Abstract
For the disposal of high-level radioactive waste (HLW), the deep geological disposal is recognized as an effective method. The distribution coefficient (Kd) of radionuclides on buffer/backfill materials or host rock is one of the key parameters used in the safety assessment of geological repository. 137Cs is one of the high-yield (t1/2 = 30.1 y, 6%) fission products in spent fuels, its high solubility makes it likely to migrate through groundwater to the biosphere. Multibarrier system prevents leakage of radionuclides to the environment. The present review discusses the general mechanisms of cesium adsorption by minerals, elaborates the parameters which influence adsorption of cesium contain concentration of cesium, pH, humic acid, competitive cations and properties of minerals. Furthermore, we have collected the Kd values from cesium adsorption studies concerned with the minerals conducted during the past two decades, and analyzed by the probabilistic modelling to obtain the best-estimated Kd values of Cs adsorption on bentonite, granite and clay under different solution conditions.
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References
De Pourcq, K., et al.: A clay permeable reactive barrier to remove Cs-137 from groundwater: column experiments. J. Environ. Radioact. 149, 36–42 (2015)
Dzene, L., et al.: Nature of the sites involved in the process of cesium desorption from vermiculite. J. Colloid Interface Sci. 455, 254–260 (2015)
Barescut, J.C., et al.: Developing methodology for description of biosphere development at Olkiluoto disposal site utilising forest studies at other land uplift sites. Radioprotection 40(Suppl 1), S927–S932 (2005)
Hell, P. et al.: Safety case for the disposal of spent nuclear fuel at Olkiluoto—definition of reference and bounding groundwaters, buffer and backfill porewaters (2014)
Holgersson, et al.: Behavior of Cs in grimsel granodiorite: sorption on main minerals and crushed rock. Radiochimica Acta International Journal for Chemical Aspects of Nuclear Science & Technology (2016)
Sagar, B.: Review of safety assessment in Posiva's construction license application for a repository at Olkiluoto (2015)
Säteilyturvakeskus: STUK’s review on the construction license stage post closure safety case of the spent nuclear fuel disposal in Olkiluoto (2015)
Idemitsu, K., Akiyama, D., Matsuki, Y., Irie, Y., Inagaki, Y., Arima, T.: Migration behaviour of lanthanides in compacted bentonite with iron corrosion product using electrochemical method. MRS Online Proc. Libr. 1475(1), 611–616 (2012). https://doi.org/10.1557/opl.2012.641
Lee, J.O., Cho, W.J., Choi, H.: Sorption of cesium and iodide ions onto KENTEX-bentonite. Environ. Earth Sci. 70(5), 2387–2395 (2013). https://doi.org/10.1007/s12665-013-2530-9
Kuleshova, M.L., Danchenko, N.N., Sergeev, V.I., Shimko, T.G., Malashenko, Z.P.: The properties of bentonites as a material for sorptive barriers. Mosc. Univ. Geol. Bull. 69(5), 356–364 (2014). https://doi.org/10.3103/S0145875214050044
Tachi, Y. et al.: Integrated sorption and diffusion model for bentonite. Part 1: clay–water interaction and sorption modeling in dispersed systems. J. Nucl. Sci. Technol. 51(10), 1177–1190 (2014)
Wu, T., et al.: Effect of organic matter on 125I diffusion in bentonite. J. Radioanal. Nucl. Chem. 303(1), 255–260 (2014)
Wu, T., et al.: Diffusion behavior of Se(IV) and Re(VII) in GMZ bentonite. Appl. Clay Sci. 101, 136–140 (2014)
Sawaguchi, T., et al.: Diffusion of Cs, Np, Am and Co in compacted sand-bentonite mixtures: evidence for surface diffusion of Cs cations. Clay Miner. 48(2), 411–422 (2018)
Bouzidi, A., et al.: Sorption behavior of cesium on Ain Oussera soil under different physicochemical conditions. J. Hazard. Mater. 184(1–3), 640–646 (2010)
Ass, A. et al.: Cs+ sorption onto Kutch clays: Influence of competing ions. Appl. Clay Sci. 166, 88–93 (2018)
Missana, T., et al.: Kinetics and irreversibility of cesium and uranium sorption onto bentonite colloids in a deep granitic environment. Appl. Clay Sci. 26(1/4), 137–150 (2004)
Savoye, S., et al.: Mobility of cesium through the callovo-oxfordian claystones under partially saturated conditions. Environ. Sci. Technol. 46(5), 2633–2641 (2012)
Iijima, K., et al.: Reversibility and modeling of adsorption behavior of cesium ions on colloidal montmorillonite particles. Appl. Clay Sci. 49(3), 262–268 (2010)
Sasaki, T., et al.: Analysis of sorption behavior of cesium ion on mineral components of granite. J. Nucl. Sci. Technol. 44(4), 641–648 (2007)
Tsai, S.C., et al.: Cesium adsorption and distribution onto crushed granite under different physicochemical conditions. J. Hazard. Mater. 161(2–3), 854–861 (2009)
Lee, C.-P., Tsai, S.-C., Wu, M.-C., Tsai, T.-L., Tu, Y.-L., Kang, L.-J.: A comparative study on sorption and diffusion of Cs in crushed argillite and granite investigated in batch and through-diffusion experiment. J. Radioanal. Nucl. Chem. 311(2), 1155–1162 (2016). https://doi.org/10.1007/s10967-016-5010-3
Wang, T.H., et al.: Effects of pH and concentration on Cs ions sorption and diffusion in crushed granite by using batch and modified capillary method. J. Chin. Chem. Soc. 56(4), 748–754 (2009)
Jan, Y.-L., et al.: Evaluating adsorption ability of granite to radioselenium by chemical sequential extraction. J. Radioanal. Nucl. Chem. 273(2), 299–306 (2007)
Tsai, S.-C., et al.: Kinetics of Cs adsorption/desorption on granite by a pseudo first order reaction model. J. Radioanal. Nucl. Chem. 275(3), 555–562 (2007)
Zang, J., et al.: Sorption and desorption of Sr onto a rough single fractured granite. J Contam Hydrol 228, 103558 (2020)
Lee, C.P., et al.: Sorption and diffusion of HTO and cesium in crushed granite compacted to different lengths. J. Radioanal. Nucl. Chem. 275(2), 371–378 (2008)
Shapiro, Allen, M.: Effective matrix diffusion in kilometer-scale transport in fractured crystalline rock. Water Resour. Res. 37(3), 507–522 (2001)
Dai, Z. et al.: Upscaling matrix diffusion coefficients for heterogeneous fractured rocks. Geophys. Res. Lett. 34(7) (2007)
Palágyi, Š, et al.: Migration and sorption of 137Cs and 152,154Eu in crushed crystalline rocks under dynamic conditions. J. Radioanal. Nucl. Chem. 279(2), 431–441 (2009)
Giannatou, S. et al.: Potassium solution concentration effect on Cs sorption in an acid soil (2012)
Kikuchi, R. et al.: Cs–sorption in weathered biotite from Fukushima granitic soil. J. Mineral. Petrol. Sci. 110(3), 126–134 (2015)
Pitkänen, P. et al.: Results of monitoring at Olkiluoto in 2007. Hydrogeochemistry (2008)
B., et al.: The sorption behavior of Cs+ ion on clay minerals and zeolite in radioactive waste management: sorption kinetics and thermodynamics. J Radioanal. Nucl. Chem. (2011)
Koarashi, J., et al.: Factors affecting vertical distribution of Fukushima accident-derived radiocesium in soil under different land-use conditions. Sci. Total Environ. 431, 392–401 (2012)
Oughton, D.H., et al.: Mobilisation of 137Cs and 90Sr from sediments: Potential sources to arctic waters. Sci. Total Environ. 202(1–3), 155–165 (1997)
Hakem, N.L., et al.: Sorption of cesium and strontium on hanford soil. J. Radioanal. Nucl. Chem. 246(2), 275–278 (2000)
Fan, Q.H., et al.: An EXAFS study on the effects of natural organic matter and the expandability of clay minerals on cesium adsorption and mobility. Geochim. Cosmochim. Acta 135, 49–65 (2014)
Bradbury, M.H., Baeyens, B.: A generalised sorption model for the concentration dependent uptake of caesium by argillaceous rocks. J. Contam. Hydrol. 42(2/4), 141–163 (2000)
Bostick, B., et al.: Cesium adsorption on clay minerals: an EXAFS spectroscopic investigation. Environ. Sci. Technol. 36(12), 2670 (2002)
Kruyts, N., Delvaux, B.: Soil organic horizons as a major source for radiocesium biorecycling in forest ecosystems. J. Environ. Radioact. 58(2–3), 175–190 (2002)
Mckinley, J.P., et al.: Microscale distribution of cesium sorbed to biotite and muscovite. Environ. Sci. Technol. 38(4), 1017–1023 (2004)
Loon, L., et al.: The sorption behaviour of caesium on opalinus clay: a comparison between intact and crushed material. Appl. Geochem. 24(5), 999–1004 (2009)
Bergaoui, L., et al.: Cesium adsorption on soil clay: macroscopic and spectroscopic measurements. Appl. Clay Sci. 29(1), 23–29 (2005)
Missana, T., et al.: Modelling of Cs sorption in natural mixed-clays and the effects of ion competition. Appl. Geochem. 49, 95–102 (2014)
Km, A. et al.: Desorption mechanisms of cesium from illite and vermiculite—Sciencedirect. Appl. Geochem. 123 (2020)
Christophe, et al.: Experimental and modelling studies of caesium sorption on illite. Geochimica et Cosmochimica Acta (1999)
Vejsada, J., et al.: Adsorption of cesium on Czech smectite-rich clays—a comparative study. Appl. Clay Sci. 30(1), 53–66 (2005)
Wang, W., et al.: Transport behaviors of Cs(+) in granite porous media: effects of mineral composition, HA, and coexisting cations. Chemosphere 268, 129341 (2021)
Yin, X. et al.: Effects of NH4+, K+, and Mg2+ and Ca2+ on the cesium adsorption/desorption in binding sites of vermiculitized biotite. Environ. Sci. Technol. 51(23) (2017)
Brouwer, E., et al.: Cesium and rubidium ion equilibriums in illite clay. J. Phys. Chem. 87(7), 1213–1219 (1983)
Cornell, R.M.: Adsorption of cesium on minerals: a review. J. Radioanal. Nucl. Chem. 171(2), 483–500 (1993)
Steefel, C.I., et al.: Cesium migration in Hanford sediment: a multisite cation exchange model based on laboratory transport experiments. J. Contam. Hydrol. 67(1–4), 219–246 (2003)
Smith, Z: A cation exchange model to describe Cs+ sorption at high ionic strength in subsurface sediments at Hanford site, USA. J. Contam. Hydrol. (2004)
Wissocq, A., et al.: Ca and Sr sorption on Ca-illite: experimental study and modelling. Procedia Earth & Planetary ence 17, 662–665 (2017)
Durrant, C.B., et al.: Cesium sorption reversibility and kinetics on illite, montmorillonite, and kaolinite. Sci. Total Environ. 610–611, 511–520 (2017)
Khan, S.A.: Sorption of the long-lived radionuclides cesium-134, strontium-85 and cobalt-60 on bentonite. J. Radioanal. Nucl. Chem. 258(1), 3–6 (2003)
Tameta, Y., et al.: Effect of dissolved soil organic matter on cesium adsorption by zeolite and illite. J. Environ. Manage. 289, 112477 (2021)
Chang, K.-P., et al.: Basic study of137Cs sorption on soil. J. Nucl. Sci. Technol. 30(12), 1243–1247 (1993)
Chiba, Y. et al.: Effect of soil organic matter on the enhancement of caesium fixation by soil mixed with minerals. Radioisotopes (2019)
Galamboš, M., et al.: Adsorption of cesium on domestic bentonites. J. Radioanal. Nucl. Chem. 281(3), 485–492 (2009)
Liu, C., et al.: Desorption kinetics of radiocesium from subsurface sediments at Hanford Site, USA. Geochim. Cosmochim. Acta 67(16), 2893–2912 (2003)
Zachara, J.M. et al.: Sorption of Cs+ to micaceous subsurface sediments from the Hanford site, USA. Geochim. Cosmochim. Acta (2002)
Staunton, S.: Adsorption of 137Cs on montmorillonite and illite: effect of charge compensating cation, ionic strength, concentration of Cs, K and Fulvic acid. Clays Clay Miner. 45(2), 251–260 (1997)
Söderlund, et al.: Sorption of cesium on boreal forest soil I: the effect of grain size, organic matter and mineralogy. J. Radioanal. Nucl. Chem. (2016)
Ana, et al.: Inter layer collapse affects on cesium adsorption onto mate. Environ. Sci. Technol. (2014)
Sawhney, B.L.: Selective sorption and fixation of cations by clay minerals: a review. Clays Clay Miner. 20(2), 93–100 (1972). https://doi.org/10.1346/CCMN.1972.0200208
Latrille, C., Bildstein, O.: Cs selectivity and adsorption reversibility on Ca-illite and Ca-vermiculite. Chemosphere 288, 132582- (2022)
Tiziana, et al.: Modeling cesium retention onto Na-, K- and Ca-smectite: effects of ionic strength, exchange and competing cations on the determination of selectivity coefficients. Geochim. Cosmochim. Acta 128(1), 266–277 (2014)
Li, S.H. et al.: Experimental study on adsorption of Cs+ and Yb3+ on calcite, kaolinite, montmorillonite, chlorite and glauconite J. Nucl. Radiochem. 70–76 (2002)
Sunkyung, et al.: Clay mineral weathering and contaminant dynamics in a caustic aqueous system: II. mineral transformation and microscale partitioning. Geochim. Cosmochim. Acta (2005)
Qin, H. et al.: Investigation of cesium adsorption on soil and sediment samples from Fukushima Prefecture by sequential extraction and EXAFS technique. Geochem. Soc. Japan (4) (2012)
Kogure, T. et al.: XRD and HRTEM evidence for fixation of cesium ions in vermiculite clay. Chem. Lett. 41(4), 380–382 (2012)
Motokawa, R., et al.: Mesoscopic structures of vermiculite and weathered biotite clays in suspension with and without cesium ions. Langmuir the Acs J. Surf. Colloids 30(50), 15127–15134 (2014)
Volkov, I.N., et al.: Sorption of 90Sr and 137Cs on clays used to build safety barriers in radioactive waste storage facilities. Nucl. Eng. Technol. 7(2), 151–156 (2021)
Degryse, F., et al.: Partitioning of metals (Cd Co, Cu, Ni, Pb, Zn) in soils: concepts, methodologies, prediction and applications—a review. Eur. J. Soil Sci. 60(4), 590–612 (2009)
Ramirez-Guinart, O. et al.: Deriving probabilistic soil distribution coefficients (Kd). Part 1: General approach to decreasing and describing variability and example using uranium Kd values. J. Environ. Radioact. 222, 106362 (2020)
Puukko, E., et al.: Electromigration experiments for studying transport parameters and sorption of cesium and strontium on intact crystalline rock. J. Contam. Hydrol. 217, 1–7 (2018)
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Wu, Y., Fang, S., Zhang, J., Mo, X., Liu, L. (2023). A Review on Adsorption Mechanisms and Distribution Coefficient (Kd) of Cesium in Clay/Host Rock. In: Liu, C. (eds) Proceedings of the 23rd Pacific Basin Nuclear Conference, Volume 2. Springer Proceedings in Physics, vol 284. Springer, Singapore. https://doi.org/10.1007/978-981-19-8780-9_86
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