Abstract
Chirality is a geometric feature, corresponding to the structures that cannot be brought to coincide with their mirror images. To discriminate the object chirality is critical and significant in many areas such as life science, chemistry and physics. Chiral plasmonic from two aspects including chiral near-fields and chiroptical effects in far-fields of nanostructures will be discussed. Chiral near-fields can be characterized by the optical chirality density. Chiroptical effects in far-fields can be analyzed by the transmission matrix. As for far-field chiroptical effects, circular birefringence (CB), circular dichroism (CD) and asymmetric transmission (AT) are frequently discussed. Additional, chiral biomolecules can change some characteristics of chiral nanostructures and thus can be used for chiral sensing. The sensor is easy to implement and is non-invasive to the analyte. Therefore, chiral plasmons have good application prospects in ultra-sensitive chiral molecular sensing. Plasmonic chirality is still evolving, and many phenomena and challenges remain undiscovered, such as circularly polarized luminescence, nonlinear chiral effects, chiral selective hot electron transfer, ultrafast detection, and chiral quantum optics. The research on plasmonic chirality plays a vital role in the future development of science and technology.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Thomson, W., & Kelvin, B. (2010). Lecture Xi. In Baltimore lectures on molecular dynamics and the wave theory of light (pp. 122–134). Cambridge University Press.
Hutt, A. J., & Tan, S. C. (1996). Drug chirality and its clinical significance. Drugs, 52(Suppl 5), 1–12.
Sharma, V., et al. (2009). Structural origin of circularly polarized iridescence in jeweled beetles. Science, 325(5939), 449–451.
Vignolini, S., et al. (2013). Analysing photonic structures in plants. Journal of the Royal Society Interface, 10(87), 20130394.
Coric, I., & List, B. (2012). Asymmetric spiroacetalization catalysed by confined Bronsted acids. Nature, 483(7389), 315–319.
Du, W., et al. (2019). Chiral plasmonics and enhanced chiral light-matter interactions. Science China Physics, Mechanics & Astronomy, 63(4), 1–11.
Collins, J. T., et al. (2017). Chirality and chiroptical effects in metal nanostructures: Fundamentals and current trends. Advanced Optical Materials, 5(16), 1700182.
Yoo, S., & Park, Q. H. (2019). Metamaterials and chiral sensing: A review of fundamentals and applications. Nanophotonics, 8(2), 249–261.
Luo, Y., et al. (2017). Plasmonic chiral nanostructures: Chiroptical effects and applications. Advanced Optical Materials, 5(16), 1700040.
Hentschel, M., et al. (2017). Chiral plasmonics. Science Advances, 3(5), e1602735.
Schäferling, M., et al. (2012). Tailoring enhanced optical chirality: Design principles for chiral plasmonic nanostructures. Physical Review X, 2(3), 031010.
Pfeiffer, C., et al. (2014). High performance bianisotropic metasurfaces: Asymmetric transmission of light. Physical Review Letters, 113(2), 023902.
Gansel, J. K., et al. (2010). Gold helix photonic metamaterials: A numerical parameter study. Optics Express, 18(2), 1059–1069.
Wang, Y., et al. (2016). Co-occurrence of circular dichroism and asymmetric transmission in twist nanoslit-nanorod arrays. Optics Express, 24(15), 16425–16433.
Tang, Y., & Cohen, A. E. (2011). Enhanced enantioselectivity in excitation of chiral molecules by superchiral light. Science, 332(6027), 333–336.
Tang, Y., & Cohen, A. E. (2010). Optical chirality and its interaction with matter. Physical Review Letters, 104(16), 163901.
Lipkin, D. M. (1964). Existence of a new conservation law in electromagnetic theory. Journal of Mathematical Physics, 5(5), 696–700.
Schäferling, M., et al. (2016). Reducing the complexity: Enantioselective chiral near-fields by diagonal slit and mirror configuration. ACS Photonics, 3(6), 1076–1084.
Schaeferling, M., Yin, X., & Giessen, H. (2012). Formation of chiral fields in a symmetric environment. Optics Express, 20(24), 26326–26336.
Meinzer, N., Hendry, E., & Barnes, W. L. (2013). Probing the chiral nature of electromagnetic fields surrounding plasmonic nanostructures. Physical Review B, 88(4), 041407.
Hendry, E., et al. (2012). Chiral electromagnetic fields generated by arrays of nanoslits. Nano Letters, 12(7), 3640–3644.
Davis, T. J., & Hendry, E. (2013). Superchiral electromagnetic fields created by surface plasmons in nonchiral metallic nanostructures. Physical Review B, 87(8), 085405.
Tretyakov, S. A., et al. (1996). Analytical antenna model for chiral scatterers: Comparison with numerical and experimental data. IEEE Transactions on Antennas and Propagation, 44, 1006–1014.
Rockstuhl, C., et al. (2009). Optical activity in chiral media composed of three-dimensional metallic meta-atoms. Physical Review B, 79(3), 035321.
Gansel, J. K., et al. (2009). Gold helix photonic metamaterial as broadband circular polarizer. Science, 325(5947), 1513–1515.
Schäferling, M., et al. (2014). Helical Plasmonic nanostructures as prototypical chiral near-field sources. ACS Photonics, 1(6), 530–537.
Rui, G., et al. (2019). Symmetric meta-absorber-induced superchirality. Advanced Optical Materials, 7(21), 1901038.
Decker, M., et al. (2007). Circular dichroism of planar chiral magnetic metamaterials. Optics Letters, 32(7), 856–858.
Zu, S., Bao, Y., & Fang, Z. (2016). Planar plasmonic chiral nanostructures. Nanoscale, 8(7), 3900–3905.
Papakostas, A., et al. (2003). Optical manifestations of planar chirality. Physical Review Letters, 90(10), 107404.
Kuwata-Gonokami, M., et al. (2005). Giant optical activity in quasi-two-dimensional planar nanostructures. Physical Review Letters, 95(22), 227401.
Horrer, A., et al. (2020). Local optical chirality induced by near-field mode interference in achiral plasmonic metamolecules. Nano Letters, 20(1), 509–516.
Eftekhari, F., & Davis, T. J. (2012). Strong chiral optical response from planar arrays of subwavelength metallic structures supporting surface plasmon resonances. Physical Review B, 86(7), 075428.
van de Groep, J., & Polman, A. (2013). Designing dielectric resonators on substrates: Combining magnetic and electric resonances. Optics Express, 21(22), 26285–26302.
Staude, I., et al. (2013). Tailoring directional scattering through magnetic and electric resonances in subwavelength silicon Nanodisks. ACS Nano, 7(9), 7824–7832.
Mohammadi, E., et al. (2019). Accessible superchiral near-fields driven by tailored electric and magnetic resonances in all-dielectric nanostructures. ACS Photonics, 6(8), 1939–1946.
García-Etxarri, A., & Dionne, J. A. (2013). Surface-enhanced circular dichroism spectroscopy mediated by nonchiral nanoantennas. Physical Review B, 87(23), 235409.
Butakov, N. A., & Schuller, J. A. (2016). Designing multipolar resonances in dielectric metamaterials. Scientific Reports, 6, 38487.
Bakker, R. M., et al. (2015). Magnetic and electric hotspots with silicon nanodimers. Nano Letters, 15(3), 2137–2142.
Evlyukhin, A. B., Reinhardt, C., & Chichkov, B. N. (2011). Multipole light scattering by nonspherical nanoparticles in the discrete dipole approximation. Physical Review B, 84(23), 235429.
Solomon, M. L., et al. (2018). Enantiospecific optical enhancement of chiral sensing and separation with dielectric Metasurfaces. ACS Photonics, 6(1), 43–49.
Takechi, H., et al. (2011). Chiroptical measurement of chiral aggregates at liquid-liquid interface in centrifugal liquid membrane cell by Mueller matrix and conventional circular dichroism methods. Molecules, 16(5), 3636–3647.
Helgert, C., et al. (2011). Chiral metamaterial composed of three-dimensional plasmonic nanostructures. Nano Letters, 11(10), 4400–4404.
Esposito, M., et al. (2015). Tailoring chiro-optical effects by helical nanowire arrangement. Nanoscale, 7(43), 18081–18088.
Singh, R., et al. (2009). Terahertz metamaterial with asymmetric transmission. Physical Review B, 80(15), 153104.
Song, K., et al. (2013). A frequency-tunable 90°-polarization rotation device using composite chiral metamaterials. Applied Physics Letters, 103(10), 101908.
Plum, E., Fedotov, V. A., & Zheludev, N. I. (2009). Planar metamaterial with transmission and reflection that depend on the direction of incidence. Applied Physics Letters, 94(13), 131901.
Fedotov, V. A., et al. (2007). Asymmetric transmission of light and enantiomerically sensitive plasmon resonance in planar chiral nanostructures. Nano Letters, 7(7), 1996–1999.
Li, Z., et al. (2016). Tunable dual-band asymmetric transmission for circularly polarized waves with graphene planar chiral metasurfaces. Optics Letters, 41(13), 3142–3145.
Han, J., et al. (2011). An ultrathin twist-structure polarization transformer based on fish-scale metallic wires. Applied Physics Letters, 98(15), 151908.
Gansel, J. K., et al. (2012). Tapered gold-helix metamaterials as improved circular polarizers. Applied Physics Letters, 100(10), 101109.
Pan, C., et al. (2014). Broadband asymmetric transmission of optical waves from spiral plasmonic metamaterials. Applied Physics Letters, 104(12), 121112.
Wang, Y., et al. (2016). Direct and indirect coupling mechanisms in a chiral plasmonic system. Journal of Physics D: Applied Physics, 49(40), 405104.
Bai, Y., et al. (2018). Asymmetric transmission of a planar metamaterial induced by symmetry breaking. Journal of Physics. Condensed Matter, 30(11), 114001.
Bai, Y., et al. (2018). Splitting an asymmetric transmission peak by introducing magnetic-dipole oscillation on gold film. Optical Materials Express, 8(9), 2743.
Aba, T., et al. (2018). Tunable asymmetric transmission through tilted rectangular nanohole arrays in a square lattice. Optics Express, 26(2), 1199–1205.
Hu, Z., et al. (2019). Plasmonic circular dichroism of gold nanoparticle based nanostructures. Advanced Optical Materials, 7(10), 1801590.
Kraust, J. (1949). The helical antenna*. Proceedings of the IEEE, 37, 263–272.
Esposito, M., et al. (2014). Nanoscale 3D chiral Plasmonic helices with circular dichroism at visible frequencies. ACS Photonics, 2(1), 105–114.
Wang, T., et al. (2017). Circular dichroism of a tilted U-shaped nanostructure. Optics Letters, 42(14), 2842–2845.
He, Y., et al. (2014). Tunable three-dimensional helically stacked plasmonic layers on nanosphere monolayers. Nano Letters, 14(4), 1976–1981.
Wang, Y., et al. (2016). Plasmonic chirality of L-shaped nanostructure composed of two slices with different thickness. Optics Express, 24(3), 2307–2317.
Ullah, H., et al. (2020). Giant circular dichroism of chiral L-shaped nanostructure coupled with achiral nanorod: Anomalous behavior of multipolar and dipolar resonant modes. Nanotechnology, 31(27), 275205.
Tang, B., et al. (2017). Chiral-selective Plasmonic Metasurface absorbers operating at visible frequencies. IEEE Photonics Technology Letters, 29(3), 295–298.
Yang, Z.-J., et al. (2016). Enhanced chiral response from the Fabry–Perot cavity coupled meta-surfaces. Chinese Physics B, 25(8), 084201.
Li, J., et al. (2015). Nanoplasmonic sensors with various photonic coupling effects for detecting different targets. The Journal of Physical Chemistry C, 119(52), 29116–29122.
Bai, Y., et al. (2020). Increasing the circular dichroism of the planar chiral nanostructure by inducing coupling between the coverage layer and the planar nanostructure. Optics Express, 28(14), 20563–20572.
Decker, M., et al. (2009). Strong optical activity from twisted-cross photonic metamaterials. Optics Letters, 34(16), 2501–2503.
Decker, M., et al. (2010). Twisted split-ring-resonator photonic metamaterial with huge optical activity. Optics Letters, 35(10), 1593–1595.
Wang, Y., et al. (2019). Strong circular dichroism enhancement by plasmonic coupling between graphene and h-shaped chiral nanostructure. Optics Express, 27(23), 33869–33879.
Narushima, T., & Okamoto, H. (2013). Circular dichroism nano-imaging of two-dimensional chiral metal nanostructures. Physical Chemistry Chemical Physics, 15(33), 13805–13809.
Phua, W. K., et al. (2015). Study of circular dichroism modes through decomposition of planar nanostructures. Plasmonics, 11(2), 449–457.
Zhao, Y., et al. (2017). Chirality detection of enantiomers using twisted optical metamaterials. Nature Communications, 8, 14180.
Wu, X., et al. (2013). Unexpected chirality of nanoparticle dimers and ultrasensitive chiroplasmonic bioanalysis. Journal of the American Chemical Society, 135(49), 18629–18636.
Tullius, R., et al. (2015). “Superchiral” spectroscopy: Detection of protein higher order hierarchical structure with chiral plasmonic nanostructures. Journal of the American Chemical Society, 137(26), 8380–8383.
Qu, Y., et al. (2020). Chiral near-fields induced by plasmonic chiral conic nanoshell metallic nanostructure for sensitive biomolecule detection. The Journal of Physical Chemistry C, 124(25), 13912–13919.
Kumar, J., & Liz-Marzán, L. M. (2019). Recent advances in chiral plasmonics – Towards biomedical applications. Bulletin of the Chemical Society of Japan, 92(1), 30–37.
Hendry, E., et al. (2010). Ultrasensitive detection and characterization of biomolecules using superchiral fields. Nature Nanotechnology, 5(11), 783–787.
Ben-Moshe, A., et al. (2013). Chirality and chiroptical effects in inorganic nanocrystal systems with plasmon and exciton resonances. Chemical Society Reviews, 42(16), 7028–7041.
Wang, Y., et al. (2017). Induced chirality in micron wave through electromagnetic coupling between chiral molecules and graphene nanostructures. Carbon, 120, 203–208.
Govorov, A. O. (2011). Plasmon-induced circular dichroism of a chiral molecule in the vicinity of metal nanocrystals. Application to various geometries. The Journal of Physical Chemistry C, 115(16), 7914–7923.
Abudukelimu, A., et al. (2019). The causality of circular dichroism inducement by isotropic and anisotropic chiral molecules. Journal of Physics D: Applied Physics, 52(30), 305306.
Bochenkov, V. E., & Shabatina, T. I. (2018). Chiral plasmonic biosensors. Biosensors (Basel), 8(4), 120.
Nesterov, M. L., et al. (2016). The role of plasmon-generated near fields for enhanced circular dichroism spectroscopy. ACS Photonics, 3(4), 578–583.
Le Ru, E. C., & Etchegoin, P. G. (2013). Quantifying SERS enhancements. MRS Bulletin, 38(8), 631–640.
Vestler, D., et al. (2018). Circular dichroism enhancement in plasmonic nanorod metamaterials. Optics Express, 26(14), 17841–17848.
Lu, F., et al. (2013). Discrete nanocubes as plasmonic reporters of molecular chirality. Nano Letters, 13(7), 3145–3151.
Yao, Y., et al. (2014). Wide wavelength tuning of optical antennas on graphene with nanosecond response time. Nano Letters, 14(1), 214–219.
Liu, T., Yi, Z., & Xiao, S. (2017). Active control of near-field coupling in a terahertz metal-graphene metamaterial. IEEE Photonics Technology Letters, 29(22), 1998–2001.
Zhou, Y., et al. (2018). Tunable low loss 1D surface plasmons in InAs nanowires. Advanced Materials, 30(35), e1802551.
Yin, X., et al. (2015). Active chiral plasmonics. Nano Letters, 15(7), 4255–4260.
Tian, X., et al. (2018). Improving Luttinger-liquid plasmons in carbon nanotubes by chemical doping. Nanoscale, 10(14), 6288–6293.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Zhang, Z. (2022). Chiral Plasmonics. In: Yu, P., Xu, H., Wang, Z.M. (eds) Plasmon-enhanced light-matter interactions. Lecture Notes in Nanoscale Science and Technology, vol 31. Springer, Cham. https://doi.org/10.1007/978-3-030-87544-2_1
Download citation
DOI: https://doi.org/10.1007/978-3-030-87544-2_1
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-87543-5
Online ISBN: 978-3-030-87544-2
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)