Korean books and bookbinding. J Inst Conserv 32(1):53–78
Ahmed HE, Ziddan YE (2011) A new approach for conservation treatment of a silk textile in Islamic Art Museum, Cairo. J Cult Herit 12(4):412–419
Maravelaki, PN, (2022) Surface cleaning: implications from choices & future perspectives. Conserving Stone Heritage, pp 37–74
Liu J, Jiao X, Cheng F, Fan Y, Wu Y, Yang X (2020) Fabrication and performance of UV cured transparent silicone modified polyurethane–acrylate coatings with high hardness, good thermal stability and adhesion. Prog Org Coat 144:105673
Ouyang Y, Kang H, Guo E, Qiu R, Su K, Chen Z, Wang T (2022) Thermo-driven oleogel-based self-healing slippery surface behaving superior corrosion inhibition to Mg-Li alloy. J Magnesium and Alloys. https://doi.org/10.1016/j.jma.2022.07.006
Zhang H, Lai H, Cheng Z, Zhang D, Liu P, Li Y, Liu Y (2020) In-situ switchable superhydrophobic shape memory microstructure patterns with reversible wettability and adhesion. Appl Surf Sci 525:146525
Mei S, Yang L, Pan Y, Wang D, Wang X, Tang T, Wei J (2019) Influences of tantalum pentoxide and surface coarsening on surface roughness, hydrophilicity, surface energy, protein adsorption and cell responses to PEEK based biocomposite. Colloids Surf, B 174:207–215
Alexander S, Eastoe J, Lord AM, Guittard F, Barron AR (2016) Branched hydrocarbon low surface energy materials for superhydrophobic nanoparticle derived surfaces. ACS Appl Mater Interfaces 8(1):660–666
Ji S, Gui H, Guan G, Zhou M, Guo Q, Tan MYJ (2021) A multi-functional coating based on acrylic copolymer modified with PDMS through copolymerization. Prog Org Coat 156:106254
Ji H, Yang H, Wan Y, Li L, Wang J, Zhang X, Yu J, Zhou X, Wang R, Zhang L (2022) Green routes toward cross-linkable and robust elastomers derived from biobased fumaric acid. ACS Sustainable Chem Eng 10(21):7065–7077
Nowrouzi Z, Mohebby B, Ebrahimi M, Petrič M (2021) Weathering performance of thermally modified wood coated with polyacrylate containing olive leaf extract as a bio-based additive. Eur J Wood Wood Prod 79(6):1551–1562
Fortunato G, Tatsi E, Rigatelli B, Turri S, Griffini G (2020) Highly transparent and colorless self-healing polyacrylate coatings based on diels-alder chemistry. Macromol Mater Eng 305(2):1900652
Zhang KQ, Cai JZ, Li XH, Li H, Zhao YH, Yuan XY (2015) Balance of polyacrylate-fluorosilicone block copolymers as icephobic coatings. Chin J Polym Sci 33(1):153–162
Chen GQ, Li NN, Fu XS, Zhou WL (2012) Preparation and characterization of a sodium polyacrylate/sodium silicate binder used in oxidation resistant coating for titanium alloy at high temperature. Powder Technol 230:134–138
Park M, Jeong Y, Kim HS, Lee W, Nam SH, Lee S, Yoon H, Kim J, Yoo S, Jeon S (2021) Quenching-resistant solid-state photoluminescence of graphene quantum dots: reduction of π−π stacking by surface functionalization with POSS, PEG, and HDA. Adv Func Mater 31(29):2102741
Kuo SW, Chang FC (2011) POSS related polymer nanocomposites. Prog Polym Sci 36(12):1649–1696
Li Y, Zhong J, Wu L, Weng Z, Zheng L, Peng S, Zhang X (2019) High performance POSS filled nanocomposites prepared via UV-curing based on 3D stereolithography printing. Compos A Appl Sci Manuf 117:276–286
Gao Y, Zhou D, Lyu J, Xu Q, Newland B, Matyjaszewski K, Wang W (2020) Complex polymer architectures through free-radical polymerization of multivinyl monomers. Nat Rev Chem 4(4):194–212
Xu Y, Sun W, Xiong X, Peng Z, Chen Y, Hao Z (2018) Microstructure and properties of ZrC-SiC multi-phase coatings prepared by thermal evaporation deposition and an in-situ reaction method. Surf Coat Technol 349:797–806
Barbey R, Klok HA (2010) Room temperature, aqueous post-polymerization modification of glycidyl methacrylate-containing polymer brushes prepared via surface-initiated atom transfer radical polymerization. Langmuir 26(23):18219–18230
Guo J, Wang C, Yu H, Li X (2020) Preparation of a wear-resistant, superhydrophobic SiO2/silicone-modified polyurethane composite coating through a two-step spraying method. Prog Org Coat 146:105710
Wu R, Li Y, Shi J, Wang Q (2021) Functionalization of cellulose via ATRP and “click” chemistry to construct hydrophobic filter paper for oil/water separation. Cellulose 28(14):9413–9424
Yuan MR, Lu JT, Kong G, Che CS (2011) Effect of silicate anion distribution in sodium silicate solution on silicate conversion coatings of hot-dip galvanized steels. Surf Coat Technol 205(19):4466–4470
Li J, Wang Q, Gao N, Nwokolo IK, Zhang W, Ma L, Liu F, Han EH (2021) Interface characteristics and anticorrosion performances of cold galvanizing coatings incorporated with γ-chloropropyl triethoxysilane on hot-dip galvanized steel. Coatings 11(4):402
Zhou H, Ye Q, Xu J (2017) Polyhedral oligomeric silsesquioxane-based hybrid materials and their applications. Mater Chem Front 1(2):212–230
Duan S, Dou B, Lin X, Zhao S, Emori W, Pan J, Hu H, Xiao H (2021) Influence of active nanofiller ZIF-8 metal-organic framework (MOF) by microemulsion method on anticorrosion of epoxy coatings. Colloids Surf, A 624:126836
Li Z, Chen C, Gröger S, Kressler J (2012) Detection of chirality of poly(glycerol methacrylate)s after derivatization by 1H NMR spectroscopy. Polymer 53(13):2613–2618
Liu H, Chung H (2017) Lignin-based polymers via graft copolymerization. J Polym Sci, Part A: Polym Chem 55(21):3515–3528
Li Y, Huang X, Zeng L, Li R, Tian H, Fu X, Wang Y, Zhong WH (2019) A review of the electrical and mechanical properties of carbon nanofiller-reinforced polymer composites. J Mater Sci 54(2):1036–1076
Dao TP, Vezenkov L, Subra G, Ladmiral V, Semsarilar M (2021) Nano-assemblies with core-forming hydrophobic polypeptide via polymerization-induced self-assembly (PISA). Polym Chem 12(1):113–121
Wu B, Zhang Y, Yang D, Yang Y, Yu Q, Che L, Liu J (2019) Self-Healing anti-atomic-oxygen phosphorus-containing polyimide film via molecular level incorporation of nanocage trisilanolphenyl POSS: preparation and characterization. Polymers 11(6):1013
Delahaye M, Winne JM, Duprez FE (2019) Internal catalysis in covalent adaptable networks: phthalate monoester transesterification as a versatile dynamic cross-linking chemistry. J Am Chem Soc 141(38):15277–15287
Ma X, He L, Huang S, Wu Y, Pan A, Liang J (2020) Effect of different molecular architectured POSS-fluoropolymers on their self-assembled hydrophobic coatings. Colloid Polym Sci 298(11):1559–1569
Banerjee I, Pangule RC, Kane RS (2011) Antifouling coatings: recent developments in the design of surfaces that prevent fouling by proteins, bacteria, and marine organisms. Adv Mater 23(6):690–718
Shin EJ, Jeong W, Brown HA, Koo BJ, Hedrick JL, Waymouth RM (2011) Crystallization of cyclic polymers: synthesis and crystallization behavior of high molecular weight cyclic poly(ε-caprolactone)s. Macromolecules 44(8):2773–2779
Kuzina EA, Emelyanenko KA, Domantovskii AG, Emelyanenko AM, Boinovich LB (2022) Preparation of stable superhydrophobic coatings on a paint surface with the use of laser treatment followed by hydrophobizer deposition. Colloid J 84(4):445–455
Asandei A, Saha G (2007) Poly(glycidyl methacrylate) graft copolymers with styrene and methacrylates by Cp2TiCl-catalyzed epoxide radical ring opening. Polymer Mater Sci Eng 96:435–436
Sun J, Ding D, Liu W, Wu G, Liu H, Wei G, Liu H (2022) Strength and elastic modulus enhancement in Mg-Li-Al matrix composites reinforced by ex situ TiB2 particles via stir casting. J Magnes Alloys. https://doi.org/10.1016/j.jma.2022.09.020
Lee H, Yu MK, Park S, Moon S, Min JJ, Jeong YY, Kang HW, Jon S (2007) Thermally cross-linked superparamagnetic iron oxide nanoparticles: synthesis and application as a dual imaging probe for cancer in vivo. J Am Chem Soc 129(42):12739–12745
Singh AK, Singh JK (2017) Fabrication of durable super-repellent surfaces on cotton fabric with liquids of varying surface tension: Low surface energy and high roughness. Appl Surf Sci 416:639–648
Zhang W, Wang D, Sun Z, Song J, Deng X (2021) Robust superhydrophobicity: mechanisms and strategies. Chem Soc Rev 50(6):4031–4061
Vazirinasab E, Jafari R, Momen G (2018) Application of superhydrophobic coatings as a corrosion barrier: a review. Surf Coat Technol 341:40–56
Zhang X, He Y, Huang P, Jiang G, Zhang M, Yu F, Zhang W, Fu G, Wang Y, Li W (2020) A novel mineralized high strength hydrogel for enhancing cell adhesion and promoting skull bone regeneration in situ. Compos B Eng 197:108183
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This work was supported by the 2022 Industry-University Cooperation and Collaborative Education Project of the Ministry of Education of China [grant number 220901444214456].
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Xiong, A., Li, J. Constructing stable transparent hydrophobic POSS@epoxy-group coatings for waterproofing protection of decorative-painting surfaces. Polym. Bull. 81, 1403–1419 (2024). https://doi.org/10.1007/s00289-023-04780-y
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DOI: https://doi.org/10.1007/s00289-023-04780-y