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Determination of the rate constants of recombination of macroradicals and stable radicals via the competitive-inhibition method

  • Polymerization
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Abstract

The rate constants of recombination, k X, of propagating radicals with nitroxides in pseudoliving radical polymerization are determined via the competitive-inhibition method with the use of ESR spectroscopy. This method is applicable to determination of k X in the reactions of propagating radicals of styrene, acrylic acid, and methyl methacrylate with two stable radicals, the nitroxide diethylphosphono-2,2-dimethylpropyl nitroxide and the phenoxide galvinoxyl. The values of k X determined at 50°C increase in the following sequence: diethylphosphono-2,2-dimethylpropyl nitroxide-TEMPO-galvinoxyl. The selectivity of the low-activity propagating radicals of styrene in reactions with stable radicals is shown.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    O. V. Borisova, M. Yu. Zaremskii, V. B. Golubev & A. V. Plutalova

  2. UPPA, CNRS UMR 5254 IPREM, Equipe de Physique et Chimie des Polyméres, Pau France2, Avenue du Président Pierre Angot, 64053, Pau CEDEX 9, France

    O. V. Borisova, O. V. Borisov & L. Billon

  3. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31 (V.O.), St. Petersburg, 199004, Russia

    O. V. Borisov

Authors
  1. O. V. Borisova
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  2. M. Yu. Zaremskii
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  3. V. B. Golubev
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  4. A. V. Plutalova
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  5. O. V. Borisov
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  6. L. Billon
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Corresponding author

Correspondence to M. Yu. Zaremskii.

Additional information

Original Russian Text © O.V. Borisova, M.Yu. Zaremskii, V.B. Golubev, A.V. Plutalova, O.V. Borisov, L. Billon, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 9, pp. 1213–1220.

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Borisova, O.V., Zaremskii, M.Y., Golubev, V.B. et al. Determination of the rate constants of recombination of macroradicals and stable radicals via the competitive-inhibition method. Polym. Sci. Ser. B 55, 508–514 (2013). https://doi.org/10.1134/S1560090413080010

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  • DOI: https://doi.org/10.1134/S1560090413080010

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