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Sample Controlled Thermal Analysis (SCTA) as a Promising Tool for Kinetic Characterization of Solid-State Reaction and Controlled Material Synthesis

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Thermal Physics and Thermal Analysis

Part of the book series: Hot Topics in Thermal Analysis and Calorimetry ((HTTC,volume 11))

Abstract

The historical development of the thermal analysis methods that imply an intelligent control of the reaction temperature by the own sample (SCTA) is outlined. It has been shown that the precise control of the reaction rate involved in SCTA enables a control, either direct or indirect, of both the partial pressure of the gases generated/consumed by the reaction and the heat evolution/adsorption rate associated to the reaction. This control allows to minimize the influences of heat and mass transfer phenomena and to obtain real kinetic parameters of the forward reaction that occur under the conditions far from the equilibrium. Moreover, it is shown that the shape of α–T plots obtained under constant rate of transformation (CRTA) is strongly dependent on the kinetic model, while the α–T plots obtained using the conventional linear nonisothermal method represent a sigmoidal shape irrespective of the kinetic model. Thus, CRTA has a considerably higher resolution power for discriminating the kinetic model obeyed by the reaction. The applications of SCTA methods both for the kinetic analysis of solid-state reactions and for the synthesis of materials with controlled texture and/or structure have been reviewed. The chapter contains 202 references.

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  1. Instituto de Ciencias de Materiales de Sevilla, Centro Mixto Universidad de Sevilla—C.S.I.C, c/Américo Vespucio 49, 41092, Seville, Spain

    Jose M. Criado & Luis A. Pérez-Maqueda

  2. Chemistry Laboratory, Department of Science Education, Graduate School of Education, Hiroshima University, Higashi-Hiroshima, 739-8524, Japan

    Nobuyoshi Koga

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  1. Jose M. Criado
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    Jaroslav Šesták

  2. Division of Solid-State Physics, Czech Academy of Sciences, Institute of Physics, Praha , Czech Republic

    Pavel Hubík

  3. Division of Solid-State Physics, Czech Academy of Sciences, Institute of Physics, Praha, Czech Republic

    Jiří J. Mareš

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Criado, J.M., Pérez-Maqueda, L.A., Koga, N. (2017). Sample Controlled Thermal Analysis (SCTA) as a Promising Tool for Kinetic Characterization of Solid-State Reaction and Controlled Material Synthesis. In: Šesták, J., Hubík, P., Mareš, J. (eds) Thermal Physics and Thermal Analysis. Hot Topics in Thermal Analysis and Calorimetry, vol 11. Springer, Cham. https://doi.org/10.1007/978-3-319-45899-1_2

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