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Silver cluster induced absorption enhancement and conformation control of peptides

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Abstract

We present a theoretical study of the structural and optical properties of isolated silver cluster-tripeptide hybrid systems. We show that small silver clusters induce enhancement of the optical absorption of peptides. Moreover, silver clusters bound to peptides can reduce the conformational flexibility and invoke changes of the secondary structure. Thus, they might serve as local optical probes in biolabelling applications.

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References

  • E. Katz, I. Willner, Angew. Chem. Int. Ed. 43, 6042 (2004)

    Google Scholar 

  • M. Moskovits, Rev. Mod. Phys. 57, 783 (1985)

    Google Scholar 

  • L. Peyser-Capadona, J. Zheng, J.I. González, T.H. Lee, S.A. Patel, R.M. Dickson, Phys. Rev. Lett. 94, 058301 (2005)

    Google Scholar 

  • J. Yu, S.A. Patel, R.M. Dickson, Angew. Chem. Int. Ed. 46, 2028 (2007)

    Google Scholar 

  • X. Jiang, J. Jiang, Y. Jin, E. Wang, S. Dong, Biomacromolecules 6, 46 (2005)

    Google Scholar 

  • V. Bonačić-Koutecký, V. Veyret, R. Mitrić, J. Chem. Phys. 115, 10450 (2001)

    Google Scholar 

  • C. Sieber, J. Buttet, W. Harbich, C. Félix, R. Mitrić, V. Bonačić-Koutecký, Phys. Rev. A 70, 041201 (2004)

    Google Scholar 

  • C. Félix, C. Sieber, W. Harbich, J. Buttet, I. Rabin, W. Schulze, G. Ertl, Phys. Rev. Lett. 86, 2992 (2001)

    Google Scholar 

  • I. Compagnon, T. Tabarin, R. Antoine, M. Broyer, P. Dugourd, R. Mitrić, J. Petersen, V. Bonačić-Koutecký, J. Chem. Phys. 125, 164326 (2006)

    Google Scholar 

  • R. Mitrić, J. Petersen, A. Kulesza, V. Bonačić-Koutecký, T. Tabarin, I. Compagnon, R. Antoine, M. Broyer, P. Dugourd, J. Chem. Phys. 127, 134301 (2007)

    Google Scholar 

  • T. Tabarin, R. Antoine, I. Compagnon, M. Broyer, P. Dugourd, R. Mitrić, J. Petersen, V. Bonačić-Koutecký, Eur. Phys. J. D 43, 275 (2007)

    Google Scholar 

  • T. Tabarin, A. Kulesza, R. Antoine, R. Mitrić, M. Broyer, P. Dugourd, V. Bonačić-Koutecký, Phys. Rev. Lett. 101, 213001 (2008)

    Google Scholar 

  • A.D. Becke, J. Chem. Phys. 98, 1372 (1993)

    Google Scholar 

  • C. Lee, W. Yang, R.G. Parr, Phys. Rev. B 37, 785 (1988)

    Google Scholar 

  • M.J.S. Dewar, E.G. Zoebisch, E.F. Healy, J.J.P. Stewart, J. Am. Chem. Soc. 107, 3902 (1985)

    Google Scholar 

  • D. Andrae, U. Haeussermann, M. Dolg, H. Stoll, H. Preuss, Theor. Chim. Acta 77, 123 (1990)

    Google Scholar 

  • V. Bonačić-Koutecký, J. Pittner, M. Boiron, P. Fantucci, J. Chem. Phys. 110, 3876 (1999)

    Google Scholar 

  • G. Granucci, M. Persico, A. Toniolo, J. Chem. Phys. 114, 10608 (2001)

    Google Scholar 

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Correspondence to V. Bonačić-Koutecký.

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Kulesza, A., Mitrić, R. & Bonačić-Koutecký, V. Silver cluster induced absorption enhancement and conformation control of peptides. Eur. Phys. J. D 52, 203–206 (2009). https://doi.org/10.1140/epjd/e2009-00056-2

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