Abstract
In the current study, inclusions and the pitting corrosion resistance of 304 stainless steels with and without lanthanum addition were analyzed using a scanning electron microscope attached with an energy dispersive spectrum and an anodic potentiodynamic polarization test in 3.5 wt% NaCl solution. Inclusions of (Mn, Cr, Si, Al, Ca)-oxides were modified to (La, Al, Si)-oxides in the stainless steel by the addition of lanthanum. The number density and area fraction of oxide inclusions increased from 8.6 mm−2 and 165 ppm to 29.9 mm−2 and 153.5 ppm, respectively, while those of pure MnS decreased from 36.9 mm−2 and 162.9 ppm to 22.6 mm−2 and 101.7 ppm, respectively. Due to the variation in the chemical composition of oxide inclusions and the decrease in the amount of MnS, the potential of pitting corrosion was increased from 0.167 VSCE to 0.303 VSCE.
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References
Wilson WG, Kay DAR, Vahed A (1974) The use of thermodynamics and phase equilibria to predict the behavior of the rare earth elements in steel. JOM 26(5):14–23
Zhang J, Ren Y, Ren Q, Zhang L (2022) Transient evolution of nonmetallic inclusions in a Si–Mn-killed stainless steel with cerium addition. Steel Res Int 93(7):2100773
Ren Q, Zhang L (2020) Effect of cerium content on inclusions in an ultra-low-carbon aluminum-killed steel. Metall and Mater Trans B 51(2):589–599
Nishimoto M, Muto I, Sugawara Y, Hara N (2021) Cerium addition to CaS inclusions in stainless steel: Insolubilizing water-soluble inclusions and improving pitting corrosion resistance. Corros Sci 180:109222
Ma M, Liu H, Chen L (2020) Effect of cerium on the initiation of pitting corrosion of 444-type heat-resistant ferritic stainless steel. High Temp Mater Processes (London) 39(1):576–587
Yang H, Yang K, Zhang B (2007) Pitting corrosion resistance of La added 316L stainless steel in simulated body fluids. Mater Lett 61(4):1154–1157
Ha H, Park C, Kwon H (2006) Effects of misch metal on the formation of non-metallic inclusions and the associated resistance to pitting corrosion in 25% Cr duplex stainless steels. Scripta Mater 55(11):991–994
Wang Y, Yang W, Zhang L (2019) Effect of cooling rate on oxide inclusions during solidification of 304 stainless steel. Steel Res Int 90(7):1900027
Wang J, Li W, Ren Y, Zhang L (2019) Thermodynamic and kinetic analysis for transformation of oxide inclusions in solid 304 stainless steels. Steel Res Int 90(7):1800600
Ren Y, Zhang L, Pistorius PC (2017) Transformation of oxide inclusions in type 304 stainless steels during heat treatment. Metall Mater Trans B 48(5):2281–2292
Acknowledgements
The authors are grateful for the support from the National Natural Science Foundation of China (Grant No. 52104342), the Natural Science Foundation of Heibei Province (Grant No. E2021203062), and the High Steel Center (HSC) at North China University of Technology, Yanshan University and University of Science and Technology Beijing.
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© 2023 The Minerals, Metals & Materials Society
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Ren, Q., Zhang, L. (2023). Improvement of Pitting Corrosion Resistance of 304 Stainless Steel with Lanthanum Addition. In: TMS 2023 152nd Annual Meeting & Exhibition Supplemental Proceedings. TMS 2023. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-22524-6_88
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DOI: https://doi.org/10.1007/978-3-031-22524-6_88
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