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Novel polyesters and polyester/Cloisite 30B nanocomposites based on a new rhodanine-based monomer

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Abstract

A novel bis-diol monomer, 3,3'-bis-(2-hydroxyethyl)-2,2'-dithioxo-[5,5']bithiazolidinylidene-4,4'-dione, was prepared in a one-pot three component reaction and used in a polyesterification reaction with various aromatic dicarboxylic acids using tosyl chloride/dimethylformamide/pyridine system as a condensing agent in order to generate a series of new polyesters. The prepared polyesters were characterized by FTIR spectroscopy and elemental analysis. In the next part, a series of polyester/clay nanocomposites were synthesized through a polyesterification reaction of the synthesized monomer with iso-phthalic acid. Cloisite 30B was used as the filler at different concentrations. Wide-angle X-ray diffraction and transmission electron microscopy studies showed that the organoclay layers are mainly exfoliated in the nanocomposites containing 1 wt % of Cloisite 30B.

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Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Science, University of Mohaghegh Ardabili, 56199-11367, Ardabil, Iran

    F. Nasiri, Y. Mansoori & N. Rostamzadeh

Authors
  1. F. Nasiri
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  2. Y. Mansoori
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  3. N. Rostamzadeh
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Correspondence to F. Nasiri.

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Nasiri, F., Mansoori, Y. & Rostamzadeh, N. Novel polyesters and polyester/Cloisite 30B nanocomposites based on a new rhodanine-based monomer. Polym. Sci. Ser. B 59, 268–280 (2017). https://doi.org/10.1134/S1560090417030137

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  • DOI: https://doi.org/10.1134/S1560090417030137

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