Abstract
We investigated the debonding energy between confined layers of a soft elastic solid (PDMS) and a circular steel indenter in a flat punch geometry. PDMS is extensively used in applications, but also a widespread model system for fundamental research. Varying systematically the pulling speed and the viscoelastic properties, notably the modulus, we determined scaling laws for the debonding energy. We showed that the debonding energy is independent of the sample thickness. Applying a new approach and separating the crack initiation and the propagation part of the force curves, we analyzed the thickness dependence more precisely and we demonstrated that the energy to propagate the crack at given average speed does not only depend on the modulus, but also on the sample thickness.
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References
C. Creton, MRS Bull. 28, 434 (2003).
R.E. Webber, K.R. Shull, A. Roos, C. Creton, Phys. Rev. E 68, 021805 (2003).
A.J. Crosby, K.R. Shull, H. Lakrout, C. Creton, J. Appl. Phys. 88, 2956 (2000).
J. Nase, A. Lindner, C. Creton, Phys. Rev. Lett. 101, 074503 (2008).
K.R. Shull, Mater. Sci. Engin. R-Rep. 36, 1 (2002).
D. Kaelble, J. Adhes. 37, 205 (1992).
C. Verdier, G. Ravilly, J. Polym. Sci. Part B-Polym. Phys. 45, 2113 (2007).
D. Maugis, M. Barquins, J. Phys. D-Appl. Phys. 11, 1989 (1978).
M. Barquins, D. Maugis, J. Adhes. 13, 53 (1981).
M.K. Chaudhury, G.M. Whitesides, Langmuir 7, 1013 (1991).
A. Zosel, Colloid Polym. Sci. 263, 541 (1985).
K.R. Shull, C. Creton, J. Polym. Sci. Part B-Polym. Phys. 42, 4023 (2004).
F. Deplace, C. Carelli, S. Mariot, H. Retsos, A. Chateauminois, K. Ouzineb, C. Creton, J. Adhes. 85, 18 (2009).
M. Deruelle, H. Hervet, G. Jandeau, L. Leger, J. Adhes. Sci. Technol. 12, 225 (1998).
K. Shull, D. Ahn, W. Chen, C. Flanigan, A. Crosby, Macromol. Chem. Phys. 199, 489 (1998).
A. Chiche, J. Dollhofer, C. Creton, Eur. Phys. J. E 17, 389 (2005).
M.D. Bartlett, A.J. Crosby, Langmuir 29, 11022 (2013).
A. Diethert, V. Körstgens, D. Magerl, K. Ecker, J. Perlich, S.V. Roth, P. Müller-Buschbaum, ACS Appl. Mater. Interfaces 4, 3951 (2012).
M. Meitl, Z. Zhu, V. Kumar, K. Lee, X. Feng, Y. Huang, I. Adesida, R. Nuzzo, J. Rogers, Nat. Mater. 5, 33 (2006).
Y. Xia, G. Whitesides, Angew. Chem. Int. Ed. 37, 550 (1998).
N. Arun, A. Sharma, P.S.G. Pattader, I. Banerjee, H.M. Dixit, K.S. Narayan, Phys. Rev. Lett. 102, 254502 (2009).
J. Nase, C. Creton, O. Ramos, L. Sonnenberg, T. Yamaguchi, A. Lindner, Soft Matter 6, 2685 (2010).
S. Patil, A. Malasi, A. Majumder, A. Ghatak, A. Sharma, Langmuir 28, 42 (2012).
E. Gutierrez, A. Groisman, PLoS ONE 6, e25534 (2011).
C.S. Davis, A.J. Crosby, J. Polym. Sci. Part B-Polym. Phys. 50, 1225 (2012).
C.S. Davis, D. Martina, C. Creton, A. Lindner, A.J. Crosby, Langmuir 28, 14899 (2012).
M.D. Bartlett, D. Michael, B. Andrew, A.J. Crosby, Adv. Funct. Mater. 22, 4985 (2012).
J.P. Gong, Soft Matter 6, 2583 (2010).
G. Josse, P. Sergot, C. Creton, M. Dorget, J. Adhes. 80, 87 (2004).
Dow Corning, Information about High Technology Silicone Materials (Dow Corning Corporation, 1991).
D. Satas (Editor), Handbook of Pressure Sensitive Adhesive Technology, 2nd edition (Van Nostrand Reinhold, New York, 1989).
S. Bhuyan, F. Tanguy, D. Martina, A. Lindner, M. Ciccotti, C. Creton, Soft Matter 9, 6515 (2013).
C. Creton, H. Lakrout, J. Polym. Sci. Part B-Polym. Phys. 38, 965 (2000).
F. Saulnier, T. Ondarcuhu, A. Aradian, E. Raphael, Macromolecules 37, 1067 (2004).
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Nase, J., Ramos, O., Creton, C. et al. Debonding energy of PDMS. Eur. Phys. J. E 36, 103 (2013). https://doi.org/10.1140/epje/i2013-13103-3
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DOI: https://doi.org/10.1140/epje/i2013-13103-3