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Mixed-ligand cluster [Mo3S4(Dtp)2(μ-AcO)Cl(Me2Bipy)]: Synthesis and structure

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Abstract

Mixed-ligand cluster [Mo3S4(Dtp)2(μ-AcO)Cl(Me2Bipy)] · CHCl3 (I · CHCl3), where Dtp is (EtO)2PS2, was synthesized by the reaction of the molybdenum aqua complex [Mo3S4(H2O)9]4+ with 4,4′-dimethyl-2,2′-bipyridine (Me2Bipy) and phosphorus sulfide (P4S10) in ethanol followed by chromatographic separation on silica gel and crystallization in the presence of acetic acid. The crystal structure of I · CHCl3 was determined by X-ray diffraction analysis. The synthesized compound was characterized by the IR and NMR spectra and elemental analysis. The electronic structure of the synthesized compound was established, and its electrochemical behavior in a solution was studied.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. L. Gushchin, Yu. A. Laricheva, D. A. Piryazev & M. N. Sokolov

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    A. L. Gushchin & M. N. Sokolov

Authors
  1. A. L. Gushchin
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  2. Yu. A. Laricheva
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  3. D. A. Piryazev
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  4. M. N. Sokolov
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Correspondence to A. L. Gushchin.

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Original Russian Text © A.L. Gushchin, Yu.A. Laricheva, D.A. Piryazev, M.N. Sokolov, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 1, pp. 8–13.

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Gushchin, A.L., Laricheva, Y.A., Piryazev, D.A. et al. Mixed-ligand cluster [Mo3S4(Dtp)2(μ-AcO)Cl(Me2Bipy)]: Synthesis and structure. Russ J Coord Chem 40, 5–9 (2014). https://doi.org/10.1134/S1070328414010023

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  • DOI: https://doi.org/10.1134/S1070328414010023

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