Abstract.
As-grown and proton-irradiation damaged crystals of the quasi-one dimensional organic conductor (fluoranthene)2PF6 are studied by static magnetic field gradient spin echo electron spin resonance. The parallel-to-stack diffusion constant \(D_{\parallel}\) varies sample dependent by a factor of 50, just like the ratio \(D_{\parallel}/D_{\bot}\). The restriction of free diffusive motion of the conduction electron spins of as-grown and microstructured crystals is analyzed.
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T. Tashma, G. Alexandrowicz, N. Kaplan, E. Dormann, A. Grayevsky, A. Gabay, Synth. Metals 106, 151 (1999)
G.G. Maresch, A. Grupp, M. Mehring, J.U. von Schütz, H.C. Wolf, J. Phys. France 46, 461 (1985)
G.G. Maresch, Zeitaufgelöste Elektronenspinresonanz zur Untersuchung von Elektron-Spindiffusion mit und ohne Elektronentransport in organischen eindimensionalen Leitern, Ph.D. thesis, Universität Stuttgart, Germany, 1987
M. Mehring in: Low-Dimensional Conductors and Superconductors, edited by D. Jérome, L.G. Caron (Plenum Publishing Corp., 1987), p. 185
G. Sachs, W. Stöcklein, B. Bail, E. Dormann, M. Schwoerer, Chem. Phys. Lett. 89, 179 (1982)
H.C. Torrey, Phys. Rev 104, 563 (1956)
J.E. Tanner, E.O. Stejskal, J. Chem. Phys. 49, 1768 (1968)
R. Ruf, N. Kaplan, E. Dormann, Phys. Rev. Lett. 74, 2122 (1995)
N. Kaplan, E. Dormann, R. Ruf, A. Coy, P.T. Callaghan, Phys. Rev. B 52, 16385 (1995)
G. Alexandrowicz, T. Tashma, A. Feintuch, A. Grayevsky, E. Dormann, N. Kaplan, Phys. Rev. Lett. 84, 2973 (2000)
T. Tashma, A. Feintuch, A. Grayevsky, J. Gmeiner, A. Gabay, E. Dormann, N. Kaplan, Synth. Metals 132, 161 (2003)
A. Feintuch, T. Tashma, A. Grayevsky, J. Gmeiner, E. Dormann, N. Kaplan, J. Magn. Res. 157, 69 (2002)
T. Wokrina, Räumlich eingeschränkte Elektronen-Spindiffusion in quasi-eindimensionalen organischen Leitern, Ph.D. thesis, Universität Karlsruhe, Germany (2002) (Shaker-Verlag, Aachen, 2002)
T. Wokrina, E. Dormann, N. Kaplan, Europhys. Lett. 49, 244 (2000)
T. Wokrina, E. Dormann, J. Gmeiner, Synth. Metals 120, 847 (2001)
T. Wokrina, E. Dormann, N. Kaplan, Phys. Rev. B 54, 10492 (1996)
C.H. Neumann, J. Chem. Phys. 60, 4508 (1974)
B. Robertson, Phys. Rev. 151, 273 (1966)
V. Enkelmann, Adv. Chem. Ser. 217, 177 (1988)
T. Wokrina, J. Gmeiner, N. Kaplan, E. Dormann, Phys. Rev. B 67, 054103 (2003)
M.D. Hürlimann, K.G. Helmer, T.M. de Swiet, P.N. Sen, C.H. Sotak, J. Magn. Res. A 113, 260 (1995)
T.M. de Swiet, P.N. Sen, J. Chem. Phys. 100, 5597 (1994)
P.T. Callaghan, Principles of Nuclear Magnetic Resonance Microscopy (Oxford Science Publications, Oxford, 1995)
M. Drescher, private communication
I. Baldea, H. Köppel, L.S. Cederbaum, J. Phys. Soc. Jpn 68, 1954 (1999)
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Received: 20 May 2003, Published online: 2 October 2003
PACS:
76.30.Pk Conduction electrons - 72.15.Lh Relaxation times and mean free paths - 61.72.-y Defects and impurities in crystals, microstructure - 61.80.Jh Ion radiation effects
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Wokrina, T., Gmeiner, J., Kaplan, N. et al. Sample dependence of anisotropy and restriction of electron-spin diffusion in the quasi-one dimensional organic conductor (fluoranthene)\(\mathsf{_2}\)PF\(\mathsf{_6}\) . Eur. Phys. J. B 35, 191–199 (2003). https://doi.org/10.1140/epjb/e2003-00268-2
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DOI: https://doi.org/10.1140/epjb/e2003-00268-2