Abstract
X-ray absorption spectroscopy (XAS) is a powerful technique for the characterization of artifacts in the cultural heritage field. The recent development of data collection techniques with a high spatial resolution has considerably improved the level of comprehension of these intrinsically inhomogeneous materials. In this contribution the XAS technique and the related instrumentation and data collection strategies are presented as well as an overview of the main studies carried out in the last years.
References
Lee PA, Citrin PH, Eisenberger P, Kincaid BM (1981) Extended x-ray absorption fine structure—its strengths and limitations as a structural tool. Rev Mod Phys 53:769–806
Rehr JJ, Albers RC (2000) Theoretical approaches to x-ray absorption fine structure. Rev Mod Phys 72:621–654
Ashley CA, Doniach S (1975) Theory of extended x-ray absorption edge fine structure (EXAFS) in crystalline solids. Phys Rev B 11:1279–1288
Lee PA, Pendry JB (1975) Theory of the extended x-ray absorption fine structure. Phys Rev B 11:2795–2811
Natoli CR, Benfatto M (1986) A unifying scheme of interpretation of x-ray absorption spectra based on the multiple scattering theory. J Phys Coll 47, No. C8, C8–11–C8–23
Rehr JJ, Kas JJ, Vila FD, Prange MP, Jorissnen K (2010) Parameter-free calculations of X-ray spectra with FEFF9. Phys Chem Chem Phys 12:5503–5513
S. Tomic, B.G. Searle, A. Wander, Harrison N.M., A.J. Dent, J. F. W. Mosselmans, and Inglesfield J. E., New tools for the analysis of EXAFS: the DL EXCURV package. Tech. report, 2005. ISSN 1362-0207
Filipponi A, Di Cicco A (1995) X-ray-absorption spectroscopy and n-body distribution functions in condensed matter. II. Data analysis and applications. Phys Rev B 52:15135–15149
Cramer SP, Eccles TK, Kutzler FW, Hodgson KO, Mortenson LE (1976) Molybdenum x-ray absorption edge spectra. the chemical state of molybdenum in nitrogenase. J Am Chem Soc 98(5):1287–1288
Galoisy L, Calas G, Arrio MA (2001) High-resolution XANES spectra of iron in minerals and glasses: structural information from the pre-edge region. Chem Geol 174(1):307–319, 6th International Silicate Melt Workshop
Wilke M, Farges F, Petit PE, Brown GE Jr, Martin F (2001) Oxidation state and co-ordination of Fe in minerals: an Fe K-XANES spectroscopic study. Am Mineral 86(5–6):714–730
Wasserman SR (1997) The analysis of mixtures: application of principal component analysis to XAS spectra. J Phys IV France 7-C2:203–205
Ressler T, Wong J, Roos J, Smith IL (2000) Quantitative speciation of mn-bearing particulates emitted from autos burning (methylcyclopentadienyl)manganese tricarbonyl-added gasolines using XANES spectroscopy. Environ Sci Technol 34(6):950–958
Frenkel AI, Kleifeld O, Wasserman SR, Sagi I (2002) Phase speciation by extended x-ray absorption fine structure spectroscopy. J Chem Phys 116(21):9449–9456
Joly Y, Bunau O, Lorenzo JE, Galra RM, Grenier B, Thomson S (2009) Self-consistency, Hubbard, spin-orbit and other advances in the FDMNES code to simulate XANES and RXD experiments. J Phys Conf Ser 190:012007
Gougoussis C, Calandra M, Seitsonen AP, Mauri F (2009) First-principles calculations of x-ray absorption in a scheme based on ultrasoft pseudopotentials: from α-quartz to high-Tc compounds. Phys Rev B 80:075102
Benfatto M, Della Longa S (2001) Geometrical fitting of experimental XANES spectra by a full multiple-scattering procedure. J Synchrotron Radiat 8(4):1087–1094
Smolentsev G, Soldatov A (2005) Quantitative local structure refinement from XANES: multi-dimensional interpolation approach. J Synchrotron Rad 13:19–29
Cotte M, Susini J, Dik J, Janssens K (2010) Synchrotron-based x-ray absorption spectroscopy for art conservation: looking back and looking forward. Acc Chem Res 43(6):705–714
Cotte M, Pouyet E, Salom M, Rivard C, De Nolf W, Castillo-Michel H, Fabris T, Monico L, Janssens K, Wang T, Sciau P, Verger L, Cormier L, Dargaud O, Brun E, Bugnazet D, Fayard B, Hesse B, Pradas del Real AE, Veronesi G, Langlois J, Balcar N, Vandenberghe Y, Sol VA, Kieffer J, Barrett R, Cohen C, Cornu C, Baker R, Gagliardini E, Papillon E, Susini J (2017) The id21 x-ray and infrared microscopy beamline at the ESRF: status and recent applications to artistic materials. J Anal At Spectrom 32:477–493
Ishikawa T, Tamasaku K, Yabashi M (2005) High-resolution x-ray monochromators. Nucl Instrum Methods Phys Res A 547(1):42–49
Krause MO, Oliver JH (1979) Natural widths of atomic K and L levels, Kα X-ray lines and several KLL Auger lines. J Phys Chem Ref Data 8(2):329–338
Bearden JA, Burr AF (1967) Reevaluation of x-ray atomic energy levels. Rev Mod Phys 39:125–142
Cotte M, Genty-Vincent A, Janssens K, Susini J (2018) Applications of synchrotron x-ray nano-probes in the field of cultural heritage. C R Phys 19(7):575–588, Physics and arts/Physique et arts
Sakdinawat A, Attwood D (2010) Nanoscale x-ray imaging. Nat Photonics 4(6):840–848
Bertrand L, Cotte M, Stampanoni M, Thoury M, Marone F, Schder S (2012) Development and trends in synchrotron studies of ancient and historical materials. Phys Rep 519(2):51–96
Chadwick AV, Berko A, Schofield EJ, Jones AM, Mosselmans JFW, Smith AD (2012) Application of microfocus x-ray beams from synchrotrons in heritage conservation. Int J Archit Herit 6(2):228–258
Erko A, Zizak I (2009) Hard x-ray micro-spectroscopy at berliner elektronenspeicherring fr synchrotronstrahlung ii. Spectrochim Acta B At Spectrosc 64(9):833–848
Edwards NP, Webb SM, Krest CM, van Campen D, Manning PL, Wogelius RA, Bergmann U (2018) A new synchrotron rapid-scanning X-ray fluorescence (SRS-XRF) imaging station at SSRL beamline 6-2. J Synchrotron Radiat 25(5):1565–1573
Flank A-M, Cauchon G, Lagarde P, Bac S, Janousch M, Wetter J-M, Dubuisson R, Idir F, Langlois M, Moreno T, Vantelon D (2006) Lucia, a microfocus soft XAS beamline. Nucl Instrum Methods Phys Res B 246(1):269–274, Synchrotron Radiation and Materials Science
Monico L, Van der Snickt G, Janssens K, De Nolf W, Miliani C, Verbeeck J, He Tian, Tan H, Dik J, Radepont M, Cotte M (2011) Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of synchrotron x-ray spectromicroscopy and related methods. 1. Artificially aged model samples. Anal Chem 83(4):1214–1223
Eng PJ, Newville M, Rivers L, Sutton SR (1998) Dynamically figured Kirkpatrick Baez x-ray microfocusing optics. SPIE’s Int Symp Opt Sci Eng Instrum 3449:145–156
Monico L, Janssens K, Alfeld M, Cotte M, Vanmeert F, Ryan CG, Falkenberg G, Howard DL, Brunetti BG, Miliani C (2015) Full spectral XANES imaging using the MAIA detector array as a new tool for the study of the alteration process of chrome yellow pigments in paintings by Vincent van Gogh. J Anal At Spectrom 30:613–626
Cotte M, Szlachetko J, Lahlil S, Salome M, Sole VA, Biron I, Susini J (2011) Coupling a wavelength dispersive spectrometer with a synchrotron-based x-ray microscope: a winning combination for micro-x-ray fluorescence and micro-XANES analyses of complex artistic materials. J Anal At Spectrom 26:1051
Ryan CG, Siddons DP, Kirkham R, Li ZY, de Jonge MD, Paterson DJ, Kuczewski A, Howard DL, Dunn PA, Falkenberg G, Boesenberg U, De Geronimo G, Fisher LA, Halfpenny A, Lintern MJ, Lombi E, Dyl KA, Jensen M, Moorhead GF, Cleverley JS, Hough RM, Godel B, Barnes SJ, James SA, Spiers KM, Alfeld M, Wellenreuther G, Vukmanovic Z, Borg S (2014) Maia x-ray fluorescence imaging: capturing detail in complex natural samples. J Phys Conf Ser 499:012002
Boesenberg U, Ryan CG, Kirkham R, Siddons DP, Alfeld M, Garrevoet J, Núñez T, Claussen T, Kracht T, Falkenberg G (2016) Fast X-ray microfluorescence imaging with submicrometer-resolution integrating a Maia detector at beamline P06 at PETRAIII. J Synchrotron Radiat 23(6):1550–1560
De Andrade V, Susini J, Salom M, Beraldin O, Rigault C, Heymes T, Lewin E, Vidal O (2011) Submicrometer hyperspectral x-ray imaging of heterogeneous rocks and geomaterials: applications at the Fe k-edge. Anal Chem 83(11):4220–4227
Pouyet E, Fayard B, Salomé M, Taniguchi Y, Sette F, Cotte M (2015) Thin-sections of painting fragments: opportunities for combined synchrotron-based micro-spectroscopic techniques. Herit Sci 3(1):3
Meirer F, Cabana J, Liu Y, Mehta A, Andrews JC, Pianetta P (2011) Three-dimensional imaging of chemical phase transformations at the nanoscale with full-field transmission X-ray microscopy. J Synchrotron Radiat 18(5):773–781
Mangold S, Steininger R, dos Santos Rolo T, Gttlicher J (2013) Full field spectroscopic imaging at the ANKA-XAS- and -SUL-x-beamlines. J Phys Conf Ser 430:012130
Sabbe PJ, Dowsett MG, De Keersmaecker M, Hand M, Thompson P, Adriaens A (2015) Synthesis and surface characterization of a patterned cuprite sample: preparatory step in the evaluation scheme of an x-ray-excited optical microscopy system. Appl Surf Sci 332:657–664
Dowsett M, Hand M, Sabbe PJ, Thompson P, Adriaens A (2015) XEOM 1 – a novel microscopy system for the chemical imaging of heritage metal surfaces. Herit Sci 3(1):14
Silversmit G, Vekemans B, Nikitenko S, Schmitz S, Schoonjans T, Brenker FE, Vincze L (2010) Spatially resolved 3d micro-XANES by a confocal detection scheme. Phys Chem Chem Phys 12:5653–5659
Kanngiesser B, Malzer W, Mantouvalou I, Sokaras D, Karydas AG (2010) A deep view in cultural heritage confocal micro x-ray spectroscopy for depth resolved elemental analysis. Appl Phys A Mater Sci Process 106:325–338
MartĂnez-Criado G, Tucoulou R, Cloetens P, Bleuet P, Bohic S, Cauzid J, Kieffer I, Kosior E, LabourĂ© S, Petitgirard S, Rack A, Sans JA, Segura-Ruiz J, Suhonen H, Susini J, Villanova J (2012) Status of the hard X-ray microprobe beamline ID22 of the European Synchrotron Radiation Facility. J Synchrotron Radiat 19(1):10–18
Chen G, Chu S, Sun T, Sun X, Zheng L, An P, Zhu J, Wu S, Du Y, Zhang J (2017) Confocal depth-resolved fluorescence micro-X-ray absorption spectroscopy for the study of cultural heritage materials: a new mobile endstation at the Beijing Synchrotron Radiation Facility. J Synchrotron Radiat 24(5):1000–1005
Lhl L, Hesse B, Mantouvalou I, Wilke M, Mahlkow S, Aloupi-Siotis E, Kanngiesser B (2014) Confocal XANES and the attic black glaze: the three-stage firing process through modern reproduction. Anal Chem 86(14):6924–6930
Erbil A, Cargill GS III, Frahm R, Boehme RF (1988) Total-electron-yield current measurements for near-surface extended x-ray-absorption fine structure. Phys Rev B37:2450–2464
Padovani S, Borgia I, Brunetti B, Sgamellotti A, Giulivi A, d’Acapito F, Mazzoldi P, Sada C, Battaglin G (2004) Silver and copper nanoclusters in the lustre decoration of Italian renaissance pottery: an exafs study. Appl Phys A Mater Sci Process 79(2):229–233
Zanella L, Casadio F, Gray KA, Warta R, Ma Q, Gaillard J-F (2011) The darkening of zinc yellow: XANES speciation of chromium in artist’s paints after light and chemical exposures. J Anal At Spectrom 26:1090–1097
Gervais C, Languille MA, Rguer S, Gillet M, Vicenzi EP, Chagnot S, Baudelet F, Bertrand L (2013) Live Prussian blue fading by time-resolved x-ray absorption spectroscopy. Appl Phys A Mater Sci Process 111:15–22
Bertrand L, Scheder S, Anglos D, Breese MBH, Janssens K, Moini M, Simon A (2015) Mitigation strategies for radiation damage in the analysis of ancient materials. TrAC Trend Anal Chem 66:128–145
Howells MR, Beetz T, Chapman HN, Cui C, Holton JM, Jacobsen CJ, Kirz J, Lima E, Marchesini S, Miao H, Sayre D, Shapiro DA, Spence JCH, Starodub D (2009) An assessment of the resolution limitation due to radiation-damage in x-ray diffraction microscopy. J Electron Spectrosc Relat Phenom 170(1):4–12, Radiation Damage
d’Acapito F, Lepore GO, Puri A, Laloni A, La Manna F, Dettona E, De Luisa A, Martin A (2019) The LISA beamline at ESRF. J Synchrotron Radiat 26(2):551–558
Gervais C, Thoury M, Rguer S, Gueriau P, Mass J (2015) Radiation damages during synchrotron X-ray micro-analyses of Prussian blue and zinc white historic paintings: detection, mitigation and integration. Appl Phys A Mater Sci Process 121:949
Colomban P (2009) The use of metal nanoparticles to produce yellow, red and iridescent colour, from bronze age to present times in lustre pottery and glass: solid state chemistry, spectroscopy and nanostructure. J Nano Res 8:109–132
Bertrand L, Bernard S, Marone F, Thoury M, Reiche I, Gourrier A, Sciau P, Bergmann U (2016) Emerging approaches in synchrotron studies of materials from cultural and natural history collections. Top Curr Chem (Z) 374:7
Janssens K, Van der Snickt G, Vanmeert F, Legrand S, Nuyts G, Alfeld M, Monico L, Anaf W, De Nolf W, Vermeulen MM, Verbeeck J, De Wael K (2016) Non-invasive and non-destructive examination of artistic pigments, paints, and paintings by means of x-ray methods. Top Curr Chem 374:81
Monico L, Van der Snickt G, Janssens K, De Nolf W, Miliani C, Dik J, Radepont M, Hendriks E, Geldof M, Cotte M (2011) Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of synchrotron x-ray spectromicroscopy and related methods. 2. Original paint layer samples. Anal Chem 83(4):1224–1231
Monico L, Janssens K, Miliani C, Brunetti BG, Vagnini M, Vanmeert F, Falkenberg G, Abakumov A, Lu Y, Tian H, Verbeeck J, Radepont M, Cotte M, Hendriks E, Geldof M, van der Loeff L, Salvant J, Menu M (2013) Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. 3. Synthesis, characterization, and detection of different crystal forms of the chrome yellow pigment. Anal Chem 85(2):851–859
L. Monico, K. Janssens, C. Miliani, G. Van der Snickt, B.G. Brunetti, M. Cestelli Guidi, M. Radepont, and M. Cotte, Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. 4. artificial aging of model samples of co-precipitates of lead chromate and lead sulfate, Anal Chem 85 (2013), no. 2, 860–867,
L. Monico, K. Janssens, F. Vanmeert, M. Cotte, B.G. Brunetti, G. Van der Snickt, M. Leeuwestein, J. Salvant Plisson, M. Menu, and C. Miliani, Degradation process of lead chromate in paintings by Vincent van Gogh studied by means of spectromicroscopic methods. Part 5. Effects of nonoriginal surface coatings into the nature and distribution of chromium and sulfur species in chrome yellow paints, Anal. Chem. 86 (2014), no. 21, 10804–10811,
Monico L, Janssens K, Hendriks E, Vanmeert F, VanderSnickt G, Cotte M, Falkenberg G, Brunetti BG, Miliani C (2015) Evidence for degradation of the chrome yellows in van Gogh’s Sunflowers: a study using noninvasive in situ methods and synchrotron-radiation based X-ray techniques. Angew Chem Int Ed 54(47):13923–13927
Monico L, Chieli A, DeMeyer S, Cotte M, deNolf W, Falkenberg G, Janssens K, Romani A, Miliani C (2018) Role of the relative humidity and the Cd/Zn stoichiometry in the photooxidation process of cadmium yellows (CdS/Cd1-xZnxS) in oil paintings. Chem Eur J 24(45):11584–11593
Robinet L, Spring M, Pags-Camagna S, Vantelon D, Trcera N (2011) Investigation of the discoloration of smalt pigment in historic paintings by micro-x-ray absorption spectroscopy at the Co k-edge. Anal Chem 83(13):5145–5152
Cianchetta I, Colantoni I, Talarico F, d’Acapito F, Trapananti A, Maurizio C, Fantacci S, Davoli I (2012) Discoloration of the smalt pigment: experimental studies and ab initio calculations. J Anal At Spectrom 27:1941–1948
Samain L, Grandjean F, Long GJ, Martinetto P, Bordet P, Strivay D (2013) Relationship between the synthesis of prussian blue pigments, their color, physical properties, and their behavior in paint layers. J Phys Chem C 117(19):9693–9712
Samain L, Silversmit G, Sanyova J, Vekemans B, Salomon H, Gilbert B, Grandjean F, Long GJ, Hermann RP, Vincze L, Strivay D (2011) Fading of modern prussian blue pigments in linseed oil medium. J Anal At Spectrom 26:930–941
Gervais C, Languille M-A, Rguer S, Gillet M, Pelletier S, Garnier C, Vicenzi EP, Bertrand L (2013) Why does prussian blue fade? understanding the role(s) of the substrate. J Anal At Spectrom 28:1600–1609
M.O. Figueiredo, T.P. Silva, J.P. Veiga, M.I. Prudencio, M.I. Dias, M.A. Matos, and A.M. Pais, 2010. Blue pigments in XVI-XVII century glazes: a comparative study between Portuguese faiences and Chinese porcelains. In: Ruvalcaba Sil JL, Reyes Trujeque J, Arenas Alatorre JA, Velzquez Castro A (eds) 2nd Latin-American symposium on physical and chemical methods in archaeology, art and cultural heritage conservation (LASMAC 2009). Symposium on archaeological and arts issues in materials science IMRC 2009. Selected papers. Publ. Instituto Nacional de Antropologa e Historia, Mexico. ISBN: 978-607-02-2017-3
Figueiredo MO, Silva TP, Veiga JP (2012) A XANES study of cobalt speciation state in blue-and-white glazes from 16th to 17th century Chinese porcelains. J Electron Spectrosc Relat Phenom 185(3):97–102
Wang L, Wang C (2011) Co speciation in blue decorations of blue-and-white porcelains from Jingdezhen kiln by using XAFS spectroscopy. J Anal At Spectrom 26:1796–1801
Wang T, Zhu TQ, Feng ZY, Fayard B, Pouyet E, Cotte M, De Nolf W, Salome M, Sciau P (2016) Synchrotron radiation-based multi-analytical approach for studying underglaze color: the microstructure of Chinese Qinghua blue decors (Ming dynasty). Anal Chim Acta 928:20–31
Li Y, Yang Y, Zhu J, Zhang X, Jiang S, Zhang Z, Yao Z, Solbrekken G (2016) Colour-generating mechanism of copper-red porcelain from Changsha Kiln (A.D. 7th-10th century), China. Ceram Int 42(7):8495–8500
Zhu J, Duan H, Yang Y, Guan L, Xu W, Chen D, Zhang J, Wang L, Huang Y, Wang C (2014) Colouration mechanism of underglaze copper-red decoration porcelain (AD 13th–14th century), China. J Synchrotron Radiat 21(4):751–755
Hao W, Yang Y, Zhu J, Gu Z, Xie Y, Zhang J, Wang L (2014) XANES investigation of Chinese faience excavated from Peng state cemetery site in western Zhou period (BC1046-BC771). J Electron Spectrosc Relat Phenom 196:133–135, Advances in Vacuum Ultraviolet and X-ray Physics, The 38th International Conference on Vacuum Ultraviolet and X-ray Physics (VUVX2013), University of Science and Technology of China
Li Y, Zhang B, Cheng H, Zheng J (2019) Revealing the coloration mechanism in the earliest Chinese celadon glaze. J Eur Ceram Soc 39(4):1675–1682
Walton M, Trentelman K, Cummings M, Poretti G, Maish J, Saunders D, Foran B, Brodie M, Mehta A (2013) Material evidence for multiple firings of ancient Athenian redfigure pottery. J Am Ceram Soc 96(7):2031–2035
Bardelli F, Barone G, Crupi V, Longo F, Maisano G, Majolino D, Mazzoleni P, Venuti V (2012) Iron speciation in ancient Attic pottery pigments: a non-destructive SR-XAS investigation. J Synchrotron Radiat 19(5):782–788
Cianchetta I, Trentelman K, Maish J, Saunders D, Foran B, Walton M, Sciau P, Wang T, Pouyet E, Cotte M, Meirer F, Liu Y, Pianetta P, Mehta A (2015) Evidence for an unorthodox firing sequence employed by the berlin painter: deciphering ancient ceramic firing conditions through high-resolution material characterization and replication. J Anal At Spectrom 30:666–676
Meirer F, Liu Y, Pouyet E, Fayard B, Cotte M, Sanchez C, Andrews JC, Mehta A, Sciau P (2013) Full-field XANES analysis of roman ceramics to estimate firing conditions – a novel probe to study hierarchical heterogeneous materials. J Anal At Spectrom 28:1870–1883
Walton MS, Svoboda M, Mehta A, Webb S, Trentelman K (2010) Material evidence for the use of attic white-ground lekythoi ceramics in cremation burials. J Archaeol Sci 37(5):936–940
Barilaro D, Crupi V, Majolino D, Venuti V, Barone G, DAcapito F, Bardelli F, Giannici F (2007) Decorated pottery study: analysis of pigments by x-ray absorbance spectroscopy measurements. J Appl Phys 101(6):064909
Barilaro D, Crupi V, Interdonato S, Majolino V, Venuti D, Barone G, La Russa MF, Bardelli F (2008) Characterization of blue decorated renaissance pottery fragments from Caltagirone (Sicily, Italy). Appl Phys A Mater Sci Process 92:91–96
Crupi V, Majolino D, Venuti V, Barone G, Mazzoleni P, Pezzino A, La Russa MF, Ruffolo SA, Bardelli F (2010) Non-destructive identification of green and yellow pigments: the case of some Sicilian renaissance glazed pottery. Appl Phys A Mater Sci Process 100(3):845–853
Bardelli F, Barone G, Crupi V, Longo F, Majolino D, Mazzoleni P, Venuti V (2011) Combined non-destructive XRF and SR-XAS study of archaeological artefacts. Anal Bioanal Chem 399:3147
Cartechini L, Rosi F, Miliani C, d’Acapito F, Brunetti BG, Sgamellotti A (2011) Modified Naples yellow in renaissance majolica: study of Pb-Sb-Zn and Pb-Sb-Fe ternary pyroantimonates by x-ray absorption spectroscopy. J Anal At Spectrom 26:2500–2507
Quartieri S, Arletti R (2013) The use of x-ray absorption spectroscopy in historical glass research, ch. 4.3. Wiley, pp 301–309
Mastelaro VR, Zanotto ED (2018) X-ray absorption fine structure (XAFS) studies of oxide glasses a 45-year overview. Materials 11:204
Zhao C, Zhang Y, Wang C, Hou M, Li A (2019) Recent progress in instrumental techniques for architectural heritage materials. Herit Sci 7(1):36
Ceglia A, Nuyts G, Cagno S, Meulebroeck W, Baert K, Cosyns P, Nys K, Thienpont H, Janssens K, Terryn H (2014) A XANES study of chromophores: the case of black glass. Anal Methods 6:2662–2671
Ceglia A, Nuyts G, Meulebroeck W, Cagno S, Silvestri A, Zoleo A, Nys K, Janssens K, Thienpont H, Terryn H (2015) Iron speciation in soda-lime-silica glass: a comparison of XANES and UV-Vis-NIR spectroscopy. J Anal At Spectrom 30:1552–1561
Arletti R, Quartieri S, Freestone IC (2013) A XANES study of chromophores in archaeological glass. Appl Phys A Mater Sci Process 111:99
Arletti R, Giacobbe C, Quartieri S, Sabatino G, Tigano G, Triscari M, Vezzalini G (2010) Archaeometrical investigation of Sicilian early byzantine glass: chemical and spectroscopic data. Archaeometry 52(1):99–114
Gliozzo E, Santagostino Barbone A, d’Acapito F, Turchiano M, Turbanti Memmi I, Volpe G (2010) The sectilia panels of Faragola (Ascoli Satriano, Southern Italy): a multi-analytical study of the green, marbled (green and yellow), blue and blackish glass slabs. Archaeometry 52(3):389–415
Gliozzo E, Santagostino Barbone A, d’Acapito F (2013) Waste glass, vessels and window-panes from Thamusida (Morocco): grouping natron-based bluegreen and colourless Roman glasses. Archaeometry 55(4):609–639
Klysubun W, Ravel B, Klysubun P, Sombunchoo P, Deenan W (2013) XAS study of Mn, Fe and Cu as indicators of historical glass decay. Appl Phys A Mater Sci Process 111:775
Hunault M, Bauchau F, Loisel C, Hrold M, Galoisy L, Newville M, Calas G (2016) Spectroscopic investigation of the coloration and fabrication conditions of medieval blue glasses. J Am Ceram Soc 99(1):89–97
Choudhury S, Hormes J, Agyeman-Budu DN, Woll AR, George GN, Coulthard I, Pickering IJ (2015) Application of a spoked channel array to confocal X-ray fluorescence imaging and x-ray absorption spectroscopy of medieval stained glass. J Anal At Spectrom 30:759–766
Abuin M, Serrano A, Chaboy J, Garca MA, Carmona N (2013) XAS study of Mn, Fe and Cu as indicators of historical glass decay. J Anal At Spectrom 28:1118–1124
Klysubun W, Thongkam Y, Pongkrapan S, Won-in K, Thienprasert JT, Dararutana P (2011) XAS study on copper red in ancient glass beads from Thailand. Anal BioAnal Chem 399:3033
Cagno S, Nuyts G, Bugani S, De Vis K, Schalm O, Caen J, Helfen L, Cotte M, Reischig P, Janssens K (2011) Evaluation of manganese-bodies removal in historical stained glass windows via Sr-μ-XANES/XRF and Sr-μ-CT. J Anal At Spectrom 26:2442–2451
Lahlil S, Biron I, Cotte M, Susini J, Menguy N (2010) Synthesis of calcium antimonate nano-crystals by the 18th dynasty Egyptian glassmakers. Appl Phys A Mater Sci Process 98:1
Lahlil S, Biron I, Cotte M, Susini J (2010) New insight on the in situ crystallization of calcium antimonate opacified glass during the roman period. Appl Phys A Mater Sci Process 100:683
Li Y, Zhu J, Ji L, Shan Y, Jiang S, Chen G, Sciau P, Wang W, Wang C (2018) Study of arsenic in famille rose porcelain from the imperial palace of Qing dynasty, Beijing, China. Ceram Int 44(2):1627–1632
Young ML (2012) Archaeometallurgy using synchrotron radiation: a review. Rep Prog Phys 75(3):036504
Monnier J, Neff D, Rguer S, Dillmann P, Bellot-Gurlet L, Leroy E, Foy E, Legrand L, Guillot I (2010) A corrosion study of the ferrous medieval reinforcement of the Amiens cathedral. phase characterisation and localisation by various microprobes techniques. Corros Sci 52(3):695–710
Monnier J, Vantelon D, Reguer S, Dillmann P (2011) X-ray absorption spectroscopy study of the various forms of phosphorus in ancient iron samples. J Anal At Spectrom 26:885–891
Adriaens A, Dowsett M (2010) The coordinated use of synchrotron spectroelectrochemistry for corrosion studies on heritage metals. Acc Chem Res 43(6):927–935
Mirambet F, Reguer S, Rocca E, Hollner S, Testemale D (2010) A complementary set of electrochemical and x-ray synchrotron techniques to determine the passivation mechanism of iron treated in a new corrosion inhibitor solution specifically developed for the preservation of metallic artefacts. Appl Phys A Mater Sci Process 99(2):341–349
Almkvist G, Persson I (2011) Distribution of iron and sulfur and their speciation in relation to degradation processes in wood from the Swedish warship Vasa. New J Chem 35:1491–1502
Schofield EJ, Sarangi R, Mehta A, Jones AM, Mosselmans FJW, Chadwick AV (2011) Nanoparticle de-acidification of the Mary Rose. Mater Today 14(7–8):358
Fors Y, Jalilehvand M, Sandstrom F (2011) Analytical aspects of waterlogged wood in historical shipwrecks. Anal Sci 27(8):785–785
Fors Y, Jalilehvand F, Risberg ED, Bjordal C, Phillips E, Sandstrom M (2012) Sulfur and iron analyses of marine archaeological wood in shipwrecks from the Baltic sea and Scandinavian waters. J Archaeol Sci 39(7):2521–2532
Fors H, Grudd Y, Rindby A, Jalilehvand F, Sandström M, Cato I, Bornmalm L (2014) Sulfur and iron accumulation in three marine-archaeological shipwrecks in the Baltic sea: the ghost, the crown and the sword. Sci Rep 4:4222
Frank P, Caruso F, Caponetti E (2012) Ancient wood of the Acqualadrone rostrum: materials history through gas chromatography/mass spectrometry and sulfur x-ray absorption spectroscopy. Anal Chem 84(10):4419–4428
Chadwick AV, Berko A, Schofield EJ, Smith AD, Mosselmans JFW, Jones AM, Cibin G (2016) The application of x-ray absorption spectroscopy in archaeological conservation: example of an artefact from henry viii warship, the Mary Rose. J Non-Cryst Solids 451:49–55, Structure, dynamics and applications of non-crystalline solids and disordered materials
Zougrou IM, Katsikini M, Pinakidou F, Paloura EC, Papadopoulou L, Tsoukala E (2014) Study of fossil bones by synchrotron radiation micro-spectroscopic techniques and scanning electron microscopy. J Synchrotron Radiat 21(1):149–160
Keenan SW, Engel AS, Roy GL, Bovenkamp-Langlois A (2015) Evaluating the consequences of diagenesis and fossilization on bioapatite lattice structure and composition. Chem Geol 413:18–27
Kakoulli I, Prikhodko SV, Fischer C, Cilluffo M, Uribe M, Bechtel HA, Fakra SC, Marcus MA (2014) Distribution and chemical speciation of arsenic in ancient human hair using synchrotron radiation. Anal Chem 86(1):521–526
Meyer M, Borca CN, Huthwelker T, Bieber M, Messlinger K, Fink RH, Spath A (2017) XRF studies on the colour brilliance in ancient wool carpets. Scanning 2017:6346212
Christiansen T, Cotte M, Loredo-Portales R, Lindelof PE, Mortensen K, Ryholt K, Larsen S (2017) The nature of ancient Egyptian copper-containing carbon inks is revealed by synchrotron radiation based x-ray microscopy. Sci Rep 7(1):15346
R. Dimper, H. Reichert, P. Raimondi, L. Sanchez Ortiz, F. Sette, and J. Susini., ESRF upgrade programme phase ii (2015–2022) technical design study, 2014
Bertrand L, Languille M-A, Cohen SX, Robinet L, Gervais C, Leroy S, Bernard D, Le Pennec E, Josse W, Doucet J, Schöder S (2011) European research platform IPANEMA at the SOLEIL synchrotron for ancient and historical materials. J Synchrotron Radiat 18(5):765–772
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D’Acapito, F. (2022). X-Ray Absorption Spectroscopy (XAS) Applied to Cultural Heritage. In: D'Amico, S., Venuti, V. (eds) Handbook of Cultural Heritage Analysis. Springer, Cham. https://doi.org/10.1007/978-3-030-60016-7_4
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DOI: https://doi.org/10.1007/978-3-030-60016-7_4
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