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Low-temperature liquid–liquid extraction of phenols from aqueous solutions with hydrophilic mixtures of extractants

  • Physical Chemistry of Separation Processes: Chromatography
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Abstract

The volume ratios in acetonitrile–ethyl acetate (90 : 10, 95 : 5), acetonitrile–isopropanol–ethyl acetate (70 : 15 : 15, 80 : 5 : 15), and isopropanol–1-butanol (50 : 50) mixtures were determined. Their mixing with water (1 : 1) and storage at–10°C led to partitioning into two immiscible liquid phases without formation of the ice phase. The mixtures were shown to be useful as hydrophilic extractants in low-temperature liquidliquid extraction of phenol from aqueous solutions.

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Correspondence to O. B. Rudakov.

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Original Russian Text © O.B. Rudakov, E.A. Khorokhordina, M.A. Preobrazhenskii, L.V. Rudakova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 8, pp. 1257–1260.

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Rudakov, O.B., Khorokhordina, E.A., Preobrazhenskii, M.A. et al. Low-temperature liquid–liquid extraction of phenols from aqueous solutions with hydrophilic mixtures of extractants. Russ. J. Phys. Chem. 90, 1665–1668 (2016). https://doi.org/10.1134/S0036024416080264

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  • DOI: https://doi.org/10.1134/S0036024416080264

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